PMID-sentid	Pub_year	Sent_text		comp_official_name	comp_offsetprotein_name	organism	prot_offset
17339993-0	2007	On the mechanism of the Rh(II)-catalysed cyclopropanation of alkenes.	Alkenes	61-68	Rh blood group D antigen	Homo sapiens	24-29	
18437248-2	2008	The Rh(II)-catalyzed reaction also takes place intramolecularly to give products derived from trapping of the carbonyl ylide dipole with a tethered alkene.	Alkenes	148-154	Rh blood group D antigen	Homo sapiens	4-9	
15264821-2	2004	A novel chiral Rh(II) catalyst (1) is introduced for the [2 + 1]-cycloaddition of ethyl diazoacetate to terminal acetylenes and olefins with high enantioselectivity.	Alkenes	128-135	Rh blood group D antigen	Homo sapiens	15-21	
15524480-0	2004	Rh(II)-catalyzed enantioselective cyclopropanation of olefins with dimethyl malonate via in situ generated phenyliodonium ylide.	Alkenes	54-61	Rh blood group D antigen	Homo sapiens	0-6	
15524480-1	2004	Olefins are cyclopropanated with dimethyl malonate (1a) iodosylbenzene (PhI=O) and a Rh(II) carboxylate catalyst via an in situ generated phenyliodonium ylide (1c).	Alkenes	0-7	Rh blood group D antigen	Homo sapiens	85-91	
33988384-0	2021	Rh(II)-Catalyzed C-H Alkylation of Benzylamines with Unactivated Alkenes: The Influence of Acid on Linear and Branch Selectivity.	Alkenes	65-72	Rh blood group D antigen	Homo sapiens	0-6	
34236835-0	2021	Rh(II)-Catalyzed Alkynylcyclopropanation of Alkenes by Decarbenation of Alkynylcycloheptatrienes.	Alkenes	44-51	Rh blood group D antigen	Homo sapiens	0-6	
15096061-4	2004	When phenyliodonium ylides are generated in the presence of Rh(II) catalysts and olefins, they react in situ to afford cyclopropanes.	Alkenes	81-88	Rh blood group D antigen	Homo sapiens	60-65	
34164088-0	2021	Rh(i)- and Rh(ii)-catalyzed C-H alkylation of benzylamines with alkenes and its application in flow chemistry.	Alkenes	64-71	Rh blood group D antigen	Homo sapiens	14-16	
33146649-2	2020	In this study, we report our efforts to use tethered thioether ligands to tune the reactivity of RhII-carbene mediated cyclopropanation of olefins with ethyl diazoacetate.	Alkenes	139-146	Rh blood group D antigen	Homo sapiens	97-101	
22070230-3	2011	This reagent, which was prepared via a Rh(II)- or Cu(I)-catalyzed carbenoid Si-H insertion, was used to introduce the desired olefin geometry and stereocenters of the C1-C5 propionate subunit.	Alkenes	126-132	Rh blood group D antigen	Homo sapiens	39-46	
30192145-3	2018	Herein, we have developed a highly efficient Rh(II)-catalyzed method for the direct preparation of unactivated aziridines from olefins using O-(sulfonyl)hydroxylamines as the aminating agent.	Alkenes	127-134	Rh blood group D antigen	Homo sapiens	45-50	
28952315-2	2017	Under the catalysis from a Rh(II) complex, this class of alpha-diazo imidates reacted with alkenes and conjugated dienes through a formal [2 + 1] (i.e., cyclopropanation) or [4 + 3] cycloaddition to furnish spiro[cyclopropane-1,4"-isochroman]-3"-imines and tetrahydroisochromeno[3,4-b] azepines, respectively.	Alkenes	91-98	Rh blood group D antigen	Homo sapiens	27-33	
22360738-2	2012	An alkynyl diazo ester under Rh(II) catalysis is employed for cyclopropanations of electron-rich olefins while an alkynyl sulfonium ylide is used for electron-poor olefins.	Alkenes	97-104	Rh blood group D antigen	Homo sapiens	29-35	
22360738-2	2012	An alkynyl diazo ester under Rh(II) catalysis is employed for cyclopropanations of electron-rich olefins while an alkynyl sulfonium ylide is used for electron-poor olefins.	Alkenes	164-171	Rh blood group D antigen	Homo sapiens	29-35	
28614619-1	2017	A RhII -catalyzed direct and stereospecific N-H- and N-alkyl aziridination of olefins is reported that uses hydroxylamine-O-sulfonic acids as inexpensive, readily available, and nitro group-free aminating reagents.	Alkenes	78-85	Rh blood group D antigen	Homo sapiens	2-6	
27258005-1	2016	The Rh(II) -catalyzed oxyamination and diamination of alkenes generate 1,2-amino alcohols and 1,2-diamines, respectively, in good to excellent yields and with complete regiocontrol.	Alkenes	54-61	Rh blood group D antigen	Homo sapiens	4-10	
21548649-0	2011	Asymmetric Rh(II)-catalyzed cyclopropanation of alkenes with diacceptor diazo compounds: p-methoxyphenyl ketone as a general stereoselectivity controlling group.	Alkenes	48-55	Rh blood group D antigen	Homo sapiens	11-17