PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 16901114-4 2006 The reaction rates increased at higher pH, and the reaction of NAC thiolate with a crotonyl thiol ester in 1:1 (v/v) acetonitrile/aqueous HEPES exhibited buffer catalysis as a result of protonation of the enolate intermediate. enolate 205-212 X-linked Kx blood group Homo sapiens 63-66