PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 20117840-1 2010 The synthesis and characterization of ruthenium compounds of the type [RuCl(2)(NO)(dppp)(L)]PF(6) [dppp=1,3-bis(diphenylphosphino)propane; L=pyridine, 4-methylpyridine, 4-phenylpyridine and dimethyl sulfoxide] are described. Ruthenium 38-47 sperm associated antigen 17 Homo sapiens 92-97 21582999-1 2009 The title compound, [Ru(eta(5)-C(5)H(5)){eta(6)-C(6)H(2)(CH(3))(3)NH(2)}]PF(6), contains a sandwich complex with a mesitylamine unit which is significantly non-planar at the ipso-carbon of the amino group due to repulsive electronic effects with Ru. Ruthenium 21-23 sperm associated antigen 17 Homo sapiens 73-78 17658753-4 2007 For other alkynes, selective formation of the dihydrobenz[g]indole is possible by using a cationic Ru catalyst, [Cp*Ru(CH3CN)3]PF6. Ruthenium 99-101 sperm associated antigen 17 Homo sapiens 127-130 15489981-1 2004 Biphasic BMI[middle dot]PF(6)/toluene solvent is a remarkably suitable and clean medium for performing olefin metathesis with a new 2nd generation ionic liquid supported-ruthenium catalyst: high levels of recyclability and reusability combined with a high reactivity were obtained with a variety of di- or tri-substituted and/or oxygen-containing dienes, and very low residual ruthenium levels were detected (1 to 22 ppm) in the products. Ruthenium 170-179 sperm associated antigen 17 Homo sapiens 24-29 15962041-1 2005 The P4 molecule bound to ruthenium as an eta1-ligand in [CpRu(PPh3)2(eta1-P4)]Y (Y = PF6, CF3SO3) undergoes an easy reaction with water in exceedingly mild conditions to yield PH3, which remains coordinated to the [CpRu(PPh3)2] fragment, and oxygenated derivatives. Ruthenium 25-34 sperm associated antigen 17 Homo sapiens 85-88 15489981-1 2004 Biphasic BMI[middle dot]PF(6)/toluene solvent is a remarkably suitable and clean medium for performing olefin metathesis with a new 2nd generation ionic liquid supported-ruthenium catalyst: high levels of recyclability and reusability combined with a high reactivity were obtained with a variety of di- or tri-substituted and/or oxygen-containing dienes, and very low residual ruthenium levels were detected (1 to 22 ppm) in the products. Ruthenium 377-386 sperm associated antigen 17 Homo sapiens 24-29 9438842-0 1998 Bimetallic system for nitrogen fixation: ruthenium-assisted protonation of coordinated N2 on tungsten with H2 Treatment of the tungsten dinitrogen complex cis-[W(N2)2(PMe2Ph)4] (Me = methyl, Ph = phenyl) with an equilibrium mixture of [RuCl(dppp)2]X and trans-[RuCl(eta2-H2)(dppp)2]X [X = BF4, PF6, or OSO2CF3; dppp = 1,3-bis(diphenylphosphino)propane] under 1 atmosphere of dihydrogen at 55 degrees Celsius for 24 hours gave NH3 in moderate yield. Ruthenium 41-50 sperm associated antigen 17 Homo sapiens 295-298 12515496-1 2003 The ruthenium catalyst [Cp*Ru(MeCN)3]PF6 effects a novel intramolecular hydrosilylation of homo- and bis-homopropargylic alcohols, producing products of unique regioselectivity under very mild conditions with excellent selectivity. Ruthenium 4-13 sperm associated antigen 17 Homo sapiens 37-40 12686486-3 2003 LD spectra of the PF(6) salt of the Ru and Os complexes