PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 34119969-3 2021 Herein, we confirmed that Co(II)/PAA reaction enables the generation of Co(IV) at acidic conditions based on multiple lines of evidences, including methyl phenyl sulfoxide (PMSO)-based probe experiments, 18O isotope-labeling technique, and in situ Raman spectroscopy. methyl phenyl sulfoxide 148-171 mitochondrially encoded cytochrome c oxidase II Homo sapiens 26-32 33225681-2 2020 However, in this study, it was surprisingly found that methyl phenyl sulfoxide (PMSO) was readily oxidized to the corresponding sulfone (PMSO2) with a transformation ratio of ~100% under acidic conditions, which strongly implied the generation of high-valent cobalt-oxo species [Co(IV)] instead of SO4 - in the Co(II)/PMS process. methyl phenyl sulfoxide 55-78 mitochondrially encoded cytochrome c oxidase II Homo sapiens 311-317