PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 32567316-1 2020 A highly efficient, cheap, and organic alternative to the commonly used iridium photosensitizer (Ir[dF(CF3)ppy]2(dtbpy))PF6 ([Ir-F]) is presented for visible-light energy transfer catalysis. Iridium 72-79 sperm associated antigen 17 Homo sapiens 120-123 35446576-3 2022 (Ir(ppy)2(CH3CN)2)PF6 (ppy = 2-phenylpyridine), containing two labile CH3CN groups, and NiCl2 are used as iridium and nickel-metal precursors, respectively, for postsynthetic decoration of the TpBpy COF. Iridium 106-113 sperm associated antigen 17 Homo sapiens 18-21 31159944-1 2019 A new cyclometalated iridium complex, [(bt)2Ir(bpy-Fc)]PF6 (bt = 2-phenylbenzothiazole, bpy-Fc = 4-ferrocenecarbonyl hydrazinocarbonyl-4"-methyl- 2,2"-bipyridine) (probe 1) was designed and synthesized for rapid photoluminescent (PL) and electrochemiluminescent (ECL) sensing of hypochlorite (ClO-). Iridium 21-28 sperm associated antigen 17 Homo sapiens 55-58 31916440-2 2020 In this work, we rationally designed and synthesized two red-emitting cationic Ir(III) complexes, [Ir(tBuPBI)2(biq)]PF6 (R1) and [Ir(tBuPBI)2(qibi)]PF6 (R2), in which a tert-butyl-functionalized 1,2-diphenyl-1H-benzo[d]imidazole (PBI) unit and conjugated 2,2"-biquinoline (biq) and 2-(1-phenyl-1H-benzo[d]imidazol-2-yl)quinolone (qibi) were employed as cyclometalated and ancillary ligands, respectively. Iridium 79-86 sperm associated antigen 17 Homo sapiens 116-119 31916440-2 2020 In this work, we rationally designed and synthesized two red-emitting cationic Ir(III) complexes, [Ir(tBuPBI)2(biq)]PF6 (R1) and [Ir(tBuPBI)2(qibi)]PF6 (R2), in which a tert-butyl-functionalized 1,2-diphenyl-1H-benzo[d]imidazole (PBI) unit and conjugated 2,2"-biquinoline (biq) and 2-(1-phenyl-1H-benzo[d]imidazol-2-yl)quinolone (qibi) were employed as cyclometalated and ancillary ligands, respectively. Iridium 79-86 sperm associated antigen 17 Homo sapiens 148-151 31702842-3 2020 In this study, generation of siloxycarbenes from alkanoylsilanes by visible-light-induced energy transfer was examined by using an Ir complex, [Ir{dF(CF 3 )ppy} 2 (dtbpy)]PF 6 , and was successfully applied to the C-C coupling reactions with boronic esters or aldehydes. Iridium 131-133 sperm associated antigen 17 Homo sapiens 171-175 31702842-3 2020 In this study, generation of siloxycarbenes from alkanoylsilanes by visible-light-induced energy transfer was examined by using an Ir complex, [Ir{dF(CF 3 )ppy} 2 (dtbpy)]PF 6 , and was successfully applied to the C-C coupling reactions with boronic esters or aldehydes. Iridium 144-146 sperm associated antigen 17 Homo sapiens 171-175 31891094-1 2019 Removal of chloride from Cp*Ir(glycinato)Cl in noncoordinating solvents with Ag[PF6] or Tl[PF6] leads to the formation of a closed octametallic loop of cations. Iridium 25-43 sperm associated antigen 17 Homo sapiens 80-83 31891094-1 2019 Removal of chloride from Cp*Ir(glycinato)Cl in noncoordinating solvents with Ag[PF6] or Tl[PF6] leads to the formation of a closed octametallic loop of cations. Iridium 25-43 sperm associated antigen 17 Homo sapiens 91-94 31687825-1 2019 The anti-Markovnikov hydrosulfonylation of unactivated alkenes with sodium sulfinates was realized via [Ir(dF(CF3)ppy)2(dtbbpy)]PF6-mediated visible light photoredox catalysis. Iridium 104-119 sperm associated antigen 17 Homo sapiens 128-131 31565717-1 2019 Visible light-driven cross-coupling reactions of alkyl halides with phenylacetylene and its derivatives catalyzed by the cobalamin derivative (B12) with the [Ir(dtbbpy)(ppy)2]PF6 photocatalyst at room temperature are reported. Iridium 158-160 sperm associated antigen 17 Homo sapiens 175-178 31559981-1 2019 Complex [Ir(dfppy)2(phca)]PF6 (1) has been synthesized, which contains an aldehyde group in the N^N ligand phca = 1,10-phenanthroline-4-carbaldehyde, with the aim of exploring solvent-driven luminescence modulation/switching in this complex. Iridium 9-11 sperm associated antigen 17 Homo sapiens 26-29 32222581-1 2020 N-heterocyclic carbenes-modified half-sandwich iridium(III) complex [(eta5-C5Me4C6H4C6H5)Ir(C^C)Cl]PF6 (C1) (where C^C is a N-heterocyclic carbene ligand) can effectively prevent the proliferation of human cervical cancer cells. Iridium 47-54 sperm associated antigen 17 Homo sapiens 99-102 32044395-1 2020 Three iridium(III) complexes [Ir(ppy)2(CPIP)](PF6) (Ir-1, ppy = 2-phenylpyridine, CPIP = 2-(4-chlorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline), [Ir(ppy)2(DCPIP)](PF6) (Ir-2, DCPIP = 2-(3,4-dichlorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline) and [Ir(ppy)2(TCPIP)](PF6) (Ir-3, TCPIP = 2,3,5-trichlorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline) were synthesized and characterized. Iridium 6-18 sperm associated antigen 17 Homo sapiens 46-49 31697000-1 2020 The iridium half-sandwich complex [Ir(eta5 :kappa1 -C5 Me4 CH2 py)(2-phenylpyridine)]PF6 is highly cytotoxic: 15-250x more potent than clinically used cisplatin in several cancer cell lines. Iridium 4-11 sperm associated antigen 17 Homo sapiens 85-88 31825583-1 2020 A series of charge-neutral bis-tridentate Ir(III) complexes (1, 3 and 4) were prepared via employing three distinctive tridentate pro-chelates, i.e., (pzptBphFO)H2, [(phpyim)H2 (PF6)] and [(pimb)H3 (PF6)2], which possess one dianionic, tridentate pzptBphFO, together with a second monoanionic chelate, namely: (pzptBphFO)H, phpyim, and pimb, while complex 2 with monoanionic chelate (pzptBphFO)Me was obtained by methylation of (pzptBphFO)H of 1 in basic media. Iridium 27-49 sperm associated antigen 17 Homo sapiens 178-181 31825583-1 2020 A series of charge-neutral bis-tridentate Ir(III) complexes (1, 3 and 4) were prepared via employing three distinctive tridentate pro-chelates, i.e., (pzptBphFO)H2, [(phpyim)H2 (PF6)] and [(pimb)H3 (PF6)2], which possess one dianionic, tridentate pzptBphFO, together with a second monoanionic chelate, namely: (pzptBphFO)H, phpyim, and pimb, while complex 2 with monoanionic chelate (pzptBphFO)Me was obtained by methylation of (pzptBphFO)H of 1 in basic media. Iridium 27-49 sperm associated antigen 17 Homo sapiens 199-202 31789019-2 2020 Here, synergistic effect of electrochemiluminescence (ECL) is observed unprecedentedly in a new cyclometalated dinuclear Ir(III) complex [Ir2(dfppy)4(imiphenH)]PF6 (1 PF6, PF6- = hexafluorophosphate) in which two {Ir(dfppy)2}+ units are bridged by an imiphenH- ligand. Iridium 121-128 sperm associated antigen 17 Homo sapiens 160-163 31789019-2 2020 Here, synergistic effect of electrochemiluminescence (ECL) is observed unprecedentedly in a new cyclometalated dinuclear Ir(III) complex [Ir2(dfppy)4(imiphenH)]PF6 (1 PF6, PF6- = hexafluorophosphate) in which two {Ir(dfppy)2}+ units are bridged by an imiphenH- ligand. Iridium 121-128 sperm associated antigen 17 Homo sapiens 167-170 31789019-2 2020 Here, synergistic effect of electrochemiluminescence (ECL) is observed unprecedentedly in a new cyclometalated dinuclear Ir(III) complex [Ir2(dfppy)4(imiphenH)]PF6 (1 PF6, PF6- = hexafluorophosphate) in which two {Ir(dfppy)2}+ units are bridged by an imiphenH- ligand. Iridium 121-128 sperm associated antigen 17 Homo sapiens 167-170 31789019-2 2020 Here, synergistic effect of electrochemiluminescence (ECL) is observed unprecedentedly in a new cyclometalated dinuclear Ir(III) complex [Ir2(dfppy)4(imiphenH)]PF6 (1 PF6, PF6- = hexafluorophosphate) in which two {Ir(dfppy)2}+ units are bridged by an imiphenH- ligand. Iridium 121-123 sperm associated antigen 17 Homo sapiens 160-163 31789019-2 2020 Here, synergistic effect of electrochemiluminescence (ECL) is observed unprecedentedly in a new cyclometalated dinuclear Ir(III) complex [Ir2(dfppy)4(imiphenH)]PF6 (1 PF6, PF6- = hexafluorophosphate) in which two {Ir(dfppy)2}+ units are bridged by an imiphenH- ligand. Iridium 121-123 sperm associated antigen 17 Homo sapiens 167-170 31789019-2 2020 Here, synergistic effect of electrochemiluminescence (ECL) is observed unprecedentedly in a new cyclometalated dinuclear Ir(III) complex [Ir2(dfppy)4(imiphenH)]PF6 (1 PF6, PF6- = hexafluorophosphate) in which two {Ir(dfppy)2}+ units are bridged by an imiphenH- ligand. Iridium 121-123 sperm associated antigen 17 Homo sapiens 167-170 31789019-4 2020 Theoretical calculation reveals that the S0 to S1 excitation is a local excitation in 1 PF6 with two electron-coupled Ir(III) centers, which contributes to the enhanced ECL. Iridium 118-125 sperm associated antigen 17 Homo sapiens 88-91 27678199-3 2016 The iridium(III) complex 1 [Ir(tpyd)2(2,9-dmphen)]PF6 (where tpyd =2-(m-tolyl)pyridine; 2,9-dmphen =2,9-dimethyl-1,10-phenanthroline) was synthesized, and it displayed high luminescence for G-quadruplex DNA compared to dsDNA and ssDNA. Iridium 4-11 sperm associated antigen 17 Homo sapiens 50-53 30801087-2 2019 This was achieved by using an optimized artificial photosynthesis (AP) system with a cyclometalated iridium complex [Ir(ppy)2(bpy)](PF6) ([Ir-PS-1]) and triethylamine (TEA) serving as a photosensitizer (PS) and a sacrificial donor, respectively. Iridium 100-107 sperm associated antigen 17 Homo sapiens 132-135 30358775-1 2018 Five mononuclear cyclometalated iridium complexes [1](PF6)-[5](PF6) were prepared using imidazole-based ligands of varying alkyl chain length. Iridium 32-39 sperm associated antigen 17 Homo sapiens 54-57 30358775-1 2018 Five mononuclear cyclometalated iridium complexes [1](PF6)-[5](PF6) were prepared using imidazole-based ligands of varying alkyl chain length. Iridium 32-39 sperm associated antigen 17 Homo sapiens 63-66 30104875-3 2018 In this study, we aimed at incorporating Ir ([Ir(ppy)2(BTCP)]PF6) into liposomes to enhance the biocompatibility and sustained release of Ir for intravenous administration and to elucidate the mechanism in A549 cells. Iridium 41-43 sperm associated antigen 17 Homo sapiens 61-64 29656200-1 2018 Three new iridium (III) complexes [Ir (ppy)2 (ipbc)](PF6) (1), [Ir (bzq)2 (ipbc)](PF6) (2) and [Ir (piq)2 (ipbc)](PF6) (3) were designed and synthesized. Iridium 10-17 sperm associated antigen 17 Homo sapiens 53-56 29656200-1 2018 Three new iridium (III) complexes [Ir (ppy)2 (ipbc)](PF6) (1), [Ir (bzq)2 (ipbc)](PF6) (2) and [Ir (piq)2 (ipbc)](PF6) (3) were designed and synthesized. Iridium 19-23 sperm associated antigen 17 Homo sapiens 53-56 31180358-4 2019 Altogether, [(DPEPhos)(bcp)Cu]PF6 acts as a convenient photoredox catalyst which appears to be an attractive, cheap and complementary alternative to the state-of-the-art iridium- and ruthenium-based photoredox catalysts. Iridium 170-177 sperm associated antigen 17 Homo sapiens 30-33 31950763-1 2019 A visible light responsive catalytic system with the B12 complex as the catalyst and [Ir(dtbbpy)(ppy)2 ]PF6 as the photosensitizer was developed. Iridium 86-102 sperm associated antigen 17 Homo sapiens 104-107 30467910-5 2019 The long-lived emission of [Ir(ppy)2 (NTY-bpy)](PF6 ) allows time-gated luminescence analysis of Cys in cells and human sera. Iridium 27-30 sperm associated antigen 17 Homo sapiens 48-51 30591827-1 2018 The degenerative transfer of xanthates to olefins is enabled by the iridium-based