PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 9309219-12 1997 Side-by-side Im and Py rings differentiate GC from CG base pairs because of tight steric contacts and sp2 hybridization at the amine nitrogen atom, with the favored conformations being G/Im,Py/C and C/Py,Im/G. Amines 127-132 Sp2 transcription factor Homo sapiens 102-105 30132331-0 2018 Visible-Light-Promoted C(sp3)-C(sp2) Cross-Dehydrogenative Coupling of Tertiary Amine with Imidazopyridine. Amines 80-85 Sp2 transcription factor Homo sapiens 30-35 33464894-2 2021 Interestingly, with the change of a reaction condition, different pathways were conducted (visible-light-induced N-dealkylation or sp3 and sp2 C-H activation) that lead to different products such as secondary amines and various sulfonyl compounds. Amines 209-215 Sp2 transcription factor Homo sapiens 139-142 32961733-4 2020 From the four discriminant functions, it can be extracted that the presence of sp3 carbons, ramifications, and secondary amine groups in a molecule enhance antibacterial activity, whereas the presence of 5-member rings, sp2 carbons, and sp2 oxygens hinder it. Amines 121-126 Sp2 transcription factor Homo sapiens 237-240 32276227-3 2020 When H2S is present, the azide group in SP2 was reduced to amine group, resulting in a turn-on fluorescence signal. Amines 59-64 Sp2 transcription factor Homo sapiens 40-43 31166642-1 2019 The Pd-catalyzed coupling of aryl (pseudo)halides and amines is one of the most powerful approaches for the formation of C(sp2 )-N bonds. Amines 54-60 Sp2 transcription factor Homo sapiens 121-126 34436813-5 2022 In this review, the aromatic sp2 -C attached free amine, hydroxyl and sulfhydryl as native functionalities are shown to be useful for the construction of five to seven-membered N-, O- and S-heterocycles. Amines 50-55 Sp2 transcription factor Homo sapiens 29-32 31799581-0 2020 Metal-free late-stage C(sp2)-H functionalization of N-aryl amines with various sodium salts. Amines 52-65 Sp2 transcription factor Homo sapiens 22-27 31799581-1 2020 Metal-free consecutive C(sp2)-X (X = Cl, Br, S, N) bond formations of N-aryl amines (cyclic, fused, carbamate, and aminium radicals) were achieved under mild conditions using [bis(trifluoroacetoxy)iodo]benzene (PIFA) and simple nonharmful sodium salts. Amines 70-83 Sp2 transcription factor Homo sapiens 23-28 31556300-0 2019 Ligand-Enabled Gold-Catalyzed C(sp2)-N Cross-Coupling Reactions of Aryl Iodides with Amines. Amines 85-91 Sp2 transcription factor Homo sapiens 30-35 30884054-4 2019 Interestingly, Por-sp2 c-COF can be used as a metal-free heterogeneous photocatalyst for the visible-light-induced aerobic oxidation of amines to imines. Amines 136-142 Sp2 transcription factor Homo sapiens 19-22 30852888-3 2019 Herein, we report a chelate-directed iridium-catalyzed asymmetric C(sp2)-H borylation of aromatic C-H bonds directed by free amine groups. Amines 125-130 Sp2 transcription factor Homo sapiens 66-71 30299971-0 2018 Palladium(II)-Catalyzed C(sp2)-H Carbonylation of Sterically Hindered Amines with Carbon Monoxide. Amines 70-76 Sp2 transcription factor Homo sapiens 24-29 30299971-1 2018 A palladium-catalyzed, amine-directed C(sp2)-H carbonylation of alpha,alpha-disubstituted benzylamine under 1 atm of CO for the facile synthesis of sterically hindered benzolactam has been developed. Amines 23-28 Sp2 transcription factor Homo sapiens 38-43 29205041-1 2017 A phenyliodine(III) diacetate mediated umpolung reactivity of the tertiary amines with suitably substituted o-hydroxybenzyl and phenyl groups is exploited to facilitate o-C(sp2)-H functionalization to afford diaryl ethers. Amines 75-81 Sp2 transcription factor Homo sapiens 171-176 28612071-0 2017 Palladium-catalyzed intermolecular carbonylative cross-coupling of heteroaryl C(sp2)-H bonds with amines: an efficient strategy for oxidative aminocarbonylation of azoles. Amines 98-104 Sp2 transcription factor Homo sapiens 78-83 28612071-2 2017 This system allows for intermolecular carbonylative cross-coupling of aromatic C(sp2)-H bonds with simple amines, which has often been asked for, but has not been realized so far. Amines 106-112 Sp2 transcription factor Homo sapiens 79-84 22937807-0 2012 Palladium-catalyzed C(sp2)-H cyanation using tertiary amine derived isocyanide as a cyano source. Amines 54-59 Sp2 transcription factor Homo sapiens 20-25 27748119-2 2016 The addition of in situ generated imines to C(sp2)-H bonds afforded branched amines in good to excellent yields. Amines 77-83 Sp2 transcription factor Homo sapiens 44-49 20446705-0 2010 FeCl3-catalyzed oxidative allylation of sp2 and sp3 C-H bond adjacent to a nitrogen atom: easy access to homoallyl tertiary amines. Amines 124-130 Sp2 transcription factor Homo sapiens 40-43