PMID-sentid	Pub_year	Sent_text		comp_official_name	comp_offsetprotein_name	organism	prot_offset
31913025-1	2020	Treatment of [Ir(PPh3)3Cl] with 2-[5-(pyridin-2-yl)-1H-pyrrol-2-yl]pyridine (Hdpp) in refluxing toluene affords an unexpected pyrrole-metalated iridium(III) hydride complex, [Ir(K2C,N-dpp)(H)(Cl)(PPh3)2] (1), via Cpyrrole-H activation, while the presence of the base KOtBu as the deprotonation reagent produces a pyridine-metalated iridium(III) hydride complex, [Ir(K3C,N,N-dpp)(H)(PPh3)2] (2), via Cpyridine-H activation.	Toluene	96-103	protein phosphatase 4 catalytic subunit	Homo sapiens	17-21	
17378557-1	2007	Sn94- reacts with Pt(PPh3)4 in ethylenediamine/toluene solvent mixtures in the presence of 2,2,2-cryptand to give four different complexes: "Rudolph"s complex" of proposed formula [Sn9Pt(PPh3)x]4- (2), the previously reported [Pt@Sn9Pt(PPh3)]2- ion (3), and the title complexes Pt2@Sn174- (4) and Pt@Sn9H3- (5).	Toluene	47-54	protein phosphatase 4 catalytic subunit	Homo sapiens	21-25	
31913025-2	2020	Treatment of [Ir(PPh3)3Cl] prepared by a convenient method with Hdpp in the presence of KOtBu under the refluxing mixture solvent toluene/methanol (2:1, v/v) generates the N,N-chelating complex [Ir(K2N,N-dpp)(H)(Cl)(PPh3)2] (3) together with 1 and the N,N-chelating dihydride complex [Ir(K2N,N-dpp)(H)2(PPh3)2] (4).	Toluene	130-137	protein phosphatase 4 catalytic subunit	Homo sapiens	17-21	
31913025-2	2020	Treatment of [Ir(PPh3)3Cl] prepared by a convenient method with Hdpp in the presence of KOtBu under the refluxing mixture solvent toluene/methanol (2:1, v/v) generates the N,N-chelating complex [Ir(K2N,N-dpp)(H)(Cl)(PPh3)2] (3) together with 1 and the N,N-chelating dihydride complex [Ir(K2N,N-dpp)(H)2(PPh3)2] (4).	Toluene	130-137	protein phosphatase 4 catalytic subunit	Homo sapiens	216-220	
31913025-2	2020	Treatment of [Ir(PPh3)3Cl] prepared by a convenient method with Hdpp in the presence of KOtBu under the refluxing mixture solvent toluene/methanol (2:1, v/v) generates the N,N-chelating complex [Ir(K2N,N-dpp)(H)(Cl)(PPh3)2] (3) together with 1 and the N,N-chelating dihydride complex [Ir(K2N,N-dpp)(H)2(PPh3)2] (4).	Toluene	130-137	protein phosphatase 4 catalytic subunit	Homo sapiens	216-220	
31913025-1	2020	Treatment of [Ir(PPh3)3Cl] with 2-[5-(pyridin-2-yl)-1H-pyrrol-2-yl]pyridine (Hdpp) in refluxing toluene affords an unexpected pyrrole-metalated iridium(III) hydride complex, [Ir(K2C,N-dpp)(H)(Cl)(PPh3)2] (1), via Cpyrrole-H activation, while the presence of the base KOtBu as the deprotonation reagent produces a pyridine-metalated iridium(III) hydride complex, [Ir(K3C,N,N-dpp)(H)(PPh3)2] (2), via Cpyridine-H activation.	Toluene	96-103	protein phosphatase 4 catalytic subunit	Homo sapiens	196-200	
31913025-1	2020	Treatment of [Ir(PPh3)3Cl] with 2-[5-(pyridin-2-yl)-1H-pyrrol-2-yl]pyridine (Hdpp) in refluxing toluene affords an unexpected pyrrole-metalated iridium(III) hydride complex, [Ir(K2C,N-dpp)(H)(Cl)(PPh3)2] (1), via Cpyrrole-H activation, while the presence of the base KOtBu as the deprotonation reagent produces a pyridine-metalated iridium(III) hydride complex, [Ir(K3C,N,N-dpp)(H)(PPh3)2] (2), via Cpyridine-H activation.	Toluene	96-103	protein phosphatase 4 catalytic subunit	Homo sapiens	196-200	
