Title : The Magnetic Behaviour of CoTPP Supported on Coinage Metal Surfaces in the Presence of Small Molecules: A Molecular Cluster Study of the Surface trans-Effect.

Pub. Date : 2022 Jan 10

PMID : 35055236






1 Functional Relationships(s)
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1 The CO and NH3 bonding to CoTPP does not influence the Co local electronic structure, while the NO (NO2 and O2) coordination induces a Co reduction (oxidation), generating a 3d8 CoI (3d6 CoIII) magnetically silent closed-shell species. Nitrogen Dioxide mitochondrially encoded cytochrome c oxidase III Homo sapiens