reveal counterion attachment, fluoride transfer, and significant losses of H for a number of peaks. Ruthenium 36-38 sperm associated antigen 17 Homo sapiens 18-23 32065454-4 2020 Recently, we reported a ruthenium complex ( [Ru(DIP) 2 (sq)](PF 6 ) where DIP is 4,7-diphenyl-1,10-phenantroline and sq is the semiquinonate), with a remarkable potential as chemotherapeutic agent against cancer, both in vitro and in vivo . Ruthenium 24-33 sperm associated antigen 17 Homo sapiens 61-65 32166853-4 2020 Ru(bpz) 3 (PF 6 ) 2 was utilized as the standard ruthenium catalyst and laser flash photolysis studies provided evidence that the catalyst operates exclusively by triplet energy transfer (sensitization). Ruthenium 49-58 sperm associated antigen 17 Homo sapiens 0-19 32065454-5 2020 In this work, we analyse a structurally similar compound, namely [Ru(DIP) 2 (mal)](PF 6 ) , carrying the flavour-enhancing agent approved by the FDA, maltol (mal). Ruthenium 66-68 sperm associated antigen 17 Homo sapiens 83-87 32065454-7 2020 Herein, we describe the synthesis and characterisation of [Ru(DIP) 2 (mal)](PF 6 ) , its stability in solutions and in conditions which resemble the physiological ones, and its in-depth biological investigation. Ruthenium 59-61 sperm associated antigen 17 Homo sapiens 76-80 32065454-9 2020 [Ru(DIP) 2 (mal)](PF 6 ) was efficiently internalised by HeLa cells through a passive transport mechanism and severely affected the mitochondrial metabolism. Ruthenium 1-3 sperm associated antigen 17 Homo sapiens 18-22 32108850-2 2020 In this study, cytotoxic activities and the possible mechanism of cell death induced by three ruthenium complexes were evaluated, [Ru(MIm)(bipy)(dppf)]PF6 (1), [RuCl(Im)(bipy)(dppf)]PF6 (2) and [Ru(tzdt)(bipy)(dppf)]PF6 (3). Ruthenium 94-103 sperm associated antigen 17 Homo sapiens 182-185 32108850-2 2020 In this study, cytotoxic activities and the possible mechanism of cell death induced by three ruthenium complexes were evaluated, [Ru(MIm)(bipy)(dppf)]PF6 (1), [RuCl(Im)(bipy)(dppf)]PF6 (2) and [Ru(tzdt)(bipy)(dppf)]PF6 (3). Ruthenium 94-103 sperm associated antigen 17 Homo sapiens 182-185 28640601-1 2017 The one-electron reduction of [CpRu(bpy)NCCH3]PF6 (Cp = cyclopentadienyl; bpy = 2,2"-bipyridine), abbreviated as [Ru-S]+, where S = CH3CN, in CO2-saturated acetonitrile initiates a cascade of rapid electrochemical and chemical steps (ECEC) at an electrode potential of ca. Ruthenium 114-118 sperm associated antigen 17 Homo sapiens 46-49 31338323-1 2019 Herein, ruthenium complexes containing heterocyclic thioamidates [Ru(mmi)(bipy)(dppb)]PF6 (1), [Ru(tzdt)(bipy)(dppb)]PF6 (2), [Ru(dmp)(bipy)(dppb)]PF6 (3) and [Ru(mpca)(bipy)(dppb)]PF6 (4) were investigated for their cellular and molecular effects in cancer cell lines. Ruthenium 8-17 sperm associated antigen 17 Homo sapiens 86-89 31338323-1 2019 Herein, ruthenium complexes containing heterocyclic thioamidates [Ru(mmi)(bipy)(dppb)]PF6 (1), [Ru(tzdt)(bipy)(dppb)]PF6 (2), [Ru(dmp)(bipy)(dppb)]PF6 (3) and [Ru(mpca)(bipy)(dppb)]PF6 (4) were investigated for their cellular and molecular effects in cancer cell lines. Ruthenium 8-17 sperm associated antigen 17 Homo sapiens 