PMID-sentid Pub_year Sent_text comp_official_name comp_offsetprotein_name organism prot_offset 32585094-3 2020 We report herein that complex fac-[MnI(bis-MesNHC)(CO)3Br] [1; bis-MesNHC = 3,3-bis(2,4,6-trimethylphenyl)-(1,1"-diimidazolin-2,2"-diylidene)methane] could catalyze the electrochemical reduction of CO2 to CO with high activity (TOFmax = 3180 +- 6 s-1) at a less negative potential. Carbon Monoxide 51-53 FA complementation group C Homo sapiens 30-33 29481726-1 2018 We report here the first purely organometallic fac-[MnI (CO)3 (bis-Me NHC)Br] complex with unprecedented activity for the selective electrocatalytic reduction of CO2 to CO, exceeding 100 turnovers with excellent faradaic yields (etaCO 95 %) in anhydrous CH3 CN. Carbon Monoxide 57-59 FA complementation group C Homo sapiens 47-50 29740881-0 2018 Electrospray ionization study of tricarbonyl fac-[Re(CO)3 (PO)(X)]-type complexes: influence of ancillary co-ligands in the release of carbon monoxide. Carbon Monoxide 135-150 FA complementation group C Homo sapiens 45-48 29740881-1 2018 RATIONALE: fac-[Re(CO)3 (PO)(X)]-type complexes (PO = chelated bidentate tertiary phosphine (1-), X = various neutral, mono-dentate ligands) represent a class of compounds that meets the synthetic criteria for the preparation of potential carbon monoxide (CO) release molecules (CORMs) for medicinal application. Carbon Monoxide 239-254 FA complementation group C Homo sapiens 11-14 29740881-1 2018 RATIONALE: fac-[Re(CO)3 (PO)(X)]-type complexes (PO = chelated bidentate tertiary phosphine (1-), X = various neutral, mono-dentate ligands) represent a class of compounds that meets the synthetic criteria for the preparation of potential carbon monoxide (CO) release molecules (CORMs) for medicinal application. Carbon Monoxide 19-21 FA complementation group C Homo sapiens 11-14 16472004-2 2006 Solution-phase continuous and laser flash photolysis of the tetraphenylarsonium salt of the fac-[CH3Ir(CO)2I3]- anion (1a) under excess carbon monoxide resulted in migratory insertion to give the acyl complex ion mer,trans-[Ir(C(O)CH3)(CO)2I3]- (2a). Carbon Monoxide 136-151 FA complementation group C Homo sapiens 92-95 27722517-1 2016 fac-[Re(CO)3(dppz)] complexes of amido ligands generated in situ under basic conditions display an intense (epsilon = 16460 L mol-1 cm-1) absorption band between 500-700 nm which are assigned to an n(amido,RNH-) pi* (dppz) inter-ligand charge transfer band offering an extraordinarily low energy charge separating absorption with potential for imaging and energy application. Carbon Monoxide 8-10 FA complementation group C Homo sapiens 0-3 24053131-1 2013 A complete mechanism for the proton-dependent electrocatalytic reduction of CO2 to CO by fac-Re(bpy)(CO)3Cl that is consistent with experimental observations has been developed using first principles quantum chemistry. Carbon Monoxide 76-78 FA complementation group C Homo sapiens 89-92 27110904-1 2016 Electrocatalytic CO2 reduction to CO was achieved with a novel Mn complex, fac-[MnBr(4,4"-bis(phosphonic acid)-2,2"-bipyridine)(CO)3 ] (MnP), immobilized on a mesoporous TiO2 electrode. Carbon Monoxide 17-19 FA complementation group C Homo sapiens 75-78 26068141-5 2015 We report here NMR, molecular (X-ray) structure, and solution data on fac-[Re(I)(CO)3(NTA)](2-) with a -CH2CO2(-) dangling monoanionic chain and on two fac-[Re(I)(CO)3(L)](-) analogues with either a -CH2CONH2 or a -CH2CH2OH dangling neutral chain. Carbon Monoxide 81-83 FA complementation group C Homo sapiens 70-73 15702193-0 2005 The chemistry of the fac-[Re(CO)2(NO)]2+ fragment in aqueous solution. Carbon Monoxide 29-32 FA complementation group C Homo sapiens 21-24