PMID-sentid	Pub_year	Sent_text		comp_official_name	comp_offsetprotein_name	organism	prot_offset
12945905-1	2003	The reaction of aryl alkynes with dilute methylene chloride solutions of quaternary ammonium bromide and 20% trifluoroacetic acid produces primarily the syn Markovnikov adducts of hydrogen bromide.	Methylene Chloride	41-59	synemin	Homo sapiens	153-156	
17503848-3	2007	The thermal syn-addition of these sulfenic acids onto the triple bonds of the unsaturated acceptors was conducted in CH2Cl2 at 40 degrees C. The concentration of sulfoxide precursors of sulfenic acid and the sulfoxide/acceptor molar ratio addressed the syn-addition toward open-chain benzene sulfoxides or thiacyclophane S-oxides.	Methylene Chloride	117-123	synemin	Homo sapiens	12-15	
22077105-3	2012	Ring fusion using standard Scholl reaction conditions (FeCl(3), dichloromethane) occurs for perylene-substituted porphyrins to give a porphyrin beta,meso annulated with perylene rings (0.7:1 ratio of syn and anti isomers).	Methylene Chloride	64-79	synemin	Homo sapiens	200-203	
20349936-6	2010	Reaction of a dichloromethane solution of 1 with a 36% aqueous solution of HCHO in the presence of H(2)SO(4) quantitatively converts 1 at room temperature to a 1:1 mixture of the syn- and anti-isomers of B(18)H(22).	Methylene Chloride	14-29	synemin	Homo sapiens	179-182	
16117501-2	2005	Pretreatment of alpha-fluoropropiophenone with TiCl4 followed by reduction with LiBH4 in diethyl ether or methylene chloride provided the syn diastereomer predominantly, while use of Ti(OiPr)4 under identical conditions provided the anti diastereomer as the major product.	Methylene Chloride	106-124	synemin	Homo sapiens	138-141	
11674293-3	1999	Strongly chelating TiCl(4) led to the syn isomer in high diastereomeric excess in noncoordinating solvents (CH(2)Cl(2)) at -78 degrees C with BH(3).py as reducing agent, while nonchelating CeCl(3) gave a high excess of the anti isomer in coordinating solvents (THF) at the same temperature with lithium triethylborohydride (LiEt(3)BH) as reducing agent.	Methylene Chloride	108-119	synemin	Homo sapiens	38-41	
11843606-3	2002	Treatment of a dichloromethane solution of syn- and anti-1,3-diol-acetonide with a catalytic amount of diluted aqueous hydrochloric acid leads to the selective cleavage of the anti diastereomer.	Methylene Chloride	15-30	synemin	Homo sapiens	43-46