PMID-sentid	Pub_year	Sent_text		comp_official_name	comp_offsetprotein_name	organism	prot_offset
34059808-6	2021	18O- and 2H-labelling studies evidence the direct evolution of O2 through the nucleophilic attack of a H2O molecule on the highly electrophilic metal-oxo species via the formation of eta2-1iv-OO.	Deuterium	9-11	DNA polymerase iota	Homo sapiens	183-187	
33073977-1	2020	A dynamic frequency shift (DFS) in the 1H NMR resonance of the HD unit of the deuterium-labeled dihydrogen complex [Ru(D)(eta2-HD)(P3P3iPr)][BPh4] [P3P3iPr = P(CH2CH2CH2PiPr2)3] has been observed and analyzed.	Deuterium	78-87	DNA polymerase iota	Homo sapiens	122-126	
33356182-0	2021	High-Frequency Fe-H and Fe-H2 Modes in a trans-Fe(eta2-H2)(H) Complex: A Speed Record for Nuclear Resonance Vibrational Spectroscopy.	Deuterium	27-29	DNA polymerase iota	Homo sapiens	50-54	
19781918-0	2009	High-resolution 2H MAS NMR applied to deuterium analogs of hydrido eta2-dihydrogen complexes.	Deuterium	16-18	DNA polymerase iota	Homo sapiens	67-71	
30114912-5	2018	A diiron eta2-H2 intermediate in the formation of H2 is proposed, and is evidenced by the H/D exchange reactions of [1(mu-H)H]+ with D2, D2O, and CD3OD.	Deuterium	133-135	DNA polymerase iota	Homo sapiens	9-13	
19781918-0	2009	High-resolution 2H MAS NMR applied to deuterium analogs of hydrido eta2-dihydrogen complexes.	Deuterium	38-47	DNA polymerase iota	Homo sapiens	67-71	
18937477-5	2008	1H NMR spectroscopy, identification of the catalyst structure, and deuterium-labeling experiments all suggest that reactions catalyzed by 2 and 4 occur by turnover-limiting generation of an eta2-imine complex.	Deuterium	67-76	DNA polymerase iota	Homo sapiens	190-194	
12526550-4	2000	In CH2Cl2, 1 is stable up to 240 K. Above this temperature, the eta 2-H2 complex begins to convert into a mixture of trans- and cis-6, which, in turn, transform into the bridging-chloride dimers trans- and cis-[[(triphos)RhH]2(mu-Cl)2]2+ at room temperature.	Deuterium	4-6	DNA polymerase iota	Homo sapiens	64-69	
17140233-5	2006	Further kinetic studies were carried out for the Cp*Fe(dppe)H + CF3COOD and Cp*Fe(dppe)D + CF3COOD systems at 273 K. The [Cp*Fe(dppe)(eta2-HD)]+ complex establishes a very rapid isotope redistribution equilibrium with the eta2-H2 and eta2-D2 analogues.	Deuterium	239-241	DNA polymerase iota	Homo sapiens	134-138	
12526550-0	2000	1H- and 2H-T1 relaxation behavior of the rhodium dihydrogen complex [(triphos)Rh(eta 2-H2)H2]+.	Deuterium	8-10	DNA polymerase iota	Homo sapiens	81-86	
15702187-4	2005	In addition evidence for two isomers of the solvent complex [CH2(eta5-C5H4)2][Rh(C2H4)2][Rh(C2H4)(eta2-toluene)] was obtained in these and related experiments when the photolysis was completed at low temperature without substrate, although no evidence for H/D exchange was observed.	Deuterium	258-259	DNA polymerase iota	Homo sapiens	98-102