PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 35023736-2 2022 However, the introduction of dimethylamino but not methoxy substituents onto the exocyclic carbon atom changes the situation drastically so that the monomers (C5H4CH(NMe2))M(CO)3 and (C5H4C(NMe2)2)M(CO)3 become strongly thermochemically favored, lying DeltaE = 43 kcal/mol (M = W) to 63 kcal/mol (M = Cr) below their corresponding dimers. Tungsten 278-279 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 166-170 35023736-2 2022 However, the introduction of dimethylamino but not methoxy substituents onto the exocyclic carbon atom changes the situation drastically so that the monomers (C5H4CH(NMe2))M(CO)3 and (C5H4C(NMe2)2)M(CO)3 become strongly thermochemically favored, lying DeltaE = 43 kcal/mol (M = W) to 63 kcal/mol (M = Cr) below their corresponding dimers. Tungsten 278-279 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 190-194 29441373-2 2018 When azobenzene was used as the substrate, a trans to cis isomerization induced by blue-LED light was essential prior to the metathesis cleavage of the N[double bond, length as m-dash]N bond by the W[triple bond, length as m-dash]W bond of (Me2N)2(TfO)W[triple bond, length as m-dash]W(OTf)(NMe2)2 (6), affording the corresponding imido-bridged dinuclear tungsten complexes 7-9. Tungsten 355-363 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 291-295