PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 30300955-2 2018 The present approach relies on an asymmetric olefin cyclopropanation reaction catalyzed by an engineered myoglobin in the presence of ex situ generated diazoacetonitrile within a compartmentalized reaction system. Alkenes 45-51 myoglobin Homo sapiens 105-114 25538035-0 2015 Highly diastereoselective and enantioselective olefin cyclopropanation using engineered myoglobin-based catalysts. Alkenes 47-53 myoglobin Homo sapiens 88-97 32943150-4 2020 These strategies are effective for imparting these myoglobin-based cyclopropanation biocatalysts with altered and improved function, including tolerance to aerobic conditions and improved reactivity toward electrondeficient olefins. Alkenes 224-231 myoglobin Homo sapiens 51-60 31133770-4 2019 In addition, substitution of the proximal histidine with an aspartate residue led to a myoglobin-based catalyst capable of promoting stereoselective olefin cyclopropanation under nonreducing conditions. Alkenes 149-155 myoglobin Homo sapiens 87-96