photocatalyst [Ir{dF(CF3)ppy}2(dtbbpy)](PF6) under blue LED light irradiation. Iridium 68-75 sperm associated antigen 17 Homo sapiens 122-125 30301346-1 2018 Multifarious sugar lactols were efficiently transformed into the corresponding phenolic glycosides by treating with aryl bromides in acetonitrile with Ir[dF(CF3)ppy]2(dtbbpy)(PF6) as a photocatalyst under visible light irradiation. Iridium 151-153 sperm associated antigen 17 Homo sapiens 175-178 31957353-7 2018 It was noted that the emission mechanism was based on Forster resonance energy transfer and Dexter energy transfer from excited PFBT to [Ir(ppy)2 (biq)]+ (PF6 )- . Iridium 137-145 sperm associated antigen 17 Homo sapiens 155-158 27960443-3 2016 Herein, we report the preparation, the crystal structures, and the optoelectronic properties of two families of cyclometalated iridium(III) complexes of the form of [(C^N)2Ir(dtBubpy)]PF6 (where dtBubpy is 4,4"-di-tert-butyl-2,2"-bipyridine) in both their racemic and enantiopure configurations. Iridium 127-134 sperm associated antigen 17 Homo sapiens 184-187 27901529-1 2016 An electron-transporting counter-anion, OXD-7-SO3-, was developed for a blue-green-emitting cationic iridium complex, which showed superior device performance in solution-processed phosphorescent light-emitting diodes over its counterpart complex with a PF6- counter-anion, due to the facilitated electron-injection/transport and more balanced carrier recombination imparted by OXD-7-SO3-. Iridium 101-108 sperm associated antigen 17 Homo sapiens 254-257 26037410-1 2015 We report on four cationic iridium(III) complexes [Ir(C^N)2(dtBubpy)](PF6) that have sulfur pentafluoride-modified 1-phenylpyrazole and 2-phenylpyridine cyclometalating (C^N) ligands (dtBubpy = 4,4"-di-tert-butyl-2,2"-bipyridyl). Iridium 27-34 sperm associated antigen 17 Homo sapiens 70-73 27193490-4 2016 In addition, the ruthenium(ii) and iridium(iii) complexes [RuCl(MeIm-(o-phenylene)-MeIm)(p-cym)](PF6) and [IrClCp*(MeIm-(o-phenylene)-MeIm)](PF6) were prepared and shown to present in these cases a chelating coordination of the di(N-heterocyclic carbene) ligand. Iridium 35-42 sperm associated antigen 17 Homo sapiens 97-100 26095956-3 2015 The coordination of an extra molecule of acetonitrile to the iridium center initiates the reversible isomerization of the chelating carbon chain of A to the monodentate butadienyl ligand of complex [Tp(Me2)Ir(CH=C(Me)C(Me)=CH2)(NCMe)2]PF6, which is capable to engage in a water-promoted C-C coupling with the MeCN co-ligands. Iridium 61-68 sperm associated antigen 17 Homo sapiens 235-238 26087119-1 2015 In this Article, we present a series of cyclometalated iridium(III) polypyridine complexes of the formula [Ir(N^C)2(N^N)](PF6) that showed dual emission under ambient conditions. Iridium 107-109 sperm associated antigen 17 Homo sapiens 122-125 24828854-1 2014 A novel and easily accessible luminescent iridium(iii) complex [Ir(tpy)2(N^N)]PF6 (, tpy = 2-(p-tolyl)pyridine, N^N = 4-[(4-amino-3-nitrophenoxy)-methylene]-4"-methyl-2,2"-bipyridine) for the sensing of HOCl has been designed and synthesized. Iridium 42-49 sperm associated antigen 17 Homo sapiens 78-81 25501466-1 2015 Ten cationic heteroleptic iridium(III) complexes, [Ir(emptz)2(N^N)](PF6) were prepared from a cyclometalated iridium bridged-chloride dimer involving two ethyl-4-methylphenylthiazole-5-carboxylate (emptz) ligands. Iridium 26-33 sperm associated antigen 17 Homo sapiens 68-71 25501466-1 2015 Ten cationic heteroleptic iridium(III) complexes, [Ir(emptz)2(N^N)](PF6) were prepared from a cyclometalated iridium bridged-chloride dimer involving two ethyl-4-methylphenylthiazole-5-carboxylate (emptz) ligands. Iridium 109-116 sperm