PMID-sentid	Pub_year	Sent_text		comp_official_name	comp_offsetprotein_name	organism	prot_offset
33258611-2	2020	The reaction proceeded via a Rh-catalyzed alkenyl sp2 C-H activation process, which allows access to macrocyclic molecules of different ring sizes.	Rhodium	29-31	Sp2 transcription factor	Homo sapiens	50-53	
31588947-1	2019	An efficient and convenient synthesis of diversely substituted naphtho[1",2":4,5]imidazo[1,2-a]-pyridine derivatives from the cascade reactions of 2-arylimidazo[1,2-a]pyridines with a-diazo carbonyl compounds via Rh(iii)-catalyzed regioselective C(sp2)-H alkylation followed by intramolecular annulation is presented.	Rhodium	213-220	Sp2 transcription factor	Homo sapiens	246-251	
32073283-1	2020	The C(sp2)-H function of indole ketone with diazo compound via a rhodium(II)-catalyzed intramolecular electrophilic trapping reaction under mild conditions in air was demonstrated.	Rhodium	65-76	Sp2 transcription factor	Homo sapiens	4-9	
31589421-4	2019	Studies into catalyst activation revealed that photochemical or thermal activation of (eta5-C5Me5)Rh(bq)H induced C(sp2)-H reductive elimination and generated the bimetallic complex, [(eta5-C5Me5)Rh(micro2,eta2-bq)Rh(eta5-C5Me5)H].	Rhodium	86-105	Sp2 transcription factor	Homo sapiens	114-119	
31589421-4	2019	Studies into catalyst activation revealed that photochemical or thermal activation of (eta5-C5Me5)Rh(bq)H induced C(sp2)-H reductive elimination and generated the bimetallic complex, [(eta5-C5Me5)Rh(micro2,eta2-bq)Rh(eta5-C5Me5)H].	Rhodium	86-100	Sp2 transcription factor	Homo sapiens	114-119	
31589421-4	2019	Studies into catalyst activation revealed that photochemical or thermal activation of (eta5-C5Me5)Rh(bq)H induced C(sp2)-H reductive elimination and generated the bimetallic complex, [(eta5-C5Me5)Rh(micro2,eta2-bq)Rh(eta5-C5Me5)H].	Rhodium	214-229	Sp2 transcription factor	Homo sapiens	114-119	
29044777-5	2018	The further process of reduction of paramagnetic species triggers the ethyl migration from carbon(22) to rhodium(III), affording the diamagnetic rhodium(III) meta-benziporphyrin containing the apically coordinated sigma-ethyl ligand providing an example of reversible C(sp2 )-C(sp3 ) bond cleavage.	Rhodium	105-112	Sp2 transcription factor	Homo sapiens	268-273	
31584826-0	2019	Rhodium(III)-Catalyzed C(sp2)-H Functionalization of Cyclobutenes.	Rhodium	0-12	Sp2 transcription factor	Homo sapiens	23-28	
31549126-0	2019	Synthesis of benzoazepine derivatives via Rh(iii)-catalyzed inert C(sp2)-H functionalization and [4 + 3] annulation.	Rhodium	42-49	Sp2 transcription factor	Homo sapiens	66-71	
31549126-2	2019	Mechanistically, the formation of the title compounds is triggered by a Rh(iii)-catalyzed C(sp2)-H alkenylation of 1 with 2 followed by an intramolecular N-nucleophilic substitution.	Rhodium	72-79	Sp2 transcription factor	Homo sapiens	90-95	
30043020-0	2018	Experimental and computational studies on H2O-promoted, Rh-catalyzed transient-ligand-free ortho-C(sp2)-H amidation of benzaldehydes with dioxazolones.	Rhodium	56-58	Sp2 transcription factor	Homo sapiens	97-102	
30043020-1	2018	An efficient and convenient ligand-free, rhodium-catalyzed ortho-C(sp2)-H amidation of benzaldehydes with dioxazolones using H2O as the key promoter is described.	Rhodium	41-48	Sp2 transcription factor	Homo sapiens	65-70	
31015939-4	2019	Herein we describe rhodium(iii)-catalyzed sp2 and sp3 C-H activation-oxidative annulations between aromatic substrates and 1,3-enynes, where alkenyl-to-allyl 1,4-rhodium(iii) migration enabled the generation of electrophilic rhodium(iii) pi-allyls via remote C-H functionalization.	Rhodium	19-26	Sp2 transcription factor	Homo sapiens	42-45	
30020791-0	2018	A Rh-Catalyzed Air and Moisture Tolerable Aldehyde (Ketone)-Directed Fluorosulfonylvinylation of Aryl C( sp2)-H Bonds.	Rhodium	2-4	Sp2 transcription factor	Homo sapiens	105-108	
29071788-0	2017	Rhodium(II)- or Copper(I)-Catalyzed Formal Intramolecular Carbene Insertion into Vinylic C(sp2 )-H Bonds: Access to Substituted 1H-Indenes.	Rhodium	0-7	Sp2 transcription factor	Homo sapiens	89-94	
23616431-0	2013	Synthesis of fluorine-containing multisubstituted phenanthridines by rhodium-catalyzed alkyne [2+2+2] cycloaddition and tandem sp2 C-H difluoromethylenation.	Rhodium	69-76	Sp2 transcription factor	Homo sapiens	127-130	
29068203-0	2017	Rhodium-Catalyzed sp2 C-H Acetoxylation of N-Aryl Azaindoles/N-Heteroaryl Indolines.	Rhodium	0-7	Sp2 transcription factor	Homo sapiens	18-21	
28328101-0	2017	Asymmetric Synthesis of Spiropyrazolones by Rhodium-Catalyzed C(sp2 )-H Functionalization/Annulation Reactions.	Rhodium	44-51	Sp2 transcription factor	Homo sapiens	62-67