PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 32715213-3 2020 In the case of derivatives, such a transition is separated by energy, and two TPA peaks can be clearly observed (derivatives containing NO2 and NMe2 groups have two TPA peaks), where the magnitude of the separation is directly related to the intensity of the peripheral group. Nitrogen Dioxide 136-139 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 144-148 33421666-3 2021 Through calculating the activation energies and rate constants of ESIPT processes, finding that the processes are increasingly inactive when substituent group changes from -CN, -CO2Me, -Cl, -Me, -NMe2 to -NO2. Nitrogen Dioxide 205-208 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 196-200 33421666-7 2021 It follows that the intramolecular charge transfer (ICT) degrees are increasingly enlarged as substituting from -CN, -CO2Me, -Cl, -Me, -NMe2 to -NO2 groups, which not only causes the red-shift of absorption and emission of enol and keto forms, but also affects the charge distribution of proton donor and acceptor, inhibiting the occurrence of ESIPT processes. Nitrogen Dioxide 145-148 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 136-140 25031077-1 2014 Interactions between the NO2 group and 13 different substituents (BF2, BH2, CF3, CH3, CHO, CN, F, NH2, NMe2, NO2, NO, OH, OMe) were investigated computationally for bicyclo[2.2.2]octane (BCO) and benzene substituted at 1,4 and 1,3 positions in the ring. Nitrogen Dioxide 25-28 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 103-107 28572905-2 2017 Second-order rate constants (k) were determined from pseudo first-order and stoichiometric experiments, and follow the trends CF3 < NO2 < Cl < H < Me < OMe < NMe2 and LCuOH < NO2 LCuOH. Nitrogen Dioxide 135-138 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 176-180 14723523-2 2004 The association constants strongly depend on the substituents, varying up to DeltaDeltaG = 3.4 kcal/mol; electron-donating substituents (OMe, NMe2) decrease the binding affinity, while electron-withdrawing groups (Cl, NO2) increase it. Nitrogen Dioxide 218-221 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 142-146