Title : Stereochemistry of an alpha, beta-elimination reaction by D-glucosaminate dehydratase.

Pub. Date : 1983 May 30

PMID : 6852253






3 Functional Relationships(s)
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1 The proton NMR analysis of D-glucosaminate dehydratase reaction in D2O revealed the incorporation of a deuterium atom at C-3 carbon of the product, 2-keto-3-deoxy-D-gluconate. Deuterium complement C3 Homo sapiens
2 Based on the chemical shift of C-3 proton of the product and the coupling constant characteristic for the C-3 and C-4 axial-axial coupling in the 2C5 pyranose conformation, the deuterium is in the pro-S position. Deuterium complement C3 Homo sapiens
3 Based on the chemical shift of C-3 proton of the product and the coupling constant characteristic for the C-3 and C-4 axial-axial coupling in the 2C5 pyranose conformation, the deuterium is in the pro-S position. Deuterium complement C3 Homo sapiens