Title : Exploring Cu/Al cluster growth and reactivity: from embryonic building blocks to intermetalloid, open-shell superatoms.

Pub. Date : 2021 Apr 1

PMID : 34040734






2 Functional Relationships(s)
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1 The radical nature of the open-shell superatomic [Cu7Al6](Cp*)6 cluster 3 is reflected in its reactivity towards addition of one Cu core atom leading to the closed shell superatom [Cu8Al6](Cp*)6 (4), and as well by its ability to undergo sigma(C-H) and sigma(Si-H) activation reactions of C6H5CH3 (toluene) and (TMS)3SiH (TMS = tris(trimethylsilyl)). Tromethamine PYD and CARD domain containing Homo sapiens
2 The radical nature of the open-shell superatomic [Cu7Al6](Cp*)6 cluster 3 is reflected in its reactivity towards addition of one Cu core atom leading to the closed shell superatom [Cu8Al6](Cp*)6 (4), and as well by its ability to undergo sigma(C-H) and sigma(Si-H) activation reactions of C6H5CH3 (toluene) and (TMS)3SiH (TMS = tris(trimethylsilyl)). Tromethamine PYD and CARD domain containing Homo sapiens