associated antigen 17 Homo sapiens 68-71 24828756-1 2014 The cellular mechanism of action of an iridium(III) half-sandwich complex [(eta(5)-C5Me4C6H4C6H5)Ir(phen)Cl]PF6 (phen = phenanthroline) (1) is reported. Iridium 39-46 sperm associated antigen 17 Homo sapiens 108-111 23865471-2 2013 Upon the complexation of a first equivalent of iridium, the photoluminescence shifts markedly into the deep red (lambdaem = 710 nm, PhiPL = 0.9%) compared to other cationic iridium complexes such as [Ir(ppy)2(bpy)]PF6. Iridium 47-54 sperm associated antigen 17 Homo sapiens 214-217 23685636-1 2013 A novel luminescent biscyclometalated iridium(III) complex [Ir(C^N)2bpy]PF6 (Ir-S, bpy = 2,2"-bipyridine) containing two 2-phenylpyridine (ppy) cyclometalating ligands (C^N) functionalized with 1,3-dithiane for the detection of Hg(2+) ions has been synthesized and characterized by spectroscopic and photophysical measurements. Iridium 38-45 sperm associated antigen 17 Homo sapiens 72-75 23843363-4 2013 Herein, a series of homoleptic tris-cyclometalated iridium complexes, based on different 2-phenylpyridine ligands, were utilized as PSs in photocatalytic systems for hydrogen production with [Rh(dtb-bpy)3 ](PF6 )3 (dtb-bpy=4,4"-di-tert-butyl-2,2"-dipyridyl) serving as the water reduction catalyst (WRC) and triethanolamine (TEOA) as the electron donor. Iridium 51-58 sperm associated antigen 17 Homo sapiens 207-210 23843363-6 2013 The excited state of neutral iridium complexes (PS*) could not be quenched by using TEOA as an electron donor, but they could be quenched by using [Rh(dtb-bpy)3 ](PF6 )3 as an electron acceptor, indicating that the PS* quenching pathway in catalytic reactions was most likely an oxidative quenching process. Iridium 29-36 sperm associated antigen 17 Homo sapiens 163-166 23843363-9 2013 Comparative studies indicated that the photocatalytic performance of these homoleptic tris-cyclometalated iridium compounds was superior to that of the cationic iridium complex [Ir(ppy)2 (bpy)](PF6 ) (ppy=2-phenylpyridine, bpy=2,2"-dipyridyl) (4), which was used as a reference. Iridium 106-113 sperm associated antigen 17 Homo sapiens 194-197 23843363-9 2013 Comparative studies indicated that the photocatalytic performance of these homoleptic tris-cyclometalated iridium compounds was superior to that of the cationic iridium complex [Ir(ppy)2 (bpy)](PF6 ) (ppy=2-phenylpyridine, bpy=2,2"-dipyridyl) (4), which was used as a reference. Iridium 161-168 sperm associated antigen 17 Homo sapiens 194-197 23148033-1 2012 We report the cellular properties of a luminescent cyclometalated iridium(III) complex, [Ir(pq)(2)(phen-ITC)](PF(6)) (Ir-ITC; Hpq=2-phenylquinoline, phen-ITC=5-isothiocyanate-1,10-phenanthroline), that efficiently and specifically labels mitochondria in living mammalian cells. Iridium 66-73 sperm associated antigen 17 Homo sapiens 110-116 17083222-1 2006 A highly luminescent novel cationic iridium complex [iridium bis(2-phenylpyridine)(4,4"-(dimethylamino)-2,2"-bipyridine)]PF6 was synthesized and characterized using NMR, UV-visible absorption, and emission spectroscopy and electrochemical methods. Iridium 36-43 sperm associated antigen 17 Homo sapiens 121-124 22334566-1 2012 Novel phenylazole ligands were applied successfully in the synthesis of cyclometalated iridium(III) complexes of the general formula [Ir(phenylazole)(2)(bpy)]PF(6) (bpy=2,2"-bipyridine). Iridium 87-94 sperm associated antigen 17 Homo sapiens 158-163 22334566-1 2012 Novel phenylazole ligands were applied successfully in the synthesis of cyclometalated iridium(III) complexes of the general formula [Ir(phenylazole)(2)(bpy)]PF(6) (bpy=2,2"-bipyridine). Iridium 134-137 sperm associated antigen 17 Homo sapiens 158-163