Title : Spectral analysis of the configuration and solution conformation of dihydrodigoxigenin epimers.

Pub. Date : 1983 Mar

PMID : 6302244






1 Functional Relationships(s)
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1 This finding, together with X-ray crystallographic data from a separate study on the minor epimer, establishes the C20 configuration of the minor epimer as S and of the major epimer as R. NMR evidence indicates that the average lactone rotamer for the minor epimer has the C22 position located on the C12 side of the steroid nucleus, whereas the average lactone rotamer for the major epimer has the C21 position located on the C12 side of the steroid nucleus. Lactones TBL1X/Y related 1 Homo sapiens