PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 31159274-2 2019 The present work described the study of a one-pot synthesis of 2,4,6-trisubstituted tetrahydropyran compounds promoted by the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate [BMIM][PF6] through a Barbier-Prins reaction between allyl bromide and aldehydes. 1-butyl-3-methylimidazolium hexafluorophosphate 139-186 sperm associated antigen 17 Homo sapiens 194-197 29470140-2 2018 Therefore, a new ionic liquid (IL) phase microextraction method using IL, 1-butyl-3-methylimidazoliumhexafluorophosphate [C4mim][PF6], as extracting solvent is proposed for simple and fast determination of low levels of TBZ in fruits and vegetables by spectrophotometry. 1-butyl-3-methylimidazolium hexafluorophosphate 74-120 sperm associated antigen 17 Homo sapiens 129-132 29636130-1 2018 The influence of functionalized multi-walled carbon nanotubes (fMWCNT) in the presence of 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM]PF6) in different ratios was investigated on the acetaminophen (ACOP) electrochemical determination. 1-butyl-3-methylimidazolium hexafluorophosphate 90-137 sperm associated antigen 17 Homo sapiens 145-148 27338127-3 2016 The extraction procedure was induced by the formation of cloudy solution, which was composed of 75 muL of 1-butyl-3-methylimidazolium hexafluorophosphate ([C4MIM]PF6 ) dispersed entirely into 5 mL sample solution with the assistance of ultrasound for 3 min and temperature at 40 C. Under optimal conditions, linearity of the five OPPs was obtained in the range of 0.09-200 ng/mL with correlation coefficients of 0.998 or more. 1-butyl-3-methylimidazolium hexafluorophosphate 106-153 sperm associated antigen 17 Homo sapiens 162-165 29331812-3 2018 Experiments reveal existence of new weak interactions involving the carbon and pi cloud of the imidazolium aromatic ring with fluoride of PF6 anion (i.e., C2--F-P and pi--F-P) in cmimPF6 but are absent in structurally similar prototype IL, bmimPF6. 1-butyl-3-methylimidazolium hexafluorophosphate 240-247 sperm associated antigen 17 Homo sapiens 138-141 29210700-6 2017 In this study, a hydrophobic IL, 1-butyl-3-methylimidazolium hexafluorophosphate ([Bmim]PF6), was immobilized in the pores of a solid polymeric support made of polyvinylidene fluoride. 1-butyl-3-methylimidazolium hexafluorophosphate 33-80 sperm associated antigen 17 Homo sapiens 88-91 27922206-1 2017 The impact of temperature-induced changes in solvent dynamics on the diffusion coefficient and standard rate constant k0 for heterogeneous electron transfer (ET) of ethylferrocene (EFc) in 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF6 ]) is investigated. 1-butyl-3-methylimidazolium hexafluorophosphate 189-236 sperm associated antigen 17 Homo sapiens 245-248 25280335-1 2015 A green and sensitive temperature controlled dispersive liquid-liquid microextraction (TIL-DLLME) methodology based on the application of ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate, [C4mim][PF6], as an extractant solvent was proposed for the preconcentration of trace levels of aluminium (Al(3+)) in scalp hair samples of Alzheimer"s (AD) patients, prior to analyzing by flame atomic absorption spectrometry (FAAS). 1-butyl-3-methylimidazolium hexafluorophosphate 151-198 sperm associated antigen 17 Homo sapiens 208-211 25469424-4 2014 Cyclic voltammetry showed that EOTT could be electropolymerized at a lower oxidation potential in BmimPF6 (~1.0 V vs Ag/AgCl) due to several advantanges of RTIL BmimPF6 itself, such as high intrinsic conductivity and mild chemical conditions, etc., and the resulting PEOTT film exhibited compact morphology with better electroactivity and stability and higher electrical conductivity. 1-butyl-3-methylimidazolium hexafluorophosphate 98-105 sperm associated antigen 17 Homo sapiens 156-168 24650158-2 2014 Simulations of an isolated water molecule embedded in 1-butyl-3-methyl imidazolium hexafluorophosphate, [bmim][PF6], were performed to shed insight into the nature of these coupled water-ion dynamics. 1-butyl-3-methylimidazolium hexafluorophosphate 54-102 sperm associated antigen 17 Homo sapiens 111-114 23241082-0 2013 A comparative study of the rotational dynamics of PF6(-) anions in the crystals and liquid states of 1-butyl-3-methylimidazolium hexafluorophosphate: results from 31P NMR spectroscopy. 