PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 17339993-0 2007 On the mechanism of the Rh(II)-catalysed cyclopropanation of alkenes. Alkenes 61-68 Rh blood group D antigen Homo sapiens 24-29 18437248-2 2008 The Rh(II)-catalyzed reaction also takes place intramolecularly to give products derived from trapping of the carbonyl ylide dipole with a tethered alkene. Alkenes 148-154 Rh blood group D antigen Homo sapiens 4-9 15264821-2 2004 A novel chiral Rh(II) catalyst (1) is introduced for the [2 + 1]-cycloaddition of ethyl diazoacetate to terminal acetylenes and olefins with high enantioselectivity. Alkenes 128-135 Rh blood group D antigen Homo sapiens 15-21 15524480-0 2004 Rh(II)-catalyzed enantioselective cyclopropanation of olefins with dimethyl malonate via in situ generated phenyliodonium ylide. Alkenes 54-61 Rh blood group D antigen Homo sapiens 0-6 15524480-1 2004 Olefins are cyclopropanated with dimethyl malonate (1a) iodosylbenzene (PhI=O) and a Rh(II) carboxylate catalyst via an in situ generated phenyliodonium ylide (1c). Alkenes 0-7 Rh blood group D antigen Homo sapiens 85-91 33988384-0 2021 Rh(II)-Catalyzed C-H Alkylation of Benzylamines with Unactivated Alkenes: The Influence of Acid on Linear and Branch Selectivity. Alkenes 65-72 Rh blood group D antigen Homo sapiens 0-6 34236835-0 2021 Rh(II)-Catalyzed Alkynylcyclopropanation of Alkenes by Decarbenation of Alkynylcycloheptatrienes. Alkenes 44-51 Rh blood group D antigen Homo sapiens 0-6 15096061-4 2004 When phenyliodonium ylides are generated in the presence of Rh(II) catalysts and olefins, they react in situ to afford cyclopropanes. Alkenes 81-88 Rh blood group D antigen Homo sapiens 60-65 34164088-0 2021 Rh(i)- and Rh(ii)-catalyzed C-H alkylation of benzylamines with alkenes and its application in flow chemistry. Alkenes 64-71 Rh blood group D antigen Homo sapiens 14-16 33146649-2 2020 In this study, we report our efforts to use tethered thioether ligands to tune the reactivity of RhII-carbene mediated cyclopropanation of olefins with ethyl diazoacetate. Alkenes 139-146 Rh blood group D antigen Homo sapiens 97-101 22070230-3 2011 This reagent, which was prepared via a Rh(II)- or Cu(I)-catalyzed carbenoid Si-H insertion, was used to introduce the desired olefin geometry and stereocenters of the C1-C5 propionate subunit. Alkenes 126-132 Rh blood group D antigen Homo sapiens 39-46 30192145-3 2018 Herein, we have developed a highly efficient Rh(II)-catalyzed method for the direct preparation of unactivated aziridines from olefins using O-(sulfonyl)hydroxylamines as the aminating agent. Alkenes 127-134 Rh blood group D antigen Homo sapiens 45-50 28952315-2 2017 Under the catalysis from a Rh(II) complex, this class of alpha-diazo imidates reacted with alkenes and conjugated dienes through a formal [2 + 1] (i.e., cyclopropanation) or [4 + 3] cycloaddition to furnish spiro[cyclopropane-1,4"-isochroman]-3"-imines and tetrahydroisochromeno[3,4-b] azepines, respectively. Alkenes 91-98 Rh blood group D antigen Homo sapiens 27-33 22360738-2 2012 An alkynyl diazo ester under Rh(II) catalysis is employed for cyclopropanations of electron-rich olefins while an alkynyl sulfonium ylide is used for electron-poor olefins. Alkenes 97-104 Rh blood group D antigen Homo sapiens 29-35 22360738-2 2012 An alkynyl diazo ester under Rh(II) catalysis is employed for cyclopropanations of electron-rich olefins while an alkynyl sulfonium ylide is used for electron-poor olefins. Alkenes 164-171 Rh blood group D antigen Homo sapiens 29-35 28614619-1 2017 A RhII -catalyzed direct and stereospecific N-H- and N-alkyl aziridination of olefins is reported that uses hydroxylamine-O-sulfonic acids as inexpensive, readily available, and nitro group-free aminating reagents. Alkenes 78-85 Rh blood group D antigen Homo sapiens 2-6 27258005-1 2016 The Rh(II) -catalyzed oxyamination and diamination of alkenes generate 1,2-amino alcohols and 1,2-diamines, respectively, in good to excellent yields and with complete regiocontrol. Alkenes 54-61 Rh blood group D antigen Homo sapiens 4-10 21548649-0 2011 Asymmetric Rh(II)-catalyzed cyclopropanation of alkenes with diacceptor diazo compounds: p-methoxyphenyl ketone as a general stereoselectivity controlling group. Alkenes 48-55 Rh blood group D antigen Homo sapiens 11-17