PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 24507930-4 2014 Each compound can undergo two metal-centered one-electron reductions leading to formation of Co(II) and Co(I) derivatives in CH2Cl2 or pyridine containing 0.1 M tetra-n-butylammonium perchlorate (TBAP). Methylene Chloride 125-131 mitochondrially encoded cytochrome c oxidase II Homo sapiens 93-99 35049285-2 2022 It was found that the Co(II)-Co(II) bond allows for protonation by (HPPh3)(BF4) resulting in a bridging hydride, (1H)+, with pKa ~ 7.6 in CH2Cl2. Methylene Chloride 138-144 mitochondrially encoded cytochrome c oxidase II Homo sapiens 22-28 35049285-2 2022 It was found that the Co(II)-Co(II) bond allows for protonation by (HPPh3)(BF4) resulting in a bridging hydride, (1H)+, with pKa ~ 7.6 in CH2Cl2. Methylene Chloride 138-144 mitochondrially encoded cytochrome c oxidase II Homo sapiens 29-35 29064238-4 2017 Two irreversible reductions are observed for (TpYPP)CoII and butano(TpYPP)CoII in CH2Cl2 containing 0.1 M tetra-n-butylammonium perchlorate; the first leads to the formation of a highly reactive cobalt(I) porphyrin, which can then rapidly react with a solvent to give a CoIIICH2Cl as the product. Methylene Chloride 82-88 mitochondrially encoded cytochrome c oxidase II Homo sapiens 52-56 29064238-4 2017 Two irreversible reductions are observed for (TpYPP)CoII and butano(TpYPP)CoII in CH2Cl2 containing 0.1 M tetra-n-butylammonium perchlorate; the first leads to the formation of a highly reactive cobalt(I) porphyrin, which can then rapidly react with a solvent to give a CoIIICH2Cl as the product. Methylene Chloride 82-88 mitochondrially encoded cytochrome c oxidase II Homo sapiens 74-78 24507930-9 2014 Thin-layer UV-visible spectroelectrochemical measurements in CH2Cl2, 0.1 M TBAP demonstrate the occurrence of an equilibrium between a Co(III) pi-anion radical and a Co(II) derivative with an uncharged macrocycle after the first controlled potential reduction of the nitro-substituted corroles. Methylene Chloride 61-67 mitochondrially encoded cytochrome c oxidase II Homo sapiens 166-172 23517550-15 2013 The CH2Cl2 solution of Co(salen)(X) shows an intense near-IR absorption, which is assigned as overlapped transitions from a ligand-to-metal charge transfer in Co(III)(salen)(X) and a ligand-to-ligand charge transfer in Co(II)(salen( +))(X). Methylene Chloride 4-10 mitochondrially encoded cytochrome c oxidase II Homo sapiens 219-225 24266650-1 2013 A Co(II) anilinosalen catalyst containing proton relays in the first coordination sphere has been synthesized that catalyzes the electrochemical production of hydrogen from acid in dichloromethane and acetonitrile solutions. Methylene Chloride 181-196 mitochondrially encoded cytochrome c oxidase II Homo sapiens 2-8 24427928-6 2013 The dichloromethane extract of privet leaves showed a considerable inhibitory effect against COX-1 and COX-2 enzyme activity. Methylene Chloride 4-19 mitochondrially encoded cytochrome c oxidase II Homo sapiens 103-108 20353154-1 2010 The isomerization dynamics of five labile octahedral Co(II) compounds have been investigated by variable temperature and pressure (1)H and (19)F NMR spectroscopy in dichloromethane solution. Methylene Chloride 165-180 mitochondrially encoded cytochrome c oxidase II Homo sapiens 53-59 16212342-2 2005 The X-ray structure of 1 grown in dichloromethane shows square-pyramidal coordination around the Co(II) ion, displaying a 1D polymeric network. Methylene Chloride 34-49 mitochondrially encoded cytochrome c oxidase II Homo sapiens 97-103 19214306-2 2009 Both C-Cl bonds of CH(2)Cl(2) are readily activated by CoCl(2) and metallic Zn allowing quantitative methylation of phosphines; unprecedented zwitterionic Co(ii) and Zn(ii) intermediates have been characterized which display alpha-metallated phosphoniums. Methylene Chloride 19-29 mitochondrially encoded cytochrome c oxidase II Homo sapiens 155-161 19214306-2 2009 Both C-Cl bonds of CH(2)Cl(2) are readily activated by CoCl(2) and metallic Zn allowing quantitative methylation of phosphines; unprecedented zwitterionic Co(ii) and Zn(ii) intermediates have been characterized which display alpha-metallated phosphoniums. Methylene Chloride 19-29 mitochondrially encoded cytochrome c oxidase II Homo sapiens 158-160 18097493-11 2008 Cyclic voltammetry experiments in MeCN-CH2Cl2 reveal facile metal-centred reversible-to-quasireversible CoIV-CoIII (or a ligand-centred redox process; 2a), CoIII-CoII (1a, 1b.MeOH, 2a, 2b and 3), CoII-CoI (1a, 1b.MeOH, 2aand 2b), and CoI-Co0 (1a, 1b.MeOH and 2b) redox processes. Methylene Chloride 39-45 mitochondrially encoded cytochrome c oxidase II Homo sapiens 109-113 18097493-11 2008 Cyclic voltammetry experiments in MeCN-CH2Cl2 reveal facile metal-centred reversible-to-quasireversible CoIV-CoIII (or a ligand-centred redox process; 2a), CoIII-CoII (1a, 1b.MeOH, 2a, 2b and 3), CoII-CoI (1a, 1b.MeOH, 2aand 2b), and CoI-Co0 (1a, 1b.MeOH and 2b) redox processes. Methylene Chloride 39-45 mitochondrially encoded cytochrome c oxidase II Homo sapiens 156-160 11488453-2 2001 Dichloromethane (DCM) extracts from dried leaves showed a marked cyclooxygenase (COX) inhibitory activity with a preferential effect on COX-2 catalysed prostaglandin synthesis. Methylene Chloride 0-15 mitochondrially encoded cytochrome c oxidase II Homo sapiens 136-141 11488453-2 2001 Dichloromethane (DCM) extracts from dried leaves showed a marked cyclooxygenase (COX) inhibitory activity with a preferential effect on COX-2 catalysed prostaglandin synthesis. Methylene Chloride 17-20 mitochondrially encoded cytochrome c oxidase II Homo sapiens 136-141