PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 33001645-2 2020 Achievement of a structural phase transition induced by adsorption/desorption of guest molecules in spin crossover (SCO) Co(II) compounds is of significant interest because of the possibility that the spin state of the magnetic anisotropic high-spin (HS, S = 3/2) and low-spin (LS, S = 1/2) states can be switched via the induced changes in associated intermolecular interactions. Cobalt(2+) 121-127 spindlin 1 Homo sapiens 100-104 33511751-0 2021 Spin-Electric Coupling in a Cobalt(II)-Based Spin Triangle Revealed by Electric Field-Modulated ESR. Cobalt(2+) 28-38 spindlin 1 Homo sapiens 0-4 33511751-0 2021 Spin-Electric Coupling in a Cobalt(II)-Based Spin Triangle Revealed by Electric Field-Modulated ESR. Cobalt(2+) 28-38 spindlin 1 Homo sapiens 45-49 33511751-1 2021 We report on a cobalt(II)-based spin triangle showing a significant spin-electric coupling. Cobalt(2+) 15-25 spindlin 1 Homo sapiens 32-36 33511751-1 2021 We report on a cobalt(II)-based spin triangle showing a significant spin-electric coupling. Cobalt(2+) 15-25 spindlin 1 Homo sapiens 68-72 9942799-0 1987 Spin-orbit coupling effects in CdGa2Se4:Co2+ single crystals. Cobalt(2+) 40-44 spindlin 1 Homo sapiens 0-4 33871890-9 2021 DFT calculations also gave spin densities in Co-X, showing that the larger Co(II) spin density in a molecule is, the larger its ZFS magnitude is. Cobalt(2+) 75-81 spindlin 1 Homo sapiens 27-31 33001645-2 2020 Achievement of a structural phase transition induced by adsorption/desorption of guest molecules in spin crossover (SCO) Co(II) compounds is of significant interest because of the possibility that the spin state of the magnetic anisotropic high-spin (HS, S = 3/2) and low-spin (LS, S = 1/2) states can be switched via the induced changes in associated intermolecular interactions. Cobalt(2+) 121-127 spindlin 1 Homo sapiens 201-205 33001645-2 2020 Achievement of a structural phase transition induced by adsorption/desorption of guest molecules in spin crossover (SCO) Co(II) compounds is of significant interest because of the possibility that the spin state of the magnetic anisotropic high-spin (HS, S = 3/2) and low-spin (LS, S = 1/2) states can be switched via the induced changes in associated intermolecular interactions. Cobalt(2+) 121-127 spindlin 1 Homo sapiens 201-205 33001645-2 2020 Achievement of a structural phase transition induced by adsorption/desorption of guest molecules in spin crossover (SCO) Co(II) compounds is of significant interest because of the possibility that the spin state of the magnetic anisotropic high-spin (HS, S = 3/2) and low-spin (LS, S = 1/2) states can be switched via the induced changes in associated intermolecular interactions. Cobalt(2+) 121-127 spindlin 1 Homo sapiens 201-205 33001645-6 2020 0.5 HS, and the field-induced single-molecule magnet (SMM) behavior attributed to the presence of the anisotropic partial high-spin Co(II) species. Cobalt(2+) 132-138 spindlin 1 Homo sapiens 127-131 31441303-0 2019 Reversible On-Off Switching of the Hysteretic Spin Crossover in a Cobalt(II) Complex via Crystal to Crystal Transformation. Cobalt(2+) 66-76 spindlin 1 Homo sapiens 46-50 32383584-0 2020 In Situ NMR Search for Spin-Crossover in Heteroleptic Cobalt(II) Complexes. Cobalt(2+) 54-64 spindlin 1 Homo sapiens 23-27 32383584-2 2020 Screening the spin state of a cobalt(II) ion in a series of thus obtained homoleptic and heteroleptic compounds of terpyridines (terpy) and 2,6-bis(pyrazol-3-yl)pyridines (3-bpp) by using this NMR-based approach, which only relies on the temperature behavior of chemical shifts, revealed the first cobalt(II) complexes with a 3-bpp ligand to undergo a thermally induced spin-crossover. Cobalt(2+) 30-40 spindlin 1 Homo sapiens 14-18 32383584-2 2020 Screening the spin state of a cobalt(II) ion in a series of thus obtained homoleptic and heteroleptic compounds of terpyridines (terpy) and 2,6-bis(pyrazol-3-yl)pyridines (3-bpp) by using this NMR-based approach, which only relies on the temperature behavior of chemical shifts, revealed the first cobalt(II) complexes with a 3-bpp ligand to undergo a thermally induced spin-crossover. Cobalt(2+) 30-40 spindlin 1 Homo sapiens 370-374 32383584-2 2020 Screening the spin state of a cobalt(II) ion in a series of thus obtained homoleptic and heteroleptic compounds of terpyridines (terpy) and 2,6-bis(pyrazol-3-yl)pyridines (3-bpp) by using this