PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 29323365-3 2018 In contrast, reaction of 1a with [Ir2Cl2(COD)2] (COD = 1,5-cyclo-octadiene) affords the complex [IrCl(COD){kappa2-P,P"-H2C(NCH2PPh2)2C10H6}], thermolysis of which affords cyclo-octene and the pincer-NHC complex [IrCl{kappa3-C,P,P"-C(NCH2PPh2)2C10H6}]. Carbon 223-225 COD2 Homo sapiens 41-46 27629250-1 2016 Various aryl-, alkenyl-, and/or alkyllithium species reacted smoothly with aryl and/or benzyl ethers with cleavage of the inert C-O bond to afford cross-coupled products, catalyzed by commercially available [Ni(cod)2 ] (cod=1,5-cyclooctadiene) catalysts with N-heterocyclic carbene (NHC) ligands. Carbon 128-129 COD2 Homo sapiens 211-216 33104370-2 2020 The key features of the strategy include construction of the C16 quaternary carbon center by a highly diastereoselective Grignard reagent addition to N-tert-butanesulfinylimine, sequential site-selective amidation and N-alkylation to form the C and E rings, and [Ni(COD)2]-mediated Michael addition to close the D ring. Carbon 76-82 COD2 Homo sapiens 262-271 32243173-2 2020 By utilizing Ni(cod)2 as a catalyst precursor, DPEphos as a ligand and 4 A molecular sieves as additives, the dearomatization reaction of beta-naphthols with aryl allylic alcohols proceeded smoothly under mild conditions, affording the desired beta-naphthalenone products bearing a quaternary carbon center in moderate to good yields with excellent linear selectivity. Carbon 293-299 COD2 Homo sapiens 13-21