PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 33755454-8 2021 Then, we investigated the reactivities of the (mu-eta2:eta2-NO2)dicopper complex toward methane and benzene by considering the conversions of N2O to N2 in the presence and the absence of methane or benzene. Benzene 100-107 DNA polymerase iota Homo sapiens 50-54 33755454-8 2021 Then, we investigated the reactivities of the (mu-eta2:eta2-NO2)dicopper complex toward methane and benzene by considering the conversions of N2O to N2 in the presence and the absence of methane or benzene. Benzene 100-107 DNA polymerase iota Homo sapiens 55-59 33755454-8 2021 Then, we investigated the reactivities of the (mu-eta2:eta2-NO2)dicopper complex toward methane and benzene by considering the conversions of N2O to N2 in the presence and the absence of methane or benzene. Benzene 198-205 DNA polymerase iota Homo sapiens 50-54 33755454-10 2021 Thus, the (mu-eta2:eta2-NO2)dicopper complex prefers the reactions with methane and benzene to that with N2O. Benzene 84-91 DNA polymerase iota Homo sapiens 14-18 33755454-10 2021 Thus, the (mu-eta2:eta2-NO2)dicopper complex prefers the reactions with methane and benzene to that with N2O. Benzene 84-91 DNA polymerase iota Homo sapiens 19-23 33755454-11 2021 The reaction of the (mu-eta2:eta2-NO2)dicopper complex with methane or benzene generated the (mu-nitrosyl)dicopper complex. Benzene 71-78 DNA polymerase iota Homo sapiens 24-28 33755454-11 2021 The reaction of the (mu-eta2:eta2-NO2)dicopper complex with methane or benzene generated the (mu-nitrosyl)dicopper complex. Benzene 71-78 DNA polymerase iota Homo sapiens 29-33 30931152-5 2019 Moreover, when the lattice of the metal surface is commensurate with the size of benzene rings, the contribution to the adsorption energy from eta2-coordination is about twice that from eta1-coordination. Benzene 81-88 DNA polymerase iota Homo sapiens 143-147 32842728-8 2020 Static DFT calculations also identified an eta2-coordinated benzene complex in which the arene is held more loosely than in the ground state, primarily through dispersion forces. Benzene 60-67 DNA polymerase iota Homo sapiens 43-47 32842728-9 2020 Although a single reaction pathway was identified by static calculations, quasiclassical direct dynamics simulations identified a network of several reaction pathways connecting the eta2-benzene and phenyl hydride isomers, due to the relatively flat energy landscape. Benzene 199-213 DNA polymerase iota Homo sapiens 182-186 30773724-1 2019 The reaction of Re2 (CO)8 (mu-C6 H5 )(mu-H), 1 with corannulene (C20 H10 ) yielded the product Re2 (CO)8 (mu-H)(mu-eta2 -1,2-C20 H9 ), 2 (65 % yield) containing a Re2 metalated corannulene ligand formed by loss of benzene from 1 and the activation of one of the CH bonds of the nonplanar corannulene molecule by an oxidative-addition to 1. Benzene 214-221 DNA polymerase iota Homo sapiens 115-119 32383858-2 2020 The reaction is initiated by boron atom addition to benzene in forming an eta2-(1, 4) Pi adduct (A). Benzene 52-59 DNA polymerase iota Homo sapiens 74-78 20858013-0 2010 C-H bond activation of benzene by unsaturated eta2-cyclopropene and eta2-benzyne complexes of niobium. Benzene 23-30 DNA polymerase iota Homo sapiens 46-50 29780565-1 2018 Previous theoretical and experimental endeavors suggested that [Cu(C6H6)]+ prefers the eta1/eta2 mode over the eta6 mode due to the augmented repulsion between the benzene ring and metal d-electrons. Benzene 164-171 DNA polymerase iota Homo sapiens 92-96 29780565-3 2018 However, the use of IPr (1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) in place of silylene results in the formation of [IPr Cu(eta2-C6H6)]+[SbF6]- (6), where the copper atom is bound to the benzene ring in the eta2 mode. Benzene 195-202 DNA polymerase iota Homo sapiens 132-136 28742965-1 2017 The effects of an electron-withdrawing group on the organic chemistry of an eta2-bound benzene ring are explored using the complex TpW(NO)(PMe3)(eta2-PhCF3). Benzene 87-94 DNA polymerase iota Homo sapiens 76-80 28742965-1 2017 The effects of an electron-withdrawing group on the organic chemistry of an eta2-bound benzene ring are explored using the complex TpW(NO)(PMe3)(eta2-PhCF3). Benzene 87-94 DNA polymerase iota Homo sapiens 145-149 20858013-0 2010 C-H bond activation of benzene by unsaturated eta2-cyclopropene and eta2-benzyne complexes of niobium. Benzene 23-30 DNA polymerase iota Homo sapiens 68-72 18072764-4 2008 The reaction of [MoO2(eta2-Pz)2] with NacNacH in benzene at room temperature leads to a mixture of 1 and the monomeric molybdenum(VI) compound [MoO2(NacNac)(eta2-Pz)] (2). Benzene 49-56 DNA polymerase iota Homo sapiens 22-26 17165710-1 2006 The intermolecular C-H bond activation of benzene occurs under very mild conditions (room temperature) via a rare stereospecific 1,3-H addition on an unsaturated eta2-cyclopropene intermediate generated by a beta-H abstraction of CH4 from TpMe2NbMe(c-C3H5)(MeCCMe) to give TpMe2NbPh(c-C3H5)(MeCCMe). Benzene 42-49 DNA polymerase iota Homo sapiens 162-166 16852478-2 2005 Coadsorbed benzene or naphthalene are found to convert eta1- and eta2-states of ethyl formate and acetone into new states displaying slightly red-shifted carbonyl bands. Benzene 11-18 DNA polymerase iota Homo sapiens 65-69