NMR-based approach, which only relies on the temperature behavior of chemical shifts, revealed the first cobalt(II) complexes with a 3-bpp ligand to undergo a thermally induced spin-crossover. Cobalt(2+) 298-308 spindlin 1 Homo sapiens 14-18 30156097-1 2018 A new low-spin (LS) cobalt(II) outer-sphere redox shuttle (OSRS) [Co(PY5Me2)(CN)]+, where PY5Me2 represents the pentadentate ligand 2,6-bis(1,1-bis(2-pyridyl)ethyl)pyridine, has been synthesized and characterized for its potential application in dye-sensitized solar cells (DSSCs). Cobalt(2+) 20-30 spindlin 1 Homo sapiens 10-14 31266895-3 2019 Here, we report a previously unreported compound, [Formula: see text], a geometrically frustrated system with effective spin-1/2 local moments for Co2+ ions on an isotropic 2-dimensional (2D) triangular lattice. Cobalt(2+) 147-151 spindlin 1 Homo sapiens 120-126 30109314-0 2018 Abrupt spin transition in a modified-terpyridine cobalt(ii) complex with a highly-distorted [CoN6] core. Cobalt(2+) 49-59 spindlin 1 Homo sapiens 7-11 31265032-4 2019 Above 340 K, compound 1a exhibits an increase in magnetic susceptibility, suggesting the onset of a VT interconversion from low spin Co(iii)-dbcat to high spin Co(ii)-dbsq (dbsq- = di-tert-butylsemiquinonate) that is incomplete up to 400 K. In solution, variable temperature electronic absorption spectra and Evans NMR method magnetic susceptibility data indicate reversible VT interconversions for 1a in several solvents, with the transition temperature varying with solvent. Cobalt(2+) 160-166 spindlin 1 Homo sapiens 155-159 29064659-0 2017 Cobalt(II) Magnetic Metal-Organic Framework with an Effective Kagome Lattice, Large Surface Area, and High Spin-Canted Ordering Temperature. Cobalt(2+) 0-10 spindlin 1 Homo sapiens 107-111 29227093-0 2018 Modeling Spin Interactions in a Triangular Cobalt(II) Complex with Triaminoguanidine Ligand Framework: Synthesis, Structure, and Magnetic Properties. Cobalt(2+) 43-53 spindlin 1 Homo sapiens 9-13 29227093-3 2018 Three octahedrally coordinated high-spin cobalt(II) ions are linked through the bridging triaminoguanidine backbone of the ligand leading to an almost equilateral triangular arrangement. Cobalt(2+) 41-51 spindlin 1 Homo sapiens 36-40 26648133-0 2015 Partial Geometric Frustration in Inorganic Supramolecular Spin Systems with One-Dimensional Trigonally Aligned Magnetic Chains 1(MCl4)2- (M = Fe2+, Co2+). Cobalt(2+) 149-153 spindlin 1 Homo sapiens 58-62 28367565-0 2017 Supramolecular architectures self-assembled using long chain alkylated spin crossover cobalt(ii) compounds. Cobalt(2+) 86-96 spindlin 1 Homo sapiens 71-75 28367565-2 2017 The hybrids display wire or rolled sheet supramolecular arrangements with odd and even alkyl chain dependence, with the cobalt(ii) centres exhibiting gradual spin-crossover behaviours. Cobalt(2+) 120-130 spindlin 1 Homo sapiens 158-162 26000802-0 2015 Role of Spin States in Nitric Oxide Binding to Cobalt(II) and Manganese(II) Porphyrins. Cobalt(2+) 47-57 spindlin 1 Homo sapiens 8-12 25599519-0 2015 Spin-crossover behaviors in solvated cobalt(ii) compounds. Cobalt(2+) 37-47 spindlin 1 Homo sapiens 0-4 25198244-0 2014 High-temperature spin crossover in a mononuclear six-coordinate cobalt(II) complex. Cobalt(2+) 64-74 spindlin 1 Homo sapiens 17-21 25198244-1 2014 The six-coordinate cobalt(II) complex of formula [Co(tppz)2](tcm)2 exhibits a thermally induced spin-crossover behavior from a high spin (S = 3/2) at higher temperatures to a low spin (S = 1/2) at lower temperatures, with the low-spin phase being achieved at T <= 200 K. Cobalt(2+) 19-29 spindlin 1 Homo sapiens 96-100 25198244-1 2014 The six-coordinate cobalt(II) complex of formula [Co(tppz)2](tcm)2 exhibits a thermally induced spin-crossover behavior from a high spin (S = 3/2) at higher temperatures to a low spin (S = 1/2) at lower temperatures, with the low-spin phase being achieved at T <= 200 K. Cobalt(2+) 19-29 spindlin 1 Homo sapiens 132-136 25198244-1 2014 The six-coordinate cobalt(II) complex of formula [Co(tppz)2](tcm)2 exhibits a thermally induced spin-crossover behavior from a high spin (S = 3/2) at higher temperatures to a low spin (S = 1/2) at lower temperatures, with the low-spin phase being achieved at T <= 200 K. Cobalt(2+) 19-29 spindlin 1 Homo sapiens 132-136 25198244-1 2014 The six-coordinate cobalt(II) complex of formula [Co(tppz)2](tcm)2 exhibits a thermally induced spin-crossover behavior from a high spin (S = 