PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 34528045-2 2021 The synthetic route used reactions of either (Sn{N(SiMe3)2}2) or (Sn(NMe2)2) with one or two equivalents of the aminoalcohols (a-d) in dry aprotic solvents leading to elimination of amines and formation of the Sn(II) species 1a-d, 2a-d and 3a-d respectively. Amines 182-188 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 69-73 34357749-0 2021 Reduction of Amides to Amines with Pinacolborane Catalyzed by Heterogeneous Lanthanum Catalyst La(CH2C6H4NMe2-o)3@SBA-15. Amines 23-29 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 105-109 34357749-2 2021 In this contribution, it was found that the supported lanthanum benzyl material La(CH2C6H4NMe2-o)3@SBA-15 was highly active for the hydroboration of primary, secondary, and tertiary amides to amines with pinacolborane. Amines 192-198 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 90-94 35621263-8 2022 The differences between the C-H sigma-bond activation of benzene and the N-H sigma-bond activation of these amines are discussed in terms of the N-H, C-H, Ni-Ph, and Ni-NMe2, and Ni-N(Me)(Bs) bond energies and back-donation to benzene from the Ni atom. Amines 108-114 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 169-173 26924395-2 2016 Preliminary coordination chemistry is presented involving phosphine (IPr[double bond, length as m-dash]CH)PR2 (R = (i)Pr and Ph) and amine (IPr[double bond, length as m-dash]CH)NMe2 ligands and the Lewis acids BH3 and AuCl. Amines 133-138 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 177-181 31233290-5 2019 Complex 8-2THF results from the oxidative addition of an amine C-H bond followed by migration to the vinylic group of the formal [C(tBu)CHC(tBu)NCH2 CH2 N(Me)CH2 CH2 NMe2 ]- ligand in 7. Amines 57-62 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 166-170 28920626-3 2017 of Ga2(NMe2)6 allowed the isolation of the corresponding (salen)Ga-NMe2 chelates (2b-2d, 2f) via an amine elimination route, as poorly soluble compounds in common solvents. Amines 100-105 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 7-11 28920626-3 2017 of Ga2(NMe2)6 allowed the isolation of the corresponding (salen)Ga-NMe2 chelates (2b-2d, 2f) via an amine elimination route, as poorly soluble compounds in common solvents. Amines 100-105 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 67-71 33676700-6 2021 It is probably based on stabilization of AuNPs with an amine that entails a decrease in the degree of their adsorption on PUF and appearance of the stabilized AuNPs in solution. Amines 55-60 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 122-125 32955246-2 2020 This protocol features the employment of Ti(NMe2)4 both as the metal center to trigger the deprotonation of the ligands and as an amine source to proceed the amidation reactions of carbonyl functionalities of the ligands. Amines 130-135 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 44-48 31718171-3 2019 Catalysis using commercially available Zr(NMe2)4, affords an alternative disconnection to access alpha-arylated primary amines upon aqueous work-up. Amines 97-126 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 42-46 26161731-1 2015 The cross-coupling of aryl tosylates with amines and anilines was achieved by using for the first time a Pd-NHC system based on the popular Pd-PEPPSI precatalyst platform in which the anchoring imidazol-2-ylidene ligand IPr((NMe2)2) incorporates two dimethylamino groups as backbone substituents enhancing both the electronic and steric properties of the carbene. Amines 42-48 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 225-229 25041474-1 2014 The design and synthesis of a mixed 2-pyridonate-Ta(NMe2)3Cl complex for the direct C-H alkylation adjacent to nitrogen in unprotected secondary amines are reported. Amines 145-151 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 52-56 23941398-5 2013 The thermal pathway was found to involve the dissociation of the terminal amine to form [H2B(mu-H)(mu-NMe2)BH2] (5) and NMe3 as intermediates, with the former operating as a catalyst and accelerating the redistribution of 1. Amines 74-79 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 102-106 18092780-2 2008 This study reveals that tris(amido)Al(III) catalysts, such as Al2(NMe2)6, promote facile equilibrium-controlled transamidation of tertiary carboxamides with secondary amines. Amines 167-173 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 66-70 16848465-1 2006 Reaction of Ti(NMe2)4 with allyl alcohols and primary amines leads to the selective formation of secondary allylic amines. Amines 54-60 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 15-19 16848465-1 2006 Reaction of Ti(NMe2)4 with allyl alcohols and primary amines leads to the selective formation of secondary allylic amines. Amines 115-121 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 15-19 15387610-6 2004 The origin of the limitation of oligomer chain length is probably due to a specific effect of the internal benzylic amine group, since the substrate 4-Me2NCH2C6H4C(O)NMe2 was found to be uniquely unreactive compared to the other 4-substituted N,N-dialkylbenzamides investigated. Amines 116-121 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 166-170 25790240-1 2015 The aluminium amide Al(NMe2)3 acts as a stoichiometric or catalytic reagent in dehydrogenic Si-N bond formation using amines and silanes. Amines 118-124 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 23-27 16608354-1 2006 The carbon-nitrogen bond of secondary carboxamides is generally thermodynamically and kinetically unreactive; however, we recently discovered that the trisamidoaluminum(III) dimer Al2(NMe2)6 catalyzes facile transamidation between simple secondary carboxamides and primary amines under moderate conditions. Amines 273-279 NME/NM23 nucleoside diphosphate kinase 2 Homo sapiens 184-188