Title : Novel Nonradical Oxidation of Sulfonamide Antibiotics with Co(II)-Doped g-C3N4-Activated Peracetic Acid: Role of High-Valent Cobalt-Oxo Species.

Pub. Date : 2021 Sep 21

PMID : 34464118






1 Functional Relationships(s)
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1 Our experiments and density functional theory calculations indicate that the Co atom fixated into the nitrogen pots of g-C3N4 serves as the main active site, enabling dissociation of the adsorbed PAA and conversion of the coordinated Co(II) to Co(IV) via a unique two-electron transfer mechanism. Nitrogen mitochondrially encoded cytochrome c oxidase II Homo sapiens