PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 12686486-4 2003 LD of the chloride salt complexes produced loss of a single bpy ligand, chloride attachment, and losses of H. Spectra of [Ru(bpy(3)]X(2) where X = BF(4)(-), CF(3)SO(3)(-), and SCN(-) were also collected using LD and compared with the spectra for Cl(2) and PF(6) salts. Chlorides 10-23 sperm associated antigen 17 Homo sapiens 256-261 20503220-4 2010 The complexes [Pd(L1)Cl](PF(6)) and [Pt(L1)Cl](PF(6)), containing a nonsymmetrical NCN" pincer ligand, are square planar with a chloride trans to the carbene donor. Chlorides 128-136 sperm associated antigen 17 Homo sapiens 47-52 17592598-5 2007 In chlorinated solvents such as dichloromethane or chloroform, [5]PF(6) rapidly abstracts chloride by reductive dechlorination of the solvent to yield [(TL(tBu))CuCl]PF6, [8]PF6 quantitatively. Chlorides 90-98 sperm associated antigen 17 Homo sapiens 166-169 17592598-5 2007 In chlorinated solvents such as dichloromethane or chloroform, [5]PF(6) rapidly abstracts chloride by reductive dechlorination of the solvent to yield [(TL(tBu))CuCl]PF6, [8]PF6 quantitatively. Chlorides 90-98 sperm associated antigen 17 Homo sapiens 174-177 15053663-5 2004 This stripping protocol was found to detect ppb levels of chloride in [C4mim][BF4], [C4mim][NTf2], and [C4mim][PF6]. Chlorides 58-66 sperm associated antigen 17 Homo sapiens 111-114 15053663-6 2004 Although other methods for chloride have been reported for [BF4](-)- and [PF6](-)-based ionic liquids, no methods have been reported for [NTf2](-) ionic liquids. Chlorides 27-35 sperm associated antigen 17 Homo sapiens 74-77 18817378-5 2008 The abstraction of a chloride ion, using [Ag(MeCN)4](PF6), from each copper site in [L(2)(CuCl2)2], affords the new complex, [L(2)(CuCl)2](PF6)2, in which the two copper(II) ions are separated by "N-P=N-P=N" phosphazene bridges. Chlorides 21-29 sperm associated antigen 17 Homo sapiens 53-56 18817378-5 2008 The abstraction of a chloride ion, using [Ag(MeCN)4](PF6), from each copper site in [L(2)(CuCl2)2], affords the new complex, [L(2)(CuCl)2](PF6)2, in which the two copper(II) ions are separated by "N-P=N-P=N" phosphazene bridges. Chlorides 21-29 sperm associated antigen 17 Homo sapiens 139-142 17589989-2 2007 At a difference of chloride, in the case of PF(6)(-) and TFPB(-) anions the conversion occurs with the intermediacy of a species, which has been assigned to a monoacid derivative on the basis of UV/vis absorption, fluorescence emission (static and dynamic), and resonance light scattering. Chlorides 19-27 sperm associated antigen 17 Homo sapiens 44-49 17589989-5 2007 Gas-phase thermodynamic calculations on the chloride species provide an estimate of the Gibbs free energy changes associated with the two protonation steps, supporting the observed different behavior of this anion with respect to PF(6)(-) and TFPB(-). Chlorides 44-52 sperm associated antigen 17 Homo sapiens 230-235 15733006-13 2005 Irradiation of 2c in the presence of added chloride affords [(phen)(o-C6H4-2-py)ClRuIIIORuIVCl(o-C6H4-2-py)(phen)]PF6, a first mu-oxo-bridged mixed valent dimer with a cyclometalated unit. Chlorides 43-51 sperm associated antigen 17 Homo sapiens 114-117 12686486-4 2003 LD of the chloride salt complexes produced loss of a single bpy ligand, chloride attachment, and losses of H. Spectra of [Ru(bpy(3)]X(2) where X = BF(4)(-), CF(3)SO(3)(-), and SCN(-) were also collected using LD and compared with the spectra for Cl(2) and PF(6) salts. Chlorides 10-18 sperm associated antigen 17 Homo sapiens 256-261 12693212-13 2003 Additionally, the chloride ligands of the monometallic complexes of "in"-[Ru(trpy)(dpo)Cl](PF6) (1d), "in"-[Ru(trpy)(4,4"-Me2dpo)Cl](PF6)] (1e), and "out"-[Ru(trpy)(dpo)Cl](PF6) (2d) were substituted with water to form their respective aqua complexes, 4d, 4e, and 5d. Chlorides 18-26 sperm associated antigen 17 Homo sapiens 91-94 12693212-13 2003 Additionally, the chloride ligands of the monometallic complexes of "in"-[Ru(trpy)(dpo)Cl](PF6) (1d), "in"-[Ru(trpy)(4,4"-Me2dpo)Cl](PF6)] (1e), and "out"-[Ru(trpy)(dpo)Cl](PF6) (2d) were substituted with water to form their respective aqua complexes, 4d, 4e, and 5d. Chlorides 18-26 sperm associated antigen 17 Homo sapiens 133-136 12693212-13 2003 