PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 29909614-4 2018 Herein, we report a combined experimental and theoretical study on the Ni(0)/PCy3-catalyzed silylation of aryl pivalates with CuF2/CsF additives that reveals the involvement of unorthodox dinickel oxidative addition complexes in C-O bond cleavage and their relevance in C-Si bond formation. Silicon 272-274 colony stimulating factor 2 Homo sapiens 131-134 31950736-1 2019 Treatment of the SiMe3 -protected dichloro-rhenium carbyne complexes Re{ CCH=C(R)C CSiMe3 }Cl2 (PMe2 Ph)3 (R = CMe3 , 1-adamantyl) with CsF in methanol directly afforded the 12-membered metallacycles {ReCl(PMe2 Ph)3 }2 { CCH=C(R)C C-}2 . Silicon 17-22 colony stimulating factor 2 Homo sapiens 136-139 11944694-11 2002 The CsF/CaO/Si system exhibited the complete destruction of CF4 at as low as 600 degrees C. The solid product analysis by X-ray diffraction (XRD) showed the formation of CaF2 and the depletion of Si with black carbon particles formed in the solid reagent residue. Silicon 12-14 colony stimulating factor 2 Homo sapiens 4-7 11944694-11 2002 The CsF/CaO/Si system exhibited the complete destruction of CF4 at as low as 600 degrees C. The solid product analysis by X-ray diffraction (XRD) showed the formation of CaF2 and the depletion of Si with black carbon particles formed in the solid reagent residue. Silicon 196-198 colony stimulating factor 2 Homo sapiens 4-7