117-120 31338323-1 2019 Herein, ruthenium complexes containing heterocyclic thioamidates [Ru(mmi)(bipy)(dppb)]PF6 (1), [Ru(tzdt)(bipy)(dppb)]PF6 (2), [Ru(dmp)(bipy)(dppb)]PF6 (3) and [Ru(mpca)(bipy)(dppb)]PF6 (4) were investigated for their cellular and molecular effects in cancer cell lines. Ruthenium 8-17 sperm associated antigen 17 Homo sapiens 117-120 31338323-1 2019 Herein, ruthenium complexes containing heterocyclic thioamidates [Ru(mmi)(bipy)(dppb)]PF6 (1), [Ru(tzdt)(bipy)(dppb)]PF6 (2), [Ru(dmp)(bipy)(dppb)]PF6 (3) and [Ru(mpca)(bipy)(dppb)]PF6 (4) were investigated for their cellular and molecular effects in cancer cell lines. Ruthenium 8-17 sperm associated antigen 17 Homo sapiens 117-120 30914954-4 2019 Thus, the present study evaluated the effect of the ruthenium complex donor of NO {[Ru(bpy)2(NO)SO3](PF6)} (complex I) in gout arthritis. Ruthenium 52-61 sperm associated antigen 17 Homo sapiens 101-104 28941025-1 2017 A photolabile ruthenium-based complex, [Ru(bpy)2 (4AMP)2 ](PF6 )2 , (4AMP=4-(aminomethyl)pyridine) is incorporated into polyurea organo- and hydrogels via the reactive amine moieties on the photocleavable 4AMP ligands. Ruthenium 14-23 sperm associated antigen 17 Homo sapiens 59-62 28586201-1 2017 We present the synthesis and characterization of novel cyclometalated ruthenium N-heterocyclic carbene (NHC) complexes of the general formula [Ru(C^C*)(bpy)2]PF6 (bpy = 2,2"-bipyridine), with the C^C* ligand being based on different 1-phenylimidazoles. Ruthenium 142-145 sperm associated antigen 17 Homo sapiens 158-161 31840945-4 2020 In this communication, we demonstrate that two ruthenium complexes previously reported by our group for their chemotherapeutic potential against cancer, namely [Ru(DIP)2(sq)](PF6) and [Ru(DIP)2(3-methoxysq)](PF6), where DIP is 4,7-diphenyl-1,10-phenanthroline, sq = semiquinonate and 3-methoxysq = 3-methoxysemiquinonate, form colloids in water-DMSO (1% v/v) mixtures that are invisible to the naked eyes. Ruthenium 47-56 sperm associated antigen 17 Homo sapiens 175-178 31840945-4 2020 In this communication, we demonstrate that two ruthenium complexes previously reported by our group for their chemotherapeutic potential against cancer, namely [Ru(DIP)2(sq)](PF6) and [Ru(DIP)2(3-methoxysq)](PF6), where DIP is 4,7-diphenyl-1,10-phenanthroline, sq = semiquinonate and 3-methoxysq = 3-methoxysemiquinonate, form colloids in water-DMSO (1% v/v) mixtures that are invisible to the naked eyes. Ruthenium 47-56 sperm associated antigen 17 Homo sapiens 208-211 31180358-4 2019 Altogether, [(DPEPhos)(bcp)Cu]PF6 acts as a convenient photoredox catalyst which appears to be an attractive, cheap and complementary alternative to the state-of-the-art iridium- and ruthenium-based photoredox catalysts. Ruthenium 183-192 sperm associated antigen 17 Homo sapiens 30-33 27225494-2 2016 METHODS: Ruthenium-based dye Ru(bpy)2(mcbpy - O - Su - ester)(PF6)2, whose lifetime of several hundred nanoseconds is comparable to the rotational correlation time of these drugs in buffer, was used as a label. Ruthenium 9-18 sperm associated antigen 17 Homo sapiens 62-65 21588544-1 2010 In the title compound, [RuCl(C(10)H(14))(C(14)H(16)N(2))]PF(6), the