Title : Metallofullerene photoswitches driven by photoinduced fullerene-to-metal electron transfer.

Pub. Date : 2021 Apr 30

PMID : 34168836






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1 We report on the discovery and detailed exploration of the unconventional photo-switching mechanism in metallofullerenes, in which the energy of the photon absorbed by the carbon cage pi-system is transformed to mechanical motion of the endohedral cluster accompanied by accumulation of spin density on the metal atoms. Carbon spindlin 1 Homo sapiens