PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 16268627-4 2005 These studies demonstrate the validity of our synthetic strategy, although they reveal some problems associated with the olefin cross metathesis, whose efficiency depends on the substituent at the C-2 position as well as the steric environment of the alkene. Alkenes 121-127 complement C2 Homo sapiens 197-200 16347505-1 1987 Eleven strains of alkene-utilizing bacteria belonging to the genera Mycobacterium, Nocardia, and Xanthobacter were tested for their ability to grow with C(1) to C(6) alkanes, C(2) to C(6) alkenes, alkadienes, and monoterpenes furnished individually as sole sources of carbon and energy in a mineral salts medium. Alkenes 18-24 complement C2 Homo sapiens 175-179 27593893-3 2016 The outcomes of the feasible C H activation of olefin carbon (C-2) by iridium catalyst are compared with the reduction of the carbonyl group (C-3) by freshly prepared borodeuterides. Alkenes 47-53 complement C2 Homo sapiens 62-65 23865980-0 2013 Fast CO2 sequestration, activation, and catalytic transformation using N-heterocyclic olefins. Alkenes 86-93 complement C2 Homo sapiens 5-8 17221975-2 2007 For 1,1,2-trisubstituted epoxyalkynes, this Co2(CO)6-allene species reacted with a tethered olefin to give [2+2]-cycloadducts, and with CO and a tethered olefin to produce [2+2+1]-cycloadducts. Alkenes 92-98 complement C2 Homo sapiens 44-47 17221975-2 2007 For 1,1,2-trisubstituted epoxyalkynes, this Co2(CO)6-allene species reacted with a tethered olefin to give [2+2]-cycloadducts, and with CO and a tethered olefin to produce [2+2+1]-cycloadducts. Alkenes 154-160 complement C2 Homo sapiens 44-47 29577133-1 2018 An efficient strategy for the synthesis of C-2 and C-3 branched sugar dienes via cross dehydrogenative coupling of sugar enol ethers with terminal alkenes was developed. Alkenes 147-154 complement C2 Homo sapiens 43-46 27714952-8 2016 Some preparations contain predominantly the alkene in C-2 and, therefore, an efficient detection method must include both primary metabolites M1 and M2. Alkenes 44-50 complement C2 Homo sapiens 54-57 27773949-4 2016 The key step in the synthesis is oxidative olefin cleavage of delta-tocotrienol to afford the chroman core of 1 with retention of chirality at the C-2 stereocenter. Alkenes 43-49 complement C2 Homo sapiens 147-150 26863099-2 2016 The developed protocol introduces pentafulvenes as nonsymmetrical alkenes for the hydroheteroarylation reaction, providing alkylidenecyclopentenylation at the C-3 position of indoles and the C-2 position of pyrrole. Alkenes 66-73 complement C2 Homo sapiens 191-194 16448104-2 2006 Catalytic activity has been observed for olefins CH2C(H)(X) with X = CN, C(O)Me, or CO2Me as well as crotononitrile. Alkenes 41-48 complement C2 Homo sapiens 84-87 34102836-5 2021 We show that the reactivity of CO2 - with electron-poor olefins results in either single electron reduction or alkene hydrocarboxylation, where substrate reduction potentials can be utilized to predict reaction outcome. Alkenes 56-63 complement C2 Homo sapiens 31-34 11058062-5 2000 The chemical shifts of alkene C(1) and C(2) indicate notable polarisation of the olefin after complexation, while the 1J(Pt, C(1)) and 1J(Pt, C(2)) values are in agreement with a stronger interaction of Pt with C(1) than with C(2). Alkenes 81-87 complement C2 Homo sapiens 39-43 11058062-5 2000 The chemical shifts of alkene C(1) and C(2) indicate notable polarisation of the olefin after complexation, while the 1J(Pt, C(1)) and 1J(Pt, C(2)) values are in agreement with a stronger interaction of Pt with C(1) than with C(2). Alkenes 81-87 complement C2 Homo sapiens 142-146 11058062-5 2000 The chemical shifts of alkene C(1) and C(2) indicate notable polarisation of the olefin after complexation, while the 1J(Pt, C(1)) and 1J(Pt, C(2)) values are in agreement with a stronger interaction of Pt with C(1) than with C(2). Alkenes 81-87 complement C2 Homo sapiens 142-146 34380308-5 2021 Mechanistic studies support the working model involving a thiol-catalyzed radical chain process wherein the atoms from formate are delivered across the alkene substrate via CO2 - as a key reactive intermediate. Alkenes 152-158 complement C2 Homo sapiens 173-176 34102836-5 2021 We show that the reactivity of CO2 - with electron-poor olefins results in either single electron reduction or alkene hydrocarboxylation, where substrate reduction potentials can be utilized to predict reaction outcome. Alkenes 111-117 complement C2 Homo sapiens 31-34