PMID-sentid	Pub_year	Sent_text		comp_official_name	comp_offsetprotein_name	organism	prot_offset
21370341-0	2011	Highly regio- and stereoselective three-component nickel-catalyzed syn-hydrocarboxylation of alkynes with diethyl zinc and carbon dioxide.	Nickel	50-56	synemin	Homo sapiens	67-70	
30489077-0	2018	Nickel Catalyzed syn-Selective Aryl Nickelation and Cyclization of Aldehyde/Enone-Tethered Terminal Alkynes with Arylboronic Acids.	Nickel	0-6	synemin	Homo sapiens	17-20	
17915885-3	2007	Treatment of the resulting 2-deoxy-2-thiotolyl-glycosides with hydrogen and Raney nickel affords the corresponding 2-deoxy-furanosides with a 1,3-syn relationship.	Nickel	82-88	synemin	Homo sapiens	146-149	
11300901-3	2001	The diastereoselectivity (syn/anti ratio) of the process was 86:14, attained with Raney nickel.	Nickel	88-94	synemin	Homo sapiens	26-29	
33568646-2	2021	Herein, we report the nickel-catalyzed intermolecular cross-dialkylation of alkynes devoid of directing or activating groups to afford multiple aliphatic substituted alkenes in a syn-selective fashion at room temperature.	Nickel	22-28	synemin	Homo sapiens	179-182	
33568646-3	2021	The combination of two-electron oxidative cyclometallation and single-electron cross-electrophile coupling of nickel enables the syn-cross-dialkylation of alkynes at room temperature.	Nickel	110-116	synemin	Homo sapiens	129-132	
20550150-0	2010	syn-Selective catalytic asymmetric 1,4-addition of alpha-ketoanilides to nitroalkenes under dinuclear nickel catalysis.	Nickel	102-108	synemin	Homo sapiens	0-3	
34410708-0	2021	Nickel-Catalyzed Enantioselective Synthesis of Pre-Differentiated Homoallylic syn- or anti-1,2-Diols from Aldehydes and Dienol Ethers.	Nickel	0-6	synemin	Homo sapiens	78-81	
30608102-0	2019	Nickel-catalyzed syn-stereocontrolled ring-opening of oxa- and azabicyclic alkenes with dialkylzinc reagents.	Nickel	0-6	synemin	Homo sapiens	17-20	
30608102-1	2019	A new nickel-catalyzed syn-stereocontrolled ring-opening of oxa- and azabicyclic alkenes with dialkylzinc reagents was developed, which afforded the corresponding cis-2-alkyl-1,2-dihydronaphthalen-1-ols and 1,2-alkyl amide derivatives in moderate to excellent yields (up to 99% yield) under mild conditions.	Nickel	6-12	synemin	Homo sapiens	23-26	
30382103-0	2018	syn-Selective alkylarylation of terminal alkynes via the combination of photoredox and nickel catalysis.	Nickel	87-93	synemin	Homo sapiens	0-3	
30746080-2	2019	Deuterium-labeling experiments and control experiments were conducted to probe the mechanism, and the results indicated that the acidity of the solvent plays a critical role in the control of diastereoselectivity by trapping the adduct of nickel hydride to C[double bond, length as m-dash]C bonds via protonolysis, giving the hydrogenation product with stereospecific syn-selectivity.	Nickel	239-245	synemin	Homo sapiens	368-371	
26771707-0	2016	Nickel-Catalyzed Double Bond Transposition of Alkenyl Boronates for in Situ syn-Selective Allylboration Reactions.	Nickel	0-6	synemin	Homo sapiens	76-79