PMID-sentid	Pub_year	Sent_text		comp_official_name	comp_offsetprotein_name	organism	prot_offset
15898752-3	2005	Treatment of (eta5-C5Me5)(CO)2W(mu-eta1:eta2-CCtBu)(SiPh2) with acetone resulted in acetone insertion into the silicon-alkynyl linkage followed by intramolecular C-H activation of the tBu group to give the chelate-type alkyl-alkene complex, (eta5-C5Me5)(CO)2W(eta1:eta2-CH2CMe2C=CHSiPh2OCMe2).	Silicon	111-118	DNA polymerase iota	Homo sapiens	40-44	
15898752-0	2005	eta1:eta2-Alkynyl-bridged W-Si complexes: formation, structure, and reaction with acetone.	Silicon	28-30	DNA polymerase iota	Homo sapiens	5-9	
15898752-1	2005	Reactions of (eta5-C5Me4R)(CO)2(MeCN)WMe (R = Me, Et) with HPh2SiCCtBu gave the novel alkynyl-bridged W-Si complexes, (eta5-C5Me4R)(CO)2W(mu-eta1:eta2-CCtBu)(SiPh2) (R = Me, Et), whose alkynyl ligands bridge the tungsten and silicon atoms in an eta1:eta2-coordination mode.	Silicon	63-65	DNA polymerase iota	Homo sapiens	146-150	
15898752-1	2005	Reactions of (eta5-C5Me4R)(CO)2(MeCN)WMe (R = Me, Et) with HPh2SiCCtBu gave the novel alkynyl-bridged W-Si complexes, (eta5-C5Me4R)(CO)2W(mu-eta1:eta2-CCtBu)(SiPh2) (R = Me, Et), whose alkynyl ligands bridge the tungsten and silicon atoms in an eta1:eta2-coordination mode.	Silicon	63-65	DNA polymerase iota	Homo sapiens	250-254	
16832512-1	2006	The bonding in Mn(eta2-SiH) complexes is interpreted in terms of an asymmetric oxidative addition whose extent is controlled by the substitution pattern at the hypercoordinate silicon centre, and especially by the ligand trans to the eta2-coordinating SiH moiety.	Silicon	176-183	DNA polymerase iota	Homo sapiens	18-22	
15898752-3	2005	Treatment of (eta5-C5Me5)(CO)2W(mu-eta1:eta2-CCtBu)(SiPh2) with acetone resulted in acetone insertion into the silicon-alkynyl linkage followed by intramolecular C-H activation of the tBu group to give the chelate-type alkyl-alkene complex, (eta5-C5Me5)(CO)2W(eta1:eta2-CH2CMe2C=CHSiPh2OCMe2).	Silicon	111-118	DNA polymerase iota	Homo sapiens	265-269	
29384245-4	2018	However, the energies required for achieving a eta2 -SiH mode are rather low, and is consistent with the propensity of these derivatives to undergo Si-H cleavage leading to the more stable silyl species [Pt(SiR3 )(It Bui Pr)2 ][BArF ] at room temperature.	Silicon	53-55	DNA polymerase iota	Homo sapiens	47-51	
34380307-5	2021	In contrast, the Si-N bond of the analogous vinylidene (R2(Me2N)Si-(R)Si (NHC)Ge:) (obtained by nucleophilic substitution of Cl by NMe2) does not oxidatively add to Ni(0), and a hydridosilagermene-eta2-nickel complex is obtained instead.	Silicon	17-19	DNA polymerase iota	Homo sapiens	197-201	
15225021-1	2004	The reaction of (2-SiH3C6H4)2SiH2 with Ni(Et2PCH2CH2PEt2)(PEt3)2 afforded a new silylnickel complex, which, in the solid state, was determined to be a bis(silyl)eta2-(Si-H)nickel complex, the first example of eta2-(Si-H)nickel complex by single-crystal X-ray analysis.	Silicon	19-21	DNA polymerase iota	Homo sapiens	161-165	
15225021-1	2004	The reaction of (2-SiH3C6H4)2SiH2 with Ni(Et2PCH2CH2PEt2)(PEt3)2 afforded a new silylnickel complex, which, in the solid state, was determined to be a bis(silyl)eta2-(Si-H)nickel complex, the first example of eta2-(Si-H)nickel complex by single-crystal X-ray analysis.	Silicon	19-21	DNA polymerase iota	Homo sapiens	209-213	
25783758-4	2015	The effect of lattice strain, implemented by a 3.2% change in the As-Si nearest-neighbour bond length, further shifts the value of eta2 to -1.87 x 10(-3) microm(2) V(-2), resulting in an excellent agreement of theory with the experimentally measured value of -1.9 +- 0.2 x 10(-3) microm(2) V(-2).	Silicon	69-71	DNA polymerase iota	Homo sapiens	131-135	
29218203-7	2015	Moreover, the calculations reveal that formation of the hydrosilane adducts proceeds via barrierless electrophilic activation of the hydrosilane by sterically controlled eta1 (end-on) or eta2 (side-on) coordination of the Si-H bond to the Lewis acidic metal center, followed by heterolytic cleavage of the Si-H bond through a concerted four-membered transition state.	Silicon	222-224	DNA polymerase iota	Homo sapiens	187-191	
29218203-7	2015	Moreover, the calculations reveal that formation of the hydrosilane adducts proceeds via barrierless electrophilic activation of the hydrosilane by sterically controlled eta1 (end-on) or eta2 (side-on) coordination of the Si-H bond to the Lewis acidic metal center, followed by heterolytic cleavage of the Si-H bond through a concerted four-membered transition state.	Silicon	306-308	DNA polymerase iota	Homo sapiens	187-191	
24154529-0	2013	Catalyst design for iron-promoted reductions: an iron disilyl-dicarbonyl complex bearing weakly coordinating eta2-(H-Si) moieties.	Silicon	117-119	DNA polymerase iota	Homo sapiens	109-113