PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 11878988-2 2002 The unusual luminescence behavior of the two-coordinate gold(I) carbene complex, [Au[C(NHMe)(2)](2)](PF(6)) x 0.5(acetone), is reported. Acetone 114-121 sperm associated antigen 17 Homo sapiens 101-106 27048724-1 2016 The only crystals that could be grown from racemic solutions of the PF6(-) salt of the resolvable cation [Ru(2,9-dimethyl-1,10-phenanthroline)2(dipyrido[3,2-d:2",3"-f]quinoxaline)](2+) have translational symmetry only (space group P1), contain nine independent sets of ions, and include numerous independent solvent molecules (11 acetone, one diethyl ether and possibly several water molecules). Acetone 330-337 sperm associated antigen 17 Homo sapiens 68-71 15822986-4 2005 Specifically, a diester cryptand with a pyridyl nitrogen atom located at a site occupied by either water or a PF(6) anion in analogous complexes exhibited the highest association constant K(a) = 5.0 x 10(6) M(-1) in acetone with paraquat, 9000 times greater than the crown ether system. Acetone 216-223 sperm associated antigen 17 Homo sapiens 110-115 15252529-2 2004 Treatment of [Ru(trpy)(PD-N,N")Cl](PF6) with AgClO4 in a mixed solvent of acetone and H2O selectively produced the acetonyl-PD complex [1](ClO4)2, and the similar treatment in a mixed solvent of 2-methoxyethanol and H2O gave the PD complex [2](ClO4)2. Acetone 74-81 sperm associated antigen 17 Homo sapiens 35-38 28880039-1 2017 This study shows that gold salts [(L)AuX] (L = PMe3, PPh3, JohnPhos, IPr; X = SbF6, PF6, BF4, TfO, Tf2N) act as bases in aqueous solutions and can transform acetone to digold acetonyl complexes [(L)2Au2(CH2COCH3)]+ without any additional base present in solution. Acetone 157-164 sperm associated antigen 17 Homo sapiens 84-87 16609766-9 2006 The reaction of 1 with AgPF6 in acetone afforded complex [Ru(eta6-cymene)(N,O,O)]PF6 (7, where N,O,O = 4-alcoxide-4-phenyl-4-(pyridin-2-yl)butan-2-one) from the C-C coupling of a deprotonated methyl group of the coordinated acetone and the C=O moiety of 2-bzpy ligand. Acetone 32-39 sperm associated antigen 17 Homo sapiens 25-28 12693212-11 2003 of 6b with acetone forms the methyl enolate complex [Ru2(trpy)2(6,6"-Me2dppz)(CH2COCH3)](PF6)2 (9b) while, analogously to a Cannizarro reaction, the reaction with benzaldehyde forms the bridging benzoate complex [Ru2(trpy)2(6,6"-Me2dppz)(C6H4CO2)](PF6)2 (11b). Acetone 11-18 sperm associated antigen 17 Homo sapiens 89-92 12693212-11 2003 of 6b with acetone forms the methyl enolate complex [Ru2(trpy)2(6,6"-Me2dppz)(CH2COCH3)](PF6)2 (9b) while, analogously to a Cannizarro reaction, the reaction with benzaldehyde forms the bridging benzoate complex [Ru2(trpy)2(6,6"-Me2dppz)(C6H4CO2)](PF6)2 (11b). Acetone 11-18 sperm associated antigen 17 Homo sapiens 248-251 11878988-3 2002 Upon freezing in a liquid N(2) bath, the colorless, nonluminescent solutions of [Au[C(NHMe)(2)](2)](PF(6)) x 0.5(acetone) become intensely luminescent. Acetone 113-120 sperm associated antigen 17 Homo sapiens 100-105 11878988-5 2002 Solid [Au[C(NHMe)(2)](2)](PF(6)) x 0.5(acetone) is also luminescent, and the luminescence is attributed to the formation of extended chains of gold(I) centers that are connected through aurophilic attractions. Acetone 39-46 sperm associated antigen 17 Homo sapiens 26-31 11878988-8 2002 In contrast, [Au[C(NMe(2))(NHMe)](2)](PF(6)) forms a colorless, nonluminescent solid, and in that solid there are no Au...Au interactions, a factor which supports the contention that aggregated species are responsible for the luminescence of [Au[C(NHMe)(2)](2)](PF(6)) x 0.5(acetone) in the solid state and in frozen solutions. Acetone 275-282 sperm associated antigen 17 Homo sapiens 38-43 12526521-4 2000 1(2+) reacts slowly with PF6- anions in acetone or KF in CH2Cl2 to yield the mu 3-fluorido complex 2(2+) with idealized D3 symmetry, containing a trigonal planar Cu3F core, as shown by single-crystal X-ray diffraction. Acetone 40-47 sperm associated antigen 17 Homo sapiens 25-28 29711853-1 1999 Anions PF6- and CF3 SO3- are trapped by the new radical host [(Cu-dppe)3 {hat-(CN)6 }]2+ , which was synthesized in a one-pot reaction from a copper(I) source, hat-(CN)6 , and dppe in acetone. Acetone 184-191 sperm associated antigen 17 Homo sapiens 7-23 11666335-8 1996 The thallium(I) complex with a ligand to metal ratio of 1/1, {[HC(3,5-Me(2)pz)(3)]Tl}PF(6), is prepared in acetone by the reaction of equimolar amounts of HC(3,5-Me(2)pz)(3) and TlPF(6). Acetone 107-114 sperm associated antigen 17 Homo sapiens 85-90 11669713-8 1997 Solutions of 1(2+) react with acetone to give the S-acetonyl derivative [(C(5)Me(5))(3)RhRu(2)S(3)(SCH(2)COCH(3))]PF(6), 4(PF(6)). Acetone 30-37 sperm associated antigen 17 Homo sapiens 114-119 11669713-8 1997 Solutions of 1(2+) react with acetone to give the S-acetonyl derivative [(C(5)Me(5))(3)RhRu(2)S(3)(SCH(2)COCH(3))]PF(6), 4(PF(6)). Acetone 30-37 sperm associated antigen 17 Homo sapiens 123-128 34443161-2 2021 The study found that the paper can realize the reversible control of surface wettability through the exchange between the anions PF6- and Cl- adsorbed on the surface of PMETAC, and further investigation of the effect of different solvents on the ion exchange properties found that water was the poor solvent for ion exchange, while the mixtures of methanol, acetone, and methanol & water were the good solvent. Acetone 358-365 sperm associated antigen 17 Homo sapiens 129-132 32597427-4 2020 The results of acetone sorption isotherm measurements show that gate opening and closing pressures of the solid solutions are dependent on the composition ratios of PAC-2-CF3SO3 and PAC-2-PF6. Acetone 15-22 sperm associated antigen 17 Homo sapiens 188-191