PMID-sentid	Pub_year	Sent_text		comp_official_name	comp_offsetprotein_name	organism	prot_offset
33104370-2	2020	The key features of the strategy include construction of the C16 quaternary carbon center by a highly diastereoselective Grignard reagent addition to N-tert-butanesulfinylimine, sequential site-selective amidation and N-alkylation to form the C and E rings, and [Ni(COD)2]-mediated Michael addition to close the D ring.	Carbon	76-82	COD2	Homo sapiens	262-271	
32243173-2	2020	By utilizing Ni(cod)2 as a catalyst precursor, DPEphos as a ligand and 4 A molecular sieves as additives, the dearomatization reaction of beta-naphthols with aryl allylic alcohols proceeded smoothly under mild conditions, affording the desired beta-naphthalenone products bearing a quaternary carbon center in moderate to good yields with excellent linear selectivity.	Carbon	293-299	COD2	Homo sapiens	13-21	
27629250-1	2016	Various aryl-, alkenyl-, and/or alkyllithium species reacted smoothly with aryl and/or benzyl ethers with cleavage of the inert C-O bond to afford cross-coupled products, catalyzed by commercially available [Ni(cod)2 ] (cod=1,5-cyclooctadiene) catalysts with N-heterocyclic carbene (NHC) ligands.	Carbon	128-129	COD2	Homo sapiens	211-216	
29323365-3	2018	In contrast, reaction of 1a with [Ir2Cl2(COD)2] (COD = 1,5-cyclo-octadiene) affords the complex [IrCl(COD){kappa2-P,P"-H2C(NCH2PPh2)2C10H6}], thermolysis of which affords cyclo-octene and the pincer-NHC complex [IrCl{kappa3-C,P,P"-C(NCH2PPh2)2C10H6}].	Carbon	223-225	COD2	Homo sapiens	41-46