Additionally, the chloride ligands of the monometallic complexes of "in"-[Ru(trpy)(dpo)Cl](PF6) (1d), "in"-[Ru(trpy)(4,4"-Me2dpo)Cl](PF6)] (1e), and "out"-[Ru(trpy)(dpo)Cl](PF6) (2d) were substituted with water to form their respective aqua complexes, 4d, 4e, and 5d. Chlorides 18-26 sperm associated antigen 17 Homo sapiens 133-136 32130744-5 2020 Interlocked analogues were also prepared, and preliminary luminescent chloride anion spectrometric titrations with 12 Ru (PF 6 ) 2 demonstrate a marked increase in halide binding affinity due to the complementary chloride binding pocket of the [2]rotaxane. Chlorides 70-78 sperm associated antigen 17 Homo sapiens 122-126 32130744-5 2020 Interlocked analogues were also prepared, and preliminary luminescent chloride anion spectrometric titrations with 12 Ru (PF 6 ) 2 demonstrate a marked increase in halide binding affinity due to the complementary chloride binding pocket of the [2]rotaxane. Chlorides 213-221 sperm associated antigen 17 Homo sapiens 122-126 31112175-8 2019 Chloride abstraction of 5 with TlPF6 in tetrahydrofuran (thf) afforded [Ir(tpp)(PPh3)(thf)](PF6) (6) that reacted with CsOH H2O and Li2S to give the hydroxo [Ir(tpp)(OH)(PPh3)] (7) and hydrosulfido [Ir(tpp)(PPh3)(SH)] (8) complexes, respectively. Chlorides 0-8 sperm associated antigen 17 Homo sapiens 33-36 31891094-1 2019 Removal of chloride from Cp*Ir(glycinato)Cl in noncoordinating solvents with Ag[PF6] or Tl[PF6] leads to the formation of a closed octametallic loop of cations. Chlorides 11-19 sperm associated antigen 17 Homo sapiens 80-83 31891094-1 2019 Removal of chloride from Cp*Ir(glycinato)Cl in noncoordinating solvents with Ag[PF6] or Tl[PF6] leads to the formation of a closed octametallic loop of cations. Chlorides 11-19 sperm associated antigen 17 Homo sapiens 91-94 28657743-1 2017 A highly useful, visible-light-driven carboxylation of aryl bromides and chlorides with CO2 was realized using a combination of Pd(OAc)2 as a carboxylation catalyst and Ir(ppy)2(dtbpy)(PF6) as a photoredox catalyst. Chlorides 73-82 sperm associated antigen 17 Homo sapiens 185-188 31458240-1 2018 Removal of chloride from CoCl2 with TlPF6 in acetonitrile, followed by addition of excess nitrosobenzene, yielded the eight-coordinate cobalt(II) complex salt [Co{Ph(O)NN(O)Ph}4](PF6)2, shown by single-crystal X-ray analysis to have a distorted tetragonal geometry. Chlorides 11-19 sperm associated antigen 17 Homo sapiens 38-41 31458240-3 2018 The use of TlPF6 to generate solvated metal complex cations from chloride salts or chlorido complexes, followed by the addition of nitrosobenzene, is shown to be a useful synthetic strategy for the preparation of azodioxide complex cations with the noncoordinating, diamagnetic PF6 - counteranion. Chlorides 65-79 sperm associated antigen 17 Homo sapiens 13-16 30400193-7 2018 Comparative cyclic voltammetry studies with [NBu4][PF6] and [NBu4][Cl] as supporting electrolytes indicate that the chloride ligand can be lost from 3 by ligand exchange upon reduction. Chlorides 116-124 sperm associated antigen 17 Homo sapiens 51-54 26148842-2 2015 The binding is up to (3.6 +- 0.2) x 10(10) M(-1) in acetonitrile (for pentafoil knot [2 Cl](PF6)9), making these topologically complex host molecules some of the strongest synthetic noncovalent binders of halide anions measured to date, comparable in chloride ion affinity to silver salts. Chlorides 251-259 sperm associated antigen 17 Homo sapiens 92-97 25501466-1 2015 Ten cationic heteroleptic iridium(III) complexes, [Ir(emptz)2(N^N)](PF6) were prepared from a cyclometalated iridium bridged-chloride dimer involving two ethyl-4-methylphenylthiazole-5-carboxylate (emptz) ligands. Chlorides 125-133 sperm associated antigen 17 Homo sapiens 68-71 25742181-1 2015 A slow hydrolyzing imidazole-based Ru(II)-arene complex [(L)Ru(II)(eta(6)-p-cym)(Cl)](PF6) (1) with excellent stability in the extracellular chloride concentration shows better activity under hypoxia and strong resistance to glutathione (GSH) in vitro under hypoxic conditions. Chlorides 141-149 sperm associated antigen 17 Homo sapiens 86-89 24605817-4 2014 The total ion charges obtained thus range between -0.6e for chloride and -0.8e for the PF6 ion. Chlorides 60-68 sperm associated antigen 17 Homo sapiens 87-90