PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 19715289-1 2009 The reaction of (trifluoromethyl)dimethylphenylsilylacetylene and (eta(2)-propene)Ti(O(i)Pr)(2) generated in situ smoothly proceeded giving the corresponding (eta(2)-1-dimethylphenylsilyl-2-trifluoromethylalkyne)Ti(O(i)Pr)(2), which reacted with aldehydes and ketones to afford the corresponding addition products in good yields with good to excellent regioselectivity. Ketones 260-267 DNA polymerase iota Homo sapiens 67-72 19715289-1 2009 The reaction of (trifluoromethyl)dimethylphenylsilylacetylene and (eta(2)-propene)Ti(O(i)Pr)(2) generated in situ smoothly proceeded giving the corresponding (eta(2)-1-dimethylphenylsilyl-2-trifluoromethylalkyne)Ti(O(i)Pr)(2), which reacted with aldehydes and ketones to afford the corresponding addition products in good yields with good to excellent regioselectivity. Ketones 260-267 DNA polymerase iota Homo sapiens 159-164 33241621-5 2021 Preliminary mechanistic studies suggest that a rare enantioselective eta 2 -coordinating activation of ketone carbonyls is involved. Ketones 103-109 DNA polymerase iota Homo sapiens 69-74 33433538-0 2021 Experimental and theoretical investigation of the reactivity of [(BDI*)Ti(Cl){eta2-P(SiMe3)-PiPr2}] towards selected ketones. Ketones 117-124 DNA polymerase iota Homo sapiens 78-82 33433538-1 2021 In this work, we report a new type of reactivity of [(BDI*)Ti(Cl){eta2-P(SiMe3)-PiPr2}] (1) towards ketones (BDI* = 2,6-diisopropylphenyl-beta-methyldiketiminate ligand). Ketones 100-107 DNA polymerase iota Homo sapiens 66-70 33456103-3 2020 When the EWG contains a pi bond (nitriles, aldehydes, ketones, ester), eta 2 coordination occurs predominantly on the nonaromatic functional group. Ketones 54-61 DNA polymerase iota Homo sapiens 71-76 22407236-0 2012 Intramolecular reductive ketone-alkynoate coupling reaction promoted by (eta2-propene)titanium. Ketones 25-31 DNA polymerase iota Homo sapiens 73-77