Title : Organozinc pivalates for cobalt-catalyzed difluoroalkylarylation of alkenes.

Pub. Date : 2021 Jul 16

PMID : 34272392






1 Functional Relationships(s)
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1 Mechanistic studies strongly support that the reaction involves direct halogen atom abstraction via single electron transfer to difluoroalkyl bromides from the in situ formed cobalt(I) species, thus realizing a Co(I)/Co(II)/Co(III) catalytic cycle. co(iii) mitochondrially encoded cytochrome c oxidase II Homo sapiens