PMID-sentid	Pub_year	Sent_text		comp_official_name	comp_offsetprotein_name	organism	prot_offset
22407236-0	2012	Intramolecular reductive ketone-alkynoate coupling reaction promoted by (eta2-propene)titanium.	Ketones	25-31	DNA polymerase iota	Homo sapiens	73-77	
33241621-5	2021	Preliminary mechanistic studies suggest that a rare enantioselective eta 2 -coordinating activation of ketone carbonyls is involved.	Ketones	103-109	DNA polymerase iota	Homo sapiens	69-74	
33433538-0	2021	Experimental and theoretical investigation of the reactivity of [(BDI*)Ti(Cl){eta2-P(SiMe3)-PiPr2}] towards selected ketones.	Ketones	117-124	DNA polymerase iota	Homo sapiens	78-82	
33433538-1	2021	In this work, we report a new type of reactivity of [(BDI*)Ti(Cl){eta2-P(SiMe3)-PiPr2}] (1) towards ketones (BDI* = 2,6-diisopropylphenyl-beta-methyldiketiminate ligand).	Ketones	100-107	DNA polymerase iota	Homo sapiens	66-70	
33456103-3	2020	When the EWG contains a pi bond (nitriles, aldehydes, ketones, ester), eta 2 coordination occurs predominantly on the nonaromatic functional group.	Ketones	54-61	DNA polymerase iota	Homo sapiens	71-76	
19715289-1	2009	The reaction of (trifluoromethyl)dimethylphenylsilylacetylene and (eta(2)-propene)Ti(O(i)Pr)(2) generated in situ smoothly proceeded giving the corresponding (eta(2)-1-dimethylphenylsilyl-2-trifluoromethylalkyne)Ti(O(i)Pr)(2), which reacted with aldehydes and ketones to afford the corresponding addition products in good yields with good to excellent regioselectivity.	Ketones	260-267	DNA polymerase iota	Homo sapiens	67-72	
19715289-1	2009	The reaction of (trifluoromethyl)dimethylphenylsilylacetylene and (eta(2)-propene)Ti(O(i)Pr)(2) generated in situ smoothly proceeded giving the corresponding (eta(2)-1-dimethylphenylsilyl-2-trifluoromethylalkyne)Ti(O(i)Pr)(2), which reacted with aldehydes and ketones to afford the corresponding addition products in good yields with good to excellent regioselectivity.	Ketones	260-267	DNA polymerase iota	Homo sapiens	159-164