1-butyl-3-methylimidazolium hexafluorophosphate 101-148 sperm associated antigen 17 Homo sapiens 50-53 23799234-1 2013 Pt-Pd bimetallic alloy nanoparticles (NPs) dispersed in the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate (Pt-Pd-BMI PF6) were employed together with a peroxidase (PO) enzyme from cauliflower immobilized on nanoclay for the development of a new biosensor for polyphenol determination by square-wave voltammetry (SWV). 1-butyl-3-methylimidazolium hexafluorophosphate 73-120 sperm associated antigen 17 Homo sapiens 132-135 20684639-1 2010 Solvation structure and dynamics of a saturated solution of carbon dioxide in the room-temperature ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate (BMI+PF6-) at 313 K and 0.15 kbar are investigated via molecular dynamics computer simulations by employing a diatomic probe solute. 1-butyl-3-methylimidazolium hexafluorophosphate 112-159 sperm associated antigen 17 Homo sapiens 165-168 22503861-1 2012 Density functional calculations have been performed to explore the interactions of thiophene and two ionic liquids of 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM]+[PF6]-) and 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM]+[BF4]-). 1-butyl-3-methylimidazolium hexafluorophosphate 118-165 sperm associated antigen 17 Homo sapiens 175-178 22500444-1 2011 A novel method was developed for trace analysis of aliphatic aldehydes and ketones in water-based adhesive based on 2,4-dinitrophenylhydrazine (DNPH) direct derivatization-1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM] PF6) preconcentration coupled with high performance liquid chromatography (HPLC). 1-butyl-3-methylimidazolium hexafluorophosphate 172-219 sperm associated antigen 17 Homo sapiens 228-231 12125560-1 2002 The room temperature ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate, [C4mim][PF6] was found to be an efficient plasticizer for poly(methyl methacrylate), prepared by in situ radical polymerization in the ionic liquid medium; the polymers have physical characteristics comparable with those containing traditional plasticizers and retain greater thermal stability. 1-butyl-3-methylimidazolium hexafluorophosphate 35-82 sperm associated antigen 17 Homo sapiens 92-95 19950961-1 2010 We have investigated phase-transition behaviors of a typical room temperature ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate ([C(4)mim]PF(6)), using calorimetric and Raman spectroscopic techniques. 1-butyl-3-methylimidazolium hexafluorophosphate 92-139 sperm associated antigen 17 Homo sapiens 150-155 19415917-3 2009 Properties of mixtures of PEG with a common IL 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]) are assessed via responses of three fluorescence probes: pyrene (Py) and pyrene-1-carboxaldehyde (PyCHO) are the dipolarity sensing probes and 1,3-bis-(1-pyrenyl) propane (BPP) is the probe for microfluidity. 1-butyl-3-methylimidazolium hexafluorophosphate 47-94 sperm associated antigen 17 Homo sapiens 103-106 26609613-6 2009 As further validation of the newly developed parameters, the Kemp elimination reaction of benzisoxazole via piperidine was computed in 1-butyl-3-methylimidazolium hexafluorophosphate [BMIM][PF6] using mixed quantum and molecular mechanics (QM/MM) simulations and was found to give close agreement with the experimental free energy of activation. 1-butyl-3-methylimidazolium hexafluorophosphate 135-182 sperm associated antigen 17 Homo sapiens 190-193 26609613-6 2009 As further validation of the newly developed parameters, the Kemp elimination reaction of benzisoxazole via piperidine was computed in 1-butyl-3-methylimidazolium hexafluorophosphate [BMIM][PF6] using mixed quantum and molecular mechanics (QM/MM) simulations and was found to give close agreement with the experimental free energy of activation. 1-butyl-3-methylimidazolium hexafluorophosphate 184-188 sperm associated antigen 17 Homo sapiens 190-193 19002319-1 2008 The preliminary results presented here show that gamma-irradiation of ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate ([C4mim][PF6]) markedly decreases Sr2+ partitioning in the crown ether/[C4mim][PF6] extraction phase due to the competition between radiation-generated H+ and Sr2+ to interact with the crown ether, however, washing irradiated [C4mim][PF6] with water gives a simple way of recycling the ionic liquid. 