Title : Nucleophilic addition reactions of free and enzyme-bound deazaflavin.

Pub. Date : 1976 Aug 25

PMID : 8450






3 Functional Relationships(s)
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1 The reaction of sulfite, cyanide, and hydroxylamine with several deazaflavin-containing enzymes (glycolate oxidase, D-amino acid oxidase, glucose oxidase, N-methylglutamate synthetase) and free deazaFMN has been examined. Sulfites D-amino acid oxidase Homo sapiens
2 The relative stability observed for the sulfite and cyanide complexes formed with various deazaflavin systems (glycolate oxidase greater than D-amino acid oxidase greater than free deazaFMN) follows the same trend observed for the stability of the sulfite complexes formed with the corresponding flavin system. Sulfites D-amino acid oxidase Homo sapiens
3 The relative stability observed for the sulfite and cyanide complexes formed with various deazaflavin systems (glycolate oxidase greater than D-amino acid oxidase greater than free deazaFMN) follows the same trend observed for the stability of the sulfite complexes formed with the corresponding flavin system. Sulfites D-amino acid oxidase Homo sapiens