Title : Selectivity, Speciation, and Substrate Control in the Gold-Catalyzed Coupling of Indoles and Alkynes.

Pub. Date : 2022 Feb 28

PMID : 35431397






2 Functional Relationships(s)
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1 A combined experimental and computational mechanistic study has revealed that the gold catalyst has a greater affinity to the indole than the alkyne, despite the carbon-carbon bond formation step proceeding through an eta2(pi)-alkyne complex, which helps to explain the stark differences between the intra- and intermolecular variants of the reaction. Carbon DNA polymerase iota Homo sapiens
2 A combined experimental and computational mechanistic study has revealed that the gold catalyst has a greater affinity to the indole than the alkyne, despite the carbon-carbon bond formation step proceeding through an eta2(pi)-alkyne complex, which helps to explain the stark differences between the intra- and intermolecular variants of the reaction. Carbon DNA polymerase iota Homo sapiens