PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 27316702-3 2016 Gadolinium-based metallofullerenols, e.g., Gd@C82(OH) x (x 22), are well known for their abundant biological activities with low toxicity experimentally and theoretically; however, their activity in direct TNF-alpha inhibition has not been explored. Gadolinium 43-45 complement C8 beta chain Homo sapiens 46-49 23035458-0 2012 Synthesis and characterization of Gd@C82-PVK and C60-PVK--a kind of fullerene-grafted polymer. Gadolinium 34-36 complement C8 beta chain Homo sapiens 37-40 18570516-3 2008 Calculations have also been performed for endohedral metallofullerene Gd@C(82) to demonstrate the possible use of shake-up processes to identify the charge transfer between the metal ion and the carbon cage. Gadolinium 70-72 complement C8 beta chain Homo sapiens 73-78 20641737-0 2004 Gd@C82 Fullerenol Fullerenes, also known as buckyballs, are spheroidal carbon cages with a molecular formula of C2n (n = 30-41) and a diameter of ~1 nm (1). Gadolinium 0-2 complement C8 beta chain Homo sapiens 3-6 20641737-4 2004 For the Gd@C2n, the encapsulation of electropositive Gd atom leads to the transfer of electrons from the Gd atom to the electronegative fullerene cage, resulting in a zwitterion [Gd(3+)@C82(3-)]. Gadolinium 8-10 complement C8 beta chain Homo sapiens 186-189 20641737-4 2004 For the Gd@C2n, the encapsulation of electropositive Gd atom leads to the transfer of electrons from the Gd atom to the electronegative fullerene cage, resulting in a zwitterion [Gd(3+)@C82(3-)]. Gadolinium 53-55 complement C8 beta chain Homo sapiens 186-189 20641737-8 2004 Gd-Fullerenols (Gd@C82(OH)40) are water-soluble Gd endohedral metallofullerenes used with in vivo MRI (8). Gadolinium 0-2 complement C8 beta chain Homo sapiens 19-22 20641737-9 2004 The encapsulation of Gd has three electrons transferred to the C82 fullerene cage, resulting in zwitterions [Gd(3+)@C82(OH)40(3-)] in which seven unpaired electrons are located on the 4f-orbital of gadolinium ion and one unpaired electron is located on the fullerene cage. Gadolinium 198-208 complement C8 beta chain Homo sapiens 63-66 20641737-9 2004 The encapsulation of Gd has three electrons transferred to the C82 fullerene cage, resulting in zwitterions [Gd(3+)@C82(OH)40(3-)] in which seven unpaired electrons are located on the 4f-orbital of gadolinium ion and one unpaired electron is located on the fullerene cage. Gadolinium 198-208 complement C8 beta chain Homo sapiens 116-119