1-butyl-3-methylimidazolium hexafluorophosphate 83-130 sperm associated antigen 17 Homo sapiens 140-143 19002319-1 2008 The preliminary results presented here show that gamma-irradiation of ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate ([C4mim][PF6]) markedly decreases Sr2+ partitioning in the crown ether/[C4mim][PF6] extraction phase due to the competition between radiation-generated H+ and Sr2+ to interact with the crown ether, however, washing irradiated [C4mim][PF6] with water gives a simple way of recycling the ionic liquid. 1-butyl-3-methylimidazolium hexafluorophosphate 83-130 sperm associated antigen 17 Homo sapiens 210-213 19002319-1 2008 The preliminary results presented here show that gamma-irradiation of ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate ([C4mim][PF6]) markedly decreases Sr2+ partitioning in the crown ether/[C4mim][PF6] extraction phase due to the competition between radiation-generated H+ and Sr2+ to interact with the crown ether, however, washing irradiated [C4mim][PF6] with water gives a simple way of recycling the ionic liquid. 1-butyl-3-methylimidazolium hexafluorophosphate 83-130 sperm associated antigen 17 Homo sapiens 210-213 18306766-2 2007 Photochemical properties of the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate [bmim][PF6] and its binary mixed solutions with MeCN were investigated by laser photolysis technique at an excitation wavelength of 355 nm, using anthraquinone (AQ) as a probe molecule. 1-butyl-3-methylimidazolium hexafluorophosphate 45-92 sperm associated antigen 17 Homo sapiens 100-103 18306766-2 2007 Photochemical properties of the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate [bmim][PF6] and its binary mixed solutions with MeCN were investigated by laser photolysis technique at an excitation wavelength of 355 nm, using anthraquinone (AQ) as a probe molecule. 1-butyl-3-methylimidazolium hexafluorophosphate 94-99 sperm associated antigen 17 Homo sapiens 100-103 18306766-3 2007 It was indicated that [bmim] [PF6] itself participates in the reaction with 3AQ*. 1-butyl-3-methylimidazolium hexafluorophosphate 22-27 sperm associated antigen 17 Homo sapiens 30-33 16971984-1 2006 We report a Molecular Dynamics (MD) study of the interface between water and the hygroscopic room temperature Ionic Liquid "IL" [BMI][PF6] (1-butyl-3-methyl-imidazolium hexafluorophosphate), comparing the TIP3P, SPC/E and TIP5P models for water and two IL models where the ions are +/-1 or +/-0.9 charged. 1-butyl-3-methylimidazolium hexafluorophosphate 140-188 sperm associated antigen 17 Homo sapiens 134-137 15214415-1 2004 The molecular structure and rotational motion of the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF6]) were studied over a wide temperature range using the Bloembergen-Purcell-Pound 13C NMR spin-lattice relaxation method and NOE factors. 1-butyl-3-methylimidazolium hexafluorophosphate 66-113 sperm associated antigen 17 Homo sapiens 122-125 12948138-1 2003 The voltammetry of ferrocene (Fc) and Fc+ in the room-temperature ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM x PF6) has been studied when solid is adhered to glassy carbon or platinum disk electrodes. 1-butyl-3-methylimidazolium hexafluorophosphate 80-127 sperm associated antigen 17 Homo sapiens 136-139 34661007-11 2021 The adsorption ability on the bentonite surface through electrostatic attraction, higher activity coefficient, and less electronegativity of PF6 - anion played a vital role in attaining such superior inhibition performance by BMIMPF6. 1-butyl-3-methylimidazolium hexafluorophosphate 226-233 sperm associated antigen 17 Homo sapiens 141-144 32115953-1 2020 Novel luminescent vesicles with enhanced emission were successfully achieved for the first time by an amphiphilic europium complex through its spontaneously self-assembly in an ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate ([Bmim]PF6). 1-butyl-3-methylimidazolium hexafluorophosphate 191-238 sperm associated antigen 17 Homo sapiens 246-249