Title : Lanthanide induced variability in localised CoII geometries of four triangular L3Co3 IILnIII complexes.

Pub. Date : 2022 Feb 3

PMID : 35425468






2 Functional Relationships(s)
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1 Lanthanide induced variability in localised CoII geometries of four triangular L3Co3 IILnIII complexes. Lanthanoid Series Elements mitochondrially encoded cytochrome c oxidase II Homo sapiens
2 The third CoII ion assumes a different coordination geometry in each complex: six-coordinate octahedral in C1, six-coordinate with a distortion towards trigonal prismatic in C2, five-coordinate trigonal bipyramidal in C3, and five-coordinate square pyramidal in C4; which has been attributed to increasing lanthanide cation size, coupled with a non-macrocyclic coordination environment. Lanthanoid Series Elements mitochondrially encoded cytochrome c oxidase II Homo sapiens