PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 15762692-2 2005 Analogously, the room-temperature photochemical reaction of 1a with [CpFe(C6H6)]PF6 gives the previously reported iron complex [1-Cp-12-tBuNH-1,2,4,12-FeC3B8H10] (3) (yield 82%). Iron 114-118 sperm associated antigen 17 Homo sapiens 74-83 35344334-4 2022 The PF6- counteranion is used for the phosphidation of Fe. Iron 55-57 sperm associated antigen 17 Homo sapiens 4-7 28834022-0 2017 Protonation of Ferrocene: A Low-Temperature X-ray Diffraction Study of [Cp2 FeH](PF6 ) Reveals an Iron-Bound Hydrido Ligand. Iron 98-102 sperm associated antigen 17 Homo sapiens 81-84 28834022-1 2017 Ferrocene, Cp2 Fe, is quantitatively protonated in a mixture of liquid HF/PF5 to yield [Cp2 FeH](PF6 ), which was characterized by 1 H/13 C NMR and 57 Fe Mossbauer spectroscopy as well as single-crystal X-ray diffraction analysis. Iron 0-2 sperm associated antigen 17 Homo sapiens 97-100 27555240-8 2016 The iron(III) centers of the diethylpyrrole-bridged diiron(III) mu-oxo bisporphyrin undergo very strong antiferromagnetic interactions (J=-137.7 cm(-1) ), although the coupling constant is reduced to only a weak value in the mu-hydroxo complexes (J=-42.2, -44.1, and -42.4 cm(-1) for the BF4 , SbF6 , and PF6 complexes, respectively). Iron 4-8 sperm associated antigen 17 Homo sapiens 305-308 24833117-2 2014 Bulk chemical oxidation of 1 and 2 with Fc[PF6] (Fc = ferrocene) is accompanied by fluoride ion abstraction from PF6(-) by the iron center trans to the Fe NR functionality, forming F-Fe((i)PrNPPh2)3Fe NR ((i)Pr = isopropyl) (R = (t)Bu, 3; adamantyl, 4). Iron 127-131 sperm associated antigen 17 Homo sapiens 43-46 24833117-2 2014 Bulk chemical oxidation of 1 and 2 with Fc[PF6] (Fc = ferrocene) is accompanied by fluoride ion abstraction from PF6(-) by the iron center trans to the Fe NR functionality, forming F-Fe((i)PrNPPh2)3Fe NR ((i)Pr = isopropyl) (R = (t)Bu, 3; adamantyl, 4). Iron 127-131 sperm associated antigen 17 Homo sapiens 113-116 24833117-2 2014 Bulk chemical oxidation of 1 and 2 with Fc[PF6] (Fc = ferrocene) is accompanied by fluoride ion abstraction from PF6(-) by the iron center trans to the Fe NR functionality, forming F-Fe((i)PrNPPh2)3Fe NR ((i)Pr = isopropyl) (R = (t)Bu, 3; adamantyl, 4). Iron 152-154 sperm associated antigen 17 Homo sapiens 43-46 24833117-2 2014 Bulk chemical oxidation of 1 and 2 with Fc[PF6] (Fc = ferrocene) is accompanied by fluoride ion abstraction from PF6(-) by the iron center trans to the Fe NR functionality, forming F-Fe((i)PrNPPh2)3Fe NR ((i)Pr = isopropyl) (R = (t)Bu, 3; adamantyl, 4). Iron 152-154 sperm associated antigen 17 Homo sapiens 113-116 24833117-2 2014 Bulk chemical oxidation of 1 and 2 with Fc[PF6] (Fc = ferrocene) is accompanied by fluoride ion abstraction from PF6(-) by the iron center trans to the Fe NR functionality, forming F-Fe((i)PrNPPh2)3Fe NR ((i)Pr = isopropyl) (R = (t)Bu, 3; adamantyl, 4). Iron 183-185 sperm associated antigen 17 Homo sapiens 43-46 24833117-2 2014 Bulk chemical oxidation of 1 and 2 with Fc[PF6] (Fc = ferrocene) is accompanied by fluoride ion abstraction from PF6(-) by the iron center trans to the Fe NR functionality, forming F-Fe((i)PrNPPh2)3Fe NR ((i)Pr = isopropyl) (R = (t)Bu, 3; adamantyl, 4). Iron 183-185 sperm associated antigen 17 Homo sapiens 113-116 31986714-1 2013 The FeIII azide complexes [FeIII (N3 )cyclam-ac]PF6 (1 PF6 ), [FeIII (N3 )Me3 cyclam-ac]PF6 (2 PF6 ), and trans-[FeIII (N3 )2 cyclam]ClO4 (3 ClO4 ) (cyclam=1,4,8,11-tetraazacyclotetradecane; cyclam-ac=1,4,8,11-tetraazacyclotetradecane-1-acetate; Me3 cyclam-ac=4,8,11-trimethyl-1,4,8,11-tetraazacyclotetra-decane-1-acetate) are studied in the gas phase with special emphasis on the formation of high-valent iron nitrides by collision-induced dissociation. Iron 4-9 sperm associated antigen 17 Homo sapiens 48-51 22297268-1 2012 The ultrafast photo-induced primary processes of the iron-(III) azido complex, [Fe(III)N(3)(cyclam-acetato)] PF(6) (1), in acetonitrile solution at room temperature were studied using femtosecond spectroscopy with ultraviolet (UV) excitation and mid-infrared (MIR) detection. Iron 53-57 sperm associated antigen 17 Homo sapiens 109-114 22334566-6 2012 Applying an in situ formed iron-based water reduction catalyst derived from [HNEt(3)](+) [HFe(3)(CO)(11)](-) and tris[3,5-tris-(trifluoromethyl)-phenyl]phosphine as the ligand, [Ir(2-phenylbenz-oxazole)(2)-(bpy)]PF(6) proved to be the most efficient complex giving a quantum yield of 16% at 440 nm light irradiation. Iron 27-31 sperm associated antigen 17 Homo sapiens 212-217 20737065-5 2010 Electrochemical studies showed that, in [ML](PF(6))(2) (M = Pd and Pt), the half-wave potential of the 1,1"-ferrocenediyl group shifts to much more positive potentials due to the strong through-space interaction between the two metals (M...Fe). Iron 240-242 sperm associated antigen 17 Homo sapiens 45-50 31696991-6 2020 Two iron complexes [(mtL42)FeCl](PF6) and [(mtL42)Fe(OTf)2]) were obtained and their reactivity studied towards aromatic substrates in the presence of H2O2. Iron 4-8 sperm associated antigen 17 Homo sapiens 33-36 27682429-4 2016 In contrast, such counterions as I5 , I3 , BF4 , SbF6 , and PF6 are found to be tightly associated with one of the porphyrin rings and, therefore, stabilize two different spin states of iron in one molecule. Iron 186-190 sperm associated antigen 17 Homo sapiens 60-63 23447398-1 2013 Treatment of [Cp*(dppe)Fe-C C-TTFMe3] (1) with Ag[PF6] (3 equiv) in DMF provides the binuclear complex [Cp*(dppe)Fe=C=C=TTFMe2 =CH-CH=TTFMe2 =C=C=Fe(dppe)Cp*][PF6]2 (2[PF6 ]2) isolated as a deep-blue powder in 69 % yield. Iron 23-25 sperm associated antigen 17 Homo sapiens 50-53 23447398-1 2013 Treatment of [Cp*(dppe)Fe-C C-TTFMe3] (1) with Ag[PF6] (3 equiv) in DMF provides the binuclear complex [Cp*(dppe)Fe=C=C=TTFMe2 =CH-CH=TTFMe2 =C=C=Fe(dppe)Cp*][PF6]2 (2[PF6 ]2) isolated as a deep-blue powder in 69 % yield. Iron 23-25 sperm associated antigen 17 Homo sapiens 159-162 23447398-1 2013 Treatment of [Cp*(dppe)Fe-C C-TTFMe3] (1) with Ag[PF6] (3 equiv) in DMF provides the binuclear complex [Cp*(dppe)Fe=C=C=TTFMe2 =CH-CH=TTFMe2 =C=C=Fe(dppe)Cp*][PF6]2 (2[PF6 ]2) isolated as a deep-blue powder in 69 % yield. Iron 23-25 sperm associated antigen 17 Homo sapiens 159-162 23447398-13 2013 In 2[PF6], the charge and the spin are both symmetrically distributed on the carbon bridge and only moderately on the iron and TTFMe2 electroactive centers. Iron 118-122 sperm associated antigen 17 Homo sapiens 5-8 14664603-3 2003 Finally, the known heterodinuclear species [(Me3[9]aneN3)CrIII(mu-O)(mu-CH3CO2)2Fe([9]aneN3)](PF6)2 (5(PF6)(2)) can also be one-electron oxidized yielding [5ox]3+ containing an iron(IV) ion. Iron 177-181 sperm associated antigen 17 Homo sapiens 94-97