PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 29400958-0 2018 Spin-Center Shift-Enabled Direct Enantioselective alpha-Benzylation of Aldehydes with Alcohols. Alcohols 86-94 spindlin 1 Homo sapiens 0-4 29400958-1 2018 Nature routinely engages alcohols as leaving groups, as DNA biosynthesis relies on the removal of water from ribonucleoside diphosphates by a radical-mediated "spin-center shift" (SCS) mechanism. Alcohols 25-33 spindlin 1 Homo sapiens 160-164 29400958-3 2018 We report herein an enantioselective alpha-benzylation of aldehydes using alcohols as alkylating agents based on the mechanistic principle of spin-center shift. Alcohols 74-82 spindlin 1 Homo sapiens 142-146 24700693-2 2014 Alcohols are typically used to probe the reactive spin states of carbenes: O-H insertions are assumed to be characteristic of singlet states, whereas C-H insertions are typical for the triplets. Alcohols 0-8 spindlin 1 Homo sapiens 50-54 11084289-6 2000 In model experiments using Fe(3+)-catalyzed nucleophilic addition of methanol or tert-butanol to the respective spin trap the respective alkoxyl radical adducts were formed in aqueous solution as transient species in the presence of high concentrations of the alcohol. Alcohols 260-267 spindlin 1 Homo sapiens 112-116