PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 20104345-0 2010 Unexpected chemoselectivity in the Schiff condensation of amines with eta(2)(C,O)- eta(1)(O)-coordinated aldehyde. Aldehydes 105-113 DNA polymerase iota Homo sapiens 70-76 20104345-1 2010 The aldehyde function coordinated as eta(1); eta(2) is able to discriminate between aliphatic and aromatic amines in the Schiff condensation reaction. Aldehydes 4-12 DNA polymerase iota Homo sapiens 45-51 19727457-0 2009 Gas phase fragmentation of eta2 coordinated aldehydes in [VO2(eta2-OCHR)]-: aldehyde structure dictates the nature of the products. Aldehydes 44-53 DNA polymerase iota Homo sapiens 27-31 19715289-1 2009 The reaction of (trifluoromethyl)dimethylphenylsilylacetylene and (eta(2)-propene)Ti(O(i)Pr)(2) generated in situ smoothly proceeded giving the corresponding (eta(2)-1-dimethylphenylsilyl-2-trifluoromethylalkyne)Ti(O(i)Pr)(2), which reacted with aldehydes and ketones to afford the corresponding addition products in good yields with good to excellent regioselectivity. Aldehydes 246-255 DNA polymerase iota Homo sapiens 67-72 19715289-1 2009 The reaction of (trifluoromethyl)dimethylphenylsilylacetylene and (eta(2)-propene)Ti(O(i)Pr)(2) generated in situ smoothly proceeded giving the corresponding (eta(2)-1-dimethylphenylsilyl-2-trifluoromethylalkyne)Ti(O(i)Pr)(2), which reacted with aldehydes and ketones to afford the corresponding addition products in good yields with good to excellent regioselectivity. Aldehydes 246-255 DNA polymerase iota Homo sapiens 159-164 19727457-0 2009 Gas phase fragmentation of eta2 coordinated aldehydes in [VO2(eta2-OCHR)]-: aldehyde structure dictates the nature of the products. Aldehydes 44-53 DNA polymerase iota Homo sapiens 62-66 19727457-0 2009 Gas phase fragmentation of eta2 coordinated aldehydes in [VO2(eta2-OCHR)]-: aldehyde structure dictates the nature of the products. Aldehydes 44-52 DNA polymerase iota Homo sapiens 27-31 19727457-0 2009 Gas phase fragmentation of eta2 coordinated aldehydes in [VO2(eta2-OCHR)]-: aldehyde structure dictates the nature of the products. Aldehydes 44-52 DNA polymerase iota Homo sapiens 62-66 19727457-1 2009 The gas phase fragmentation reactions of eta2 coordinated aldehydes in [VO2(eta2-OCHR)]-, which have previously been shown to play a role in the catalytic oxidation of alcohols to aldehydes, were examined using a combination of isotope labelling experiments and collision induced dissociation in a quadrupole ion trap mass spectrometer. Aldehydes 58-67 DNA polymerase iota Homo sapiens 41-45 19727457-1 2009 The gas phase fragmentation reactions of eta2 coordinated aldehydes in [VO2(eta2-OCHR)]-, which have previously been shown to play a role in the catalytic oxidation of alcohols to aldehydes, were examined using a combination of isotope labelling experiments and collision induced dissociation in a quadrupole ion trap mass spectrometer. Aldehydes 58-67 DNA polymerase iota Homo sapiens 76-80 19727457-1 2009 The gas phase fragmentation reactions of eta2 coordinated aldehydes in [VO2(eta2-OCHR)]-, which have previously been shown to play a role in the catalytic oxidation of alcohols to aldehydes, were examined using a combination of isotope labelling experiments and collision induced dissociation in a quadrupole ion trap mass spectrometer. Aldehydes 180-189 DNA polymerase iota Homo sapiens 41-45 19727457-1 2009 The gas phase fragmentation reactions of eta2 coordinated aldehydes in [VO2(eta2-OCHR)]-, which have previously been shown to play a role in the catalytic oxidation of alcohols to aldehydes, were examined using a combination of isotope labelling experiments and collision induced dissociation in a quadrupole ion trap mass spectrometer. Aldehydes 180-189 DNA polymerase iota Homo sapiens 76-80 35623059-1 2022 Here we report an asymmetric formal nucleophilic o-cresolylation reaction with the Morita-Baylis-Hillman (MBH) carbonates from 2-cyclohexanones and diverse aldehydes under palladium catalysis, by in situ generation of electron-neutral and HOMO-raised eta2-Pd(0)-dienone complexes via an oxidative insertion/pi-sigma-isomerization/beta-H elimination activation sequence. Aldehydes 156-165 DNA polymerase iota Homo sapiens 251-255 12603128-0 2003 (Eta2-alkyne)methyl(dioxo)rhenium complexes as aldehyde-olefination catalysts. Aldehydes 47-55 DNA polymerase iota Homo sapiens 1-5 29099520-1 2017 Reacting the low-valent nickel complex [(dtbpe)Ni]2(mu-eta2:eta2-C6H6) with oxaziridines was found to form mixtures of imine, amide and aldehyde products. Aldehydes 136-144 DNA polymerase iota Homo sapiens 55-59 29099520-1 2017 Reacting the low-valent nickel complex [(dtbpe)Ni]2(mu-eta2:eta2-C6H6) with oxaziridines was found to form mixtures of imine, amide and aldehyde products. Aldehydes 136-144 DNA polymerase iota Homo sapiens 60-64