PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 12444787-6 2002 In each subunit, the pair of metal ions separated at 3.130(1) A is assembled by a phenolate oxygen from L, and a monodentate and a syn-syn bidentate formate bridges. formic acid 149-156 synemin Homo sapiens 131-134 17725346-2 2007 All of these compounds adopt 3D framework structures consisting of InO6 octahedra and the 2.11 binding modes of formate with the (syn, syn-; syn, anti-; anti, anti-) configurations. formic acid 112-119 synemin Homo sapiens 130-133 17725346-2 2007 All of these compounds adopt 3D framework structures consisting of InO6 octahedra and the 2.11 binding modes of formate with the (syn, syn-; syn, anti-; anti, anti-) configurations. formic acid 112-119 synemin Homo sapiens 135-138 17725346-2 2007 All of these compounds adopt 3D framework structures consisting of InO6 octahedra and the 2.11 binding modes of formate with the (syn, syn-; syn, anti-; anti, anti-) configurations. formic acid 112-119 synemin Homo sapiens 135-138 21344112-0 2011 Structure and magnetic properties of an unprecedented syn-anti mu-nitrito-1kappaO:2kappaO" bridged Mn(III)-salen complex and its isoelectronic and isostructural formate analogue. formic acid 161-168 synemin Homo sapiens 54-57 21344112-2 2011 The structures show that the salen ligand coordinates to the four equatorial sites of the metal ion and the formate or nitrite ions coordinate to the axial positions to bridge the Mn(III)-salen units through a syn-antimu-1kappaO:2kappaO" coordination mode. formic acid 108-115 synemin Homo sapiens 210-213 19466800-3 2009 The structure displays triangular Mn(3) building blocks, in which the metal centers are bonded by formate ligands in a syn-anti mode (Mn-Mn 5.697(1) A). formic acid 98-105 synemin Homo sapiens 119-122 15038278-1 2004 We report a theoretical study on seven radical hydrogen bond complexes between syn-HCOOH and OH and eight radical hydrogen bond complexes between anti-HCOOH and OH, that have been carried out by using the B3LYP, MP2, QCISD, and CCSD(T) theoretical approaches with the 6-311 + G(2df,2p) basis set. formic acid 83-88 synemin Homo sapiens 79-82 12444787-7 2002 The formate group displays a novel tridentate mode, namely, monodentate and syn-anti bidentate bridges. formic acid 4-11 synemin Homo sapiens 76-79 25233266-3 2014 The structural variety is caused by the nature of the transition metals, the alkali metal ion templation, and the versatility of the formate group, which offers metal-metal coordination through three different O-C-O bridging modes (syn-syn, syn-anti, anti-anti) in addition to metal-metal bridging via a single oxygen atom. formic acid 133-140 synemin Homo sapiens 232-235 34955015-6 2022 The iPrPNPhP-ligated species is the most active for formic acid dehydrogenation, and mechanistic studies suggest that this is likely because there are kinetic advantages for catalysts that operate via the syn isomer. formic acid 52-63 synemin Homo sapiens 205-208 32321826-10 2020 We observe experimentally and predict theoretically fast reaction of syn-MVK-oxide with SO2 and formic acid, similar to smaller alkyl-substituted CIs, and by contrast, slow removal in the presence of water. formic acid 96-107 synemin Homo sapiens 69-72 26781998-1 2016 The synthesis of new enantiopure syn- and anti-3-(alpha-aminobenzyl)-benzo-gamma-sultam ligands 6 and their application in the ruthenium(ii)-catalyzed asymmetric transfer hydrogenation (ATH) of ketones using formic acid/triethylamine is described. formic acid 208-219 synemin Homo sapiens 4-7 25233266-3 2014 The structural variety is caused by the nature of the transition metals, the alkali metal ion templation, and the versatility of the formate group, which offers metal-metal coordination through three different O-C-O bridging modes (syn-syn, syn-anti, anti-anti) in addition to metal-metal bridging via a single oxygen atom. formic acid 133-140 synemin Homo sapiens 236-239 25233266-3 2014 The structural variety is caused by the nature of the transition metals, the alkali metal ion templation, and the versatility of the formate group, which offers metal-metal coordination through three different O-C-O bridging modes (syn-syn, syn-anti, anti-anti) in addition to metal-metal bridging via a single oxygen atom. formic acid 133-140 synemin Homo sapiens 236-239