PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 12950226-2 2003 Reaction of [Co(NH(3))(5)Cl]Cl(2) with PyPS(4)(-) in DMF affords the thiolato-bridged dimeric Co(III) complex (Et(4)N)(2)[Co(2)(PyPS)(2)] (1). co(2) 122-127 mitochondrially encoded cytochrome c oxidase III Homo sapiens 97-100 11531445-3 2001 The volume of activation for the reaction (hedta)Fe(III)-CO(2)(2-) + CO(2)(*-) + 2H(+) --> Fe(II)(hedta)(H(2)O)(-) + CO + CO(2) was measured, and the results enable a tentative proposal for the nature of the transition state of this interesting reaction. co(2) 57-62 mitochondrially encoded cytochrome c oxidase III Homo sapiens 52-55 11531445-3 2001 The volume of activation for the reaction (hedta)Fe(III)-CO(2)(2-) + CO(2)(*-) + 2H(+) --> Fe(II)(hedta)(H(2)O)(-) + CO + CO(2) was measured, and the results enable a tentative proposal for the nature of the transition state of this interesting reaction. co(2) 69-74 mitochondrially encoded cytochrome c oxidase III Homo sapiens 52-55 22857013-6 2012 In this Account, we outline our efforts to develop highly active Co(III)-based catalysts for the selective production of polycarbonates from the alternating copolymerization of CO(2) with epoxides. co(2) 177-182 mitochondrially encoded cytochrome c oxidase III Homo sapiens 65-72 22857013-7 2012 Binary systems consisting of simple (salen)Co(III)X and a nucleophilic cocatalyst exhibited high activity under mild conditions even at 0.1 MPa CO(2) pressure and afforded copolymers with >99% carbonate linkages and a high regiochemical control (~95% head-to-tail content). co(2) 144-149 mitochondrially encoded cytochrome c oxidase III Homo sapiens 46-49 22857013-8 2012 Discrete, one-component (salen)Co(III)X complexes bearing an appended quaternary ammonium salt or sterically hindered Lewis base showed excellent activity in the selectively alternating copolymerization of CO(2) with both aliphatic epoxides and cyclohexene oxide at high temperatures with low catalyst loading and/or low pressures of CO(2). co(2) 206-211 mitochondrially encoded cytochrome c oxidase III Homo sapiens 34-37 22857013-8 2012 Discrete, one-component (salen)Co(III)X complexes bearing an appended quaternary ammonium salt or sterically hindered Lewis base showed excellent activity in the selectively alternating copolymerization of CO(2) with both aliphatic epoxides and cyclohexene oxide at high temperatures with low catalyst loading and/or low pressures of CO(2). co(2) 334-339 mitochondrially encoded cytochrome c oxidase III Homo sapiens 34-37 22857013-9 2012 Binary or one-component catalysts based on unsymmetric multichiral Co(III) complexes facilitated the efficient enantioselective copolymerization of CO(2) with epoxides, providing aliphatic polycarbonates with >99% head-to-tail content. co(2) 148-153 mitochondrially encoded cytochrome c oxidase III Homo sapiens 67-74 22857013-14 2012 The high activity and excellent regioselectivity observed in the epoxide ring-opening reactions results from epoxide activation through the moderate electrophilicity of the Co(III) ion, the fast insertion of CO(2) into the Co-O bond, and the facile dissociation of the propagating carboxylate species from the central metal ion. co(2) 208-213 mitochondrially encoded cytochrome c oxidase III Homo sapiens 173-180