Title : EPR spectroscopic evidence for the mechanism-based inactivation of adenosylcobalamin-dependent diol dehydratase by coenzyme analogs.

Pub. Date : 1998 Sep

PMID : 9722671






1 Functional Relationships(s)
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1 Upon suicide inactivation with a [15N2]imidazolyl analog, the octet signals due to Co(II) showed superhyperfine splitting into doublets, indicating axial coordination of 5,6-dimethylbenzimidazole to the cobalamin bound to diol dehydratase. imidazolyl mitochondrially encoded cytochrome c oxidase II Homo sapiens