PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 33411859-2 2021 Upon activation by [Ph3C][B(C6F5)4], the scandium (P-Sc and S-Sc) and yttrium complexes (P-Y and S-Y) could catalyze the polymerization of isoprene with cis-1,4 selectivity (up to 98.8%), while the lutetium analogues P-Lu and S-Lu produced trans-1,4 selective polyisoprene (up to 83.3%). isoprene 139-147 suppressor of cytokine signaling 1 Homo sapiens 153-158 35581680-4 2022 Terminating a living cis -1,4-selective isoprene polymerization by isocyanate as cross-linker ( CL ), star polyisoprene with low polydispersity was obtained at high yield (91.8%). isoprene 40-48 suppressor of cytokine signaling 1 Homo sapiens 21-27 33881099-7 2021 Upon activation with Al2Et3Cl3 in toluene, these complexes showed high activities in isoprene polymerization affording cis-1,4 enriched polymers with a moderate molecular weight (0.85-4.72 x 104 Da). isoprene 85-93 suppressor of cytokine signaling 1 Homo sapiens 119-124 21321731-0 2011 Rare earth metal bis(amide) complexes bearing amidinate ancillary ligands: synthesis, characterization, and performance as catalyst precursors for cis-1,4 selective polymerization of isoprene. isoprene 183-191 suppressor of cytokine signaling 1 Homo sapiens 147-152 30965837-0 2017 Cis-1,4-Polymerization of Isoprene by 1,3-Bis(oxazolinymethylidene)isoindoline-Ligated Rare-Earth Metal Dialkyl Complexes. isoprene 26-34 suppressor of cytokine signaling 1 Homo sapiens 0-5 30965837-3 2017 In the presence of a cocatalyst such as borate and AlR3, these complexes 1-3 exhibit high activities of up to 6.8 x 104 (g of polymer)/(molLn h) and high cis-1,4 selectivities of up to 97% in the polymerization of isoprene in toluene, yielding the cis-1,4-polyisoprenes with heavy molecular weights (Mn of up to 710,000 g/mol) and bimodal molecular weight distributions (Mw/Mn = 2.0-4.5). isoprene 214-222 suppressor of cytokine signaling 1 Homo sapiens 154-159 30965837-3 2017 In the presence of a cocatalyst such as borate and AlR3, these complexes 1-3 exhibit high activities of up to 6.8 x 104 (g of polymer)/(molLn h) and high cis-1,4 selectivities of up to 97% in the polymerization of isoprene in toluene, yielding the cis-1,4-polyisoprenes with heavy molecular weights (Mn of up to 710,000 g/mol) and bimodal molecular weight distributions (Mw/Mn = 2.0-4.5). isoprene 214-222 suppressor of cytokine signaling 1 Homo sapiens 248-253 28660461-1 2017 Rubber is a polymer of isoprene, consisting mainly of cis-1,4-polyisoprene units. isoprene 23-31 suppressor of cytokine signaling 1 Homo sapiens 54-59 27264840-8 2016 The resulting activities of up to 6 x 10(5) mol isoprene per mol Co per h are the highest yet recorded for catalysts selective for cis-1,4 enchained polyisoprene. isoprene 48-56 suppressor of cytokine signaling 1 Homo sapiens 131-136 33444001-4 2021 Upon activation by [Ph3C][B(C6F5)4], 1-Y and 2-Lu could catalyze the living polymerization of isoprene and beta-myrcene with high catalytic activity and high cis-1,4-selectivity (up to 92.3% for isoprene and 98.5% for beta-myrcene). isoprene 94-102 suppressor of cytokine signaling 1 Homo sapiens 158-163 33444001-4 2021 Upon activation by [Ph3C][B(C6F5)4], 1-Y and 2-Lu could catalyze the living polymerization of isoprene and beta-myrcene with high catalytic activity and high cis-1,4-selectivity (up to 92.3% for isoprene and 98.5% for beta-myrcene). isoprene 195-203 suppressor of cytokine signaling 1 Homo sapiens 158-163 33444001-5 2021 Moreover, the 1-Y/[Ph3C][B(C6F5)4] catalytic system also could promote the polymerization of butadiene and its copolymerization with isoprene to produce copolymers with high cis-1,4-selectivity and narrow polydispersity. isoprene 133-141 suppressor of cytokine signaling 1 Homo sapiens 174-179 26008592-4 2015 These lanthanide complexes in combination with aluminum alkyls and [Ph3C](+)[B(C6F5)4](-) generated efficient homogeneous catalysts for the cis-1,4 polymerization of isoprene, with complex 1 having the best catalytic activity. isoprene 166-174 suppressor of cytokine signaling 1 Homo sapiens 140-145 21321731-5 2011 In the presence of AlMe(3), and in combination with one equimolar amount of [Ph(3)C][B(C(6)F(5))(4)], complexes 1 and 2 showed high activity towards isoprene polymerization to give high molecular weight polyisoprene (M(n) > 10(4)) with good cis-1,4 selectivity (>90%). isoprene 149-157 suppressor of cytokine signaling 1 Homo sapiens 244-249 17274086-0 2007 Cationic alkyl rare-earth metal complexes bearing an ancillary bis(phosphinophenyl)amido ligand: a catalytic system for living cis-1,4-polymerization and copolymerization of isoprene and butadiene. isoprene 174-182 suppressor of cytokine signaling 1 Homo sapiens 127-132