PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 17441112-1 2006 In the 1,4-addition of phenylboronic acid to alpha,beta-unsaturated ketones, [Rh(OH)(cod)]2 has a much higher catalytic activity than [Rh(OH)(binap)]2 (cod = 1,5-cyclooctadiene, binap = 2,2"-bis(diphenylphosphanyl)-1,1"-binaphthyl). BINAP, 2-naphthol 142-147 COD2 Homo sapiens 85-91 16146408-2 2005 A rhodium complex of [RhOH(COD)]2 and optically pure BINAP is the optimal catalyst that provides good yields and high enantioselectivities ranging from 90 to 99% ee for various arylboronic acids at 50 degrees C. A concise total synthesis of optically pure (+)-gamma-lycorane in overall 38% yield was achieved on the basis of this new method. BINAP, 2-naphthol 53-58 COD2 Homo sapiens 22-33