3/2) at higher temperatures to a low spin (S = 1/2) at lower temperatures, with the low-spin phase being achieved at T <= 200 K. Cobalt(2+) 19-29 spindlin 1 Homo sapiens 132-136 21351791-0 2011 Spin ground state and magnetic properties of cobalt(II): relativistic DFT calculations guided by EPR measurements of bis(2,4-acetylacetonate)cobalt(II)-based complexes. Cobalt(2+) 45-55 spindlin 1 Homo sapiens 0-4 24980875-4 2014 Here we study the spin dynamics of cobalt(II) ions in a model molecular complex. Cobalt(2+) 35-45 spindlin 1 Homo sapiens 18-22 23777336-2 2013 Magnetic susceptibility measurements and X-ray diffraction (XRD) analysis reveal a central low-spin octahedral Co(2+) ion with both ligands in the neutral radical form (L( )) forming a linear L( ) Co(II) L( ) arrangement. Cobalt(2+) 111-117 spindlin 1 Homo sapiens 95-99 24220293-5 2013 X-band EPR spectroscopy has revealed that the Co(ii) centres of both assemblies are high spin, in contrast to most previously described cobaloximes, and likely plays an important role in facilitating photoinduced charge separation. Cobalt(2+) 46-52 spindlin 1 Homo sapiens 89-93 21351791-0 2011 Spin ground state and magnetic properties of cobalt(II): relativistic DFT calculations guided by EPR measurements of bis(2,4-acetylacetonate)cobalt(II)-based complexes. Cobalt(2+) 141-151 spindlin 1 Homo sapiens 0-4 34851330-6 2021 In particular, the TF5TA containing ligand show interesting stacking motifs depending on the used solvent, and these interactions have an influence on the spin state of the cobalt(II) complexes. Cobalt(2+) 173-183 spindlin 1 Homo sapiens 155-159 19113375-3 2008 In contrast, the substitutions with Co2+ (S=3/2) spin with Ising-like anisotropy and Heisenberg Mn2+ (S=5/2) spin induce a conventional spin glass phase below 1 K. From these comparisons, it is suggested that the integer size of the Heisenberg spins is important to stabilize the 2D coherent behavior observed in the frozen spin-disordered state. Cobalt(2+) 36-40 spindlin 1 Homo sapiens 49-53 17696425-0 2007 Spin transition at the mesophase transition temperature in a cobalt(II) compound with branched alkyl chains. Cobalt(2+) 61-71 spindlin 1 Homo sapiens 0-4 17696425-2 2007 The cobalt(II) compound exhibits a spin transition between low-spin and high-spin with a thermal hysteresis loop (T(1/2) upward arrow = 288 K and T(1/2) downward arrow = 284 K) at the liquid-crystal transition temperature. Cobalt(2+) 4-14 spindlin 1 Homo sapiens 35-39 17696425-2 2007 The cobalt(II) compound exhibits a spin transition between low-spin and high-spin with a thermal hysteresis loop (T(1/2) upward arrow = 288 K and T(1/2) downward arrow = 284 K) at the liquid-crystal transition temperature. Cobalt(2+) 4-14 spindlin 1 Homo sapiens 63-67 17696425-2 2007 The cobalt(II) compound exhibits a spin transition between low-spin and high-spin with a thermal hysteresis loop (T(1/2) upward arrow = 288 K and T(1/2) downward arrow = 284 K) at the liquid-crystal transition temperature. Cobalt(2+) 4-14 spindlin 1 Homo sapiens 63-67 17696425-3 2007 It is the first example in the cobalt(II) compounds in which the spin transition occurs at the crystal-liquid crystal transition temperature. Cobalt(2+) 31-41 spindlin 1 Homo sapiens 65-69 11237628-7 2001 Detailed studies coupled with theoretical estimates reveal that, for the chlorides and perchlorates of Ni(2+) (and Co(2+)), the relaxation enhancements are dominated by Heisenberg spin exchange interactions with paramagnetic ions dissolved in fluid membranes. Cobalt(2+) 115-121 spindlin 1 Homo sapiens 180-184 18813367-0 2008 Spin canting in an unprecedented three-dimensional pyrophosphate- and 2,2"-bipyrimidine-bridged cobalt(II) framework. Cobalt(2+) 96-106 spindlin 1 Homo sapiens 0-4 18813367-1 2008 The three-dimensional cobalt(ii) compound of formula {[Co(2)(P(2)O(7))(bpym)(2)].12H(2)O}(n), where the pyrophosphate and 2,2"-bipyrimidine act as bridging ligands, is a new example of a spin-canted antiferromagnet with T(c) = 19 K. Cobalt(2+) 22-32 spindlin 1 Homo sapiens 187-191 34851330-0 2021 Spin-state control of cobalt(II) and iron(II) complexes with click-derived tripodal ligands through non-covalent and fluorine-specific interactions. Cobalt(2+) 22-32 spindlin 1 Homo sapiens 0-4 34341808-0 2021 Spin transition triggered by desorption of crystal solvents for a two-dimensional cobalt(II) complex with hydrogen bonding. Cobalt(2+) 82-92 spindlin 1 Homo sapiens 0-4