Title : Synthesis and Characterization of Solvated Lanthanide Tris(trimethylsilyl)siloxides.

Pub. Date : 2022 Mar 28

PMID : 35286077






2 Functional Relationships(s)
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1 In general, these compounds are similar to the previously reported (Gd(SST)3(THF)2) complex, where each metal center of the monomeric species is found to adopt a trigonal bipyramidal (TBP; tau = av 0.95) geometry; however, the crystallographic structure solutions for these crystals invoke a much larger unit cell that reveals the complex disorder of the axial THF ligands. Metals microtubule associated protein tau Homo sapiens
2 The Ln-py structures exhibit the larger unit cell noted for the THF derivatives with each Ln adopting a TBP (tau = av 0.98) metal center possessing equatorial SST and axial py ligands. Metals microtubule associated protein tau Homo sapiens