Title : Carbon-hydrogen bond activation in bridging cyclobutadiene ligands in unsaturated binuclear vanadium carbonyl derivatives.

Pub. Date : 2022 Jan 20

PMID : 35050433






1 Functional Relationships(s)
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1 The two lowest energy (C4H4)2V2(CO)7 structures include one with an agostic C-H-V interaction activating a hydrogen atom from one of the cyclobutadiene rings and another with a four-electron donor bridging eta2-micro-CO group with a short V-O bonding distance. Hydrogen DNA polymerase iota Homo sapiens