PMID-sentid	Pub_year	Sent_text		comp_official_name	comp_offsetprotein_name	organism	prot_offset
1024583-3	1976	It is demonstrated that CD4 is a competitive inhibitor of CH4 oxidation.	Methane	58-61	CD4 molecule	Homo sapiens	24-27	
30444626-4	2018	The molecular rotation of methyl radicals isolated in the deuterated solid methane isotopomer, CD4, was investigated both by experimental and theoretical electron paramagnetic resonance (EPR) methods.	Methane	75-82	CD4 molecule	Homo sapiens	95-98	
30968506-1	2019	Mass spectrometric analysis of the anionic products of interaction between platinum atomic anions, Pt- , and methane, CH4 and CD4 , in a collision cell shows the preferred generation of [PtCH4 ]- and [PtCD4 ]- complexes and a low tendency toward dehydrogenation.	Methane	109-116	CD4 molecule	Homo sapiens	126-129	
27438025-2	2016	Pt(+) cations are formed by laser ablation and exposed to controlled amounts of CH4/CD4 leading to [Pt,xC,(4x-2)H/D](+) dehydrogenation products.	Methane	80-83	CD4 molecule	Homo sapiens	84-87	
29633220-1	2018	The present work explores the structures of species formed by dehydrogenation of methane (CH4) and perdeuterated methane (CD4) by the 5d transition metal cation osmium (Os+).	Methane	113-120	CD4 molecule	Homo sapiens	122-125	
25768128-1	2015	The reaction of atomic thorium cations with CH4 (CD4) and the collision-induced dissociation (CID) of ThCH4(+) with Xe are studied using guided ion beam tandem mass spectrometry.	Methane	44-47	CD4 molecule	Homo sapiens	49-52	
24588097-0	2014	Temperature-dependent kinetics of charge transfer, hydrogen-atom transfer, and hydrogen-atom expulsion in the reaction of CO+ with CH4 and CD4.	Methane	131-134	CD4 molecule	Homo sapiens	139-142	
24749673-0	2014	Theoretical kinetics study of the O(3P) + CH4/CD4 hydrogen abstraction reaction: the role of anharmonicity, recrossing effects, and quantum mechanical tunneling.	Methane	42-45	CD4 molecule	Homo sapiens	46-49	
24568117-1	2014	The temperature dependences of the rate constants and product branching ratios for the reactions of FeO(+) with CH4 and CD4 have been measured from 123 to 700 K. The 300 K rate constants are 9.5 x 10(-11) and 5.1 x 10(-11) cm(3) s(-1) for the CH4 and CD4 reactions, respectively.	Methane	112-115	CD4 molecule	Homo sapiens	251-254	
24568117-1	2014	The temperature dependences of the rate constants and product branching ratios for the reactions of FeO(+) with CH4 and CD4 have been measured from 123 to 700 K. The 300 K rate constants are 9.5 x 10(-11) and 5.1 x 10(-11) cm(3) s(-1) for the CH4 and CD4 reactions, respectively.	Methane	243-246	CD4 molecule	Homo sapiens	120-123	
23812350-6	2013	From the collision energy dependence of the abstraction/insertion ratio, the barrier height for the abstraction pathway is estimated to be 0.7 +- 0.3 and 0.8 +- 0.1 kcal mol(-1) for O((1)D2) with CH4 and CD4, respectively.	Methane	196-199	CD4 molecule	Homo sapiens	204-207	
23812350-7	2013	The insertion pathway of the O((1)D2) reaction with CH4 has a narrower angular width in the forward scattering and a larger insertion/abstraction ratio than the reaction with CD4, which indicates that the insertion reaction with CH4 has a larger cross section and a shorter reaction time than the reaction with CD4.	Methane	52-55	CD4 molecule	Homo sapiens	175-178	
23812350-7	2013	The insertion pathway of the O((1)D2) reaction with CH4 has a narrower angular width in the forward scattering and a larger insertion/abstraction ratio than the reaction with CD4, which indicates that the insertion reaction with CH4 has a larger cross section and a shorter reaction time than the reaction with CD4.	Methane	52-55	CD4 molecule	Homo sapiens	311-314	
23812350-7	2013	The insertion pathway of the O((1)D2) reaction with CH4 has a narrower angular width in the forward scattering and a larger insertion/abstraction ratio than the reaction with CD4, which indicates that the insertion reaction with CH4 has a larger cross section and a shorter reaction time than the reaction with CD4.	Methane	229-232	CD4 molecule	Homo sapiens	175-178	
23812350-7	2013	The insertion pathway of the O((1)D2) reaction with CH4 has a narrower angular width in the forward scattering and a larger insertion/abstraction ratio than the reaction with CD4, which indicates that the insertion reaction with CH4 has a larger cross section and a shorter reaction time than the reaction with CD4.	Methane	229-232	CD4 molecule	Homo sapiens	311-314	
21240398-0	2011	Deuterium kinetic isotope effects on the gas-phase reactions of C2H with H2(D2) and CH4(CD4).	Methane	84-87	CD4 molecule	Homo sapiens	88-91	
17030134-7	2007	Calculations are also reported for the isotopic methane (CD4, 13CH4) hydrates.	Methane	48-55	CD4 molecule	Homo sapiens	57-60	
26616766-1	2010	Application to the CH4/CD3H/CD4 + CF3 Abstraction Reactions.	Methane	19-22	CD4 molecule	Homo sapiens	28-31	