31458047-5	2018	The reaction of OXLH2 with [RuII(PPh3)3Cl2] in boiling toluene in air affords an orthometalated OXL2- complex of ruthenium(III), trans-[(OXL2-)RuIII(PPh3)2(Cl)] (1), whereas the similar reaction with [OsII(PPh3)3Br2] yields an orthometalated OXL - complex, cis-[(OXL -)OsIII(PPh3)Br2] (2).	Toluene	55-62	protein phosphatase 4 catalytic subunit	Homo sapiens	33-37	
31552976-4	2019	1 and 2 reacted with stoichiometric amounts of tristriphenylphosphine platinum(0) [Pt(PPh3)3] under toluene refluxing conditions leading to formation of Pt(ii) distorted square-planar complexes [Ph2P(o-C6H4CH2)Pt(SnR3)(PPh3)], (R = Ph, 4; R = Me, 5), each bearing a five-membered carbometallated ring resulting from Pt coordination to P and the benzylic C sp3 atom of the ligand architecture rather than from activation of the terminal Sn-C carbon bonds of the phenyl or methyl substituents which would have rendered six-membered rings.	Toluene	100-107	protein phosphatase 4 catalytic subunit	Homo sapiens	86-90	
31458047-5	2018	The reaction of OXLH2 with [RuII(PPh3)3Cl2] in boiling toluene in air affords an orthometalated OXL2- complex of ruthenium(III), trans-[(OXL2-)RuIII(PPh3)2(Cl)] (1), whereas the similar reaction with [OsII(PPh3)3Br2] yields an orthometalated OXL - complex, cis-[(OXL -)OsIII(PPh3)Br2] (2).	Toluene	55-62	protein phosphatase 4 catalytic subunit	Homo sapiens	149-153	
31458047-5	2018	The reaction of OXLH2 with [RuII(PPh3)3Cl2] in boiling toluene in air affords an orthometalated OXL2- complex of ruthenium(III), trans-[(OXL2-)RuIII(PPh3)2(Cl)] (1), whereas the similar reaction with [OsII(PPh3)3Br2] yields an orthometalated OXL - complex, cis-[(OXL -)OsIII(PPh3)Br2] (2).	Toluene	55-62	protein phosphatase 4 catalytic subunit	Homo sapiens	149-153	
31458047-5	2018	The reaction of OXLH2 with [RuII(PPh3)3Cl2] in boiling toluene in air affords an orthometalated OXL2- complex of ruthenium(III), trans-[(OXL2-)RuIII(PPh3)2(Cl)] (1), whereas the similar reaction with [OsII(PPh3)3Br2] yields an orthometalated OXL - complex, cis-[(OXL -)OsIII(PPh3)Br2] (2).	Toluene	55-62	protein phosphatase 4 catalytic subunit	Homo sapiens	149-153	
24170306-1	2014	Studies examining the photochemical reactivity of CpRu(PPh3)2Cl and CpRu(PPh3)2Me towards the two electron donor ligands PEt3, C2H4, DMSO, the CH bond activatable reagents tetrahydrofuran, toluene, and pyridine, and the SiH bond activatable reagents HSiEt3 and HSi(Me)2CH=CH2) are presented.	Toluene	189-196	protein phosphatase 4 catalytic subunit	Homo sapiens	55-59	
24170306-1	2014	Studies examining the photochemical reactivity of CpRu(PPh3)2Cl and CpRu(PPh3)2Me towards the two electron donor ligands PEt3, C2H4, DMSO, the CH bond activatable reagents tetrahydrofuran, toluene, and pyridine, and the SiH bond activatable reagents HSiEt3 and HSi(Me)2CH=CH2) are presented.	Toluene	189-196	protein phosphatase 4 catalytic subunit	Homo sapiens	73-77	
24170306-4	2014	However, when these reactions are followed by in situ laser irradiation (325 nm source) at low temperature, three solvent activated isomers (ortho, meta and para) of CpRu(PPh3)2(C6H4Me) are detected in toluene in addition to eta(1)- and eta(3)-coordinated benzyl species.	Toluene	202-209	protein phosphatase 4 catalytic subunit	Homo sapiens	171-175