Title : Preparation of 3beta, 16beta-dihydroxyandrost-5-en-17-one: stabilization of its alpha-ketolic group toward alkali by formation of a semicarbazone.

Pub. Date : 1976 Jun

PMID : 941194






1 Functional Relationships(s)
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1 Hydrolysis can be achieved without rearrangement by 1) formation of a C-17 semicarbazone, 2) alkaline removal of the acetate group, and 3) removal of the semicarbazone group in the presence of pyruvic acid-acetic acid. Semicarbazones cytokine like 1 Homo sapiens