26616766-5	2010	The performance of this algorithm has been tested for the CH4/CD3H/CD4 + CF3 hydrogen abstraction reactions with encouraging results, i.e., when the fitting is performed using 13 points, the algorithm is about 30 times faster than the full calculation with deviations that are smaller than 5%.	Methane	58-61	CD4 molecule	Homo sapiens	67-70	
19787985-4	2005	There has been a controversial discussion about an experiment which seemed to indicate that deuteron transfer from CD4+ to CH4 can create stable isotopomers with chemically distinguishable hydrogen atoms, CH3-HD+.	Methane	123-126	CD4 molecule	Homo sapiens	115-118	
17249765-1	2007	High-resolution electron spin resonance (ESR) spectra of radical pairs of a hydrogen atom that coupled with a methyl radical (H...CH3, H...CHD2, D...CH2D, and D...CD3) were observed for X-ray irradiated solid argon containing selectively deuterium-labeled methanes, CH4, CH2D2, and CD4, at 4.2 K. The double-quartet 1H-hyperfine (hf) splittings of ca.	Methane	256-264	CD4 molecule	Homo sapiens	282-285	
17249765-1	2007	High-resolution electron spin resonance (ESR) spectra of radical pairs of a hydrogen atom that coupled with a methyl radical (H...CH3, H...CHD2, D...CH2D, and D...CD3) were observed for X-ray irradiated solid argon containing selectively deuterium-labeled methanes, CH4, CH2D2, and CD4, at 4.2 K. The double-quartet 1H-hyperfine (hf) splittings of ca.	Methane	266-269	CD4 molecule	Homo sapiens	282-285	
19787985-6	2005	In collisions of CH4+ with CH4 or CD4, there is significant scrambling and one would need to use differential scattering selection for getting ions produced exclusively via a specific mechanism.	Methane	17-21	CD4 molecule	Homo sapiens	34-37	
19787985-6	2005	In collisions of CH4+ with CH4 or CD4, there is significant scrambling and one would need to use differential scattering selection for getting ions produced exclusively via a specific mechanism.	Methane	17-20	CD4 molecule	Homo sapiens	34-37	
34658236-4	2021	We found that as the incident velocity of CH4 and CD4 increases, the sticking probabilities for both molecules on a CH4 condensed film decrease systematically, but that preferential sticking and condensation occur for CD4.	Methane	42-45	CD4 molecule	Homo sapiens	218-221	
15267839-3	2004	For isotopomers containing CH4, 13CH4, and CD4, two sets of transitions with K = 0 and one with K = 1 were recorded, correlating to the j = 0, 1, and 2 rotational levels of free methane, respectively (j is the rotational angular momentum quantum number of the methane monomer).	Methane	178-185	CD4 molecule	Homo sapiens	43-46	
12783540-3	2003	The temperature dependence of the EIE for oxidative addition of CH4 and CD4 differs significantly from that for coordination, with the EIE being normal at all temperatures and approaching infinity at 0 K. In contrast to oxidative addition of methane which is normal at all temperatures, the EIE for oxidative addition of H2 and D2 exhibits a transition from inverse to normal upon raising the temperature.	Methane	242-249	CD4 molecule	Homo sapiens	72-75	
15250683-1	2004	We present an ab initio direct dynamics trajectory study of the hydrogen abstraction reaction: H2CO+ + CD4 --> H2COD+ + CD3, with methane excited in two different distortion modes (nu4 and nu2).	Methane	133-140	CD4 molecule	Homo sapiens	103-106	
34658236-4	2021	We found that as the incident velocity of CH4 and CD4 increases, the sticking probabilities for both molecules on a CH4 condensed film decrease systematically, but that preferential sticking and condensation occur for CD4.	Methane	116-119	CD4 molecule	Homo sapiens	50-53	
34658236-8	2021	We propose that enhanced multi-phonon interactions and inelastic cross sections between the incident CD4 projectile and the CH4 film allow for more efficacious gas-surface energy transfer.	Methane	124-127	CD4 molecule	Homo sapiens	101-104	
34074750-6	2021	The experimental rates for methane conversion are first order in both CH4 and S2, consistent with the involvement of two S sites in the rate-determining methane C-H activation step, with a CD4/CH4 kinetic isotope effect of 1.78.	Methane	27-34	CD4 molecule	Homo sapiens	189-192	
34985901-2	2022	When methane (CH4) in the spatially homogeneous methane hydrate was replaced with deuterated methane (CD4), it showed a previously unrecognized strong anharmonic effect, identified by the Raman peak located at 1952.78 cm-1.	Methane	5-12	CD4 molecule	Homo sapiens	102-105	
34985901-2	2022	When methane (CH4) in the spatially homogeneous methane hydrate was replaced with deuterated methane (CD4), it showed a previously unrecognized strong anharmonic effect, identified by the Raman peak located at 1952.78 cm-1.	Methane	14-17	CD4 molecule	Homo sapiens	102-105