aromatic ring of the isopropyl-methyl-benzene fragment shows an eta(6)-arene coordination to the ruthenium atom. Ruthenium 165-174 sperm associated antigen 17 Homo sapiens 57-62 27193490-4 2016 In addition, the ruthenium(ii) and iridium(iii) complexes [RuCl(MeIm-(o-phenylene)-MeIm)(p-cym)](PF6) and [IrClCp*(MeIm-(o-phenylene)-MeIm)](PF6) were prepared and shown to present in these cases a chelating coordination of the di(N-heterocyclic carbene) ligand. Ruthenium 17-26 sperm associated antigen 17 Homo sapiens 97-100 26344929-3 2015 Complexes 1(PF6)-6(PF6) (from short to long in length) with the organic redox-active amine and inorganic cyclometalated ruthenium termini bridged by the para-oligophenylene wire have been prepared. Ruthenium 120-129 sperm associated antigen 17 Homo sapiens 12-15 26344929-3 2015 Complexes 1(PF6)-6(PF6) (from short to long in length) with the organic redox-active amine and inorganic cyclometalated ruthenium termini bridged by the para-oligophenylene wire have been prepared. Ruthenium 120-129 sperm associated antigen 17 Homo sapiens 19-22 25738762-8 2015 Importantly, the chiral ruthenium complexes can be recycled as Delta/Lambda-[Ru(bpy)2(MeCN)2](PF6)2 and reused in a next reaction cycle with complete retention of the configurations at ruthenium centers. Ruthenium 24-33 sperm associated antigen 17 Homo sapiens 94-97 25738762-8 2015 Importantly, the chiral ruthenium complexes can be recycled as Delta/Lambda-[Ru(bpy)2(MeCN)2](PF6)2 and reused in a next reaction cycle with complete retention of the configurations at ruthenium centers. Ruthenium 185-194 sperm associated antigen 17 Homo sapiens 94-97 24533637-1 2014 The effects of the nonprotonated and protonated calix[6]crypturea 1/1( )H(+) on the PF6(-) and Cl(-) salts of a luminescent Ru-TAP complex (TAP = 1,4,5,8-tetraazaphenanthrene) were investigated. Ruthenium 124-126 sperm associated antigen 17 Homo sapiens 84-87 23971074-1 2013 Ruthenium nanoparticle tris(2,2"-bipyridyl)ruthenium(II) bis(hexafluorophosphate) (Ru(bpy)3(PF6)2, RuNP) was self-assembled on polystyrene (PS) electrospun microfibers. Ruthenium 0-9 sperm associated antigen 17 Homo sapiens 92-95 26494105-1 2016 Mono- and multinuclear complexes of ruthenium and [n]cycloparaphenylene (CPP, n = 5 and 6) were synthesized in excellent yields through ligand exchange of the cationic complex [(Cp)Ru(CH3CN)3](PF6) with CPP. Ruthenium 36-45 sperm associated antigen 17 Homo sapiens 193-196 24292453-2 2014 A hydrophobic cyclometallated ruthenium complex [Ru(II)(bpy)2(thpy)]PF6 (abbreviated as Ru1; bpy = 2,2"-bipyridine and thpy = 2-(2-thienyl)pyridine) is employed as a chemodosimeter to assemble on amphiphilic polymer-coating upconversion nanophosphors (UCNPs) based on the hydrophobic-hydrophobic interaction. Ruthenium 30-39 sperm associated antigen 17 Homo sapiens 68-71 23284392-1 2012 In the crystal of the title compound, [Ru(C(2)H(6)NS)(C(26)H(24)P(2))(2)]PF(6), the Ru(II) atom is in a slightly distorted octa-hedral geometry, coordinated by one 2-amino-ethane-thiol-ate (aet) and two 1,2-bis-(diphenyl-phosphan-yl)ethane (dppe) ligands. Ruthenium 39-42 sperm associated antigen 17 